Desenvolvimento de tratamentos térmicos visando ganhos magnéticos em aços com ultra baixa concentração de carbono

The relationship between the microstructure and the magnetic properties of soft magnetic materials, have been studied by different researchers who seek to employ electrical systems, increasing their life span and reduce their energy consumption. Following this same line the Brazilian Synchrotron Light Laboratory developed a new synchrotron light source, the Sirius, where magnetic materials with high magnetic permeability values are being studied for use in accelerator dipoles. The low carbon steel is a ferromagnetic material that has a great relationship between cost and magnetic permeability. Aiming to raise the values of permeability of the material, heat treatments were done and evaluated the magnetic properties, microstructure and mechanical properties to correlate them. It was noted that the thermal annealing were the most effective, and the annealing performed with a small time threshold, which only phenomenon observed was the primary recrystallisation, was the most elevated values of magnetic permeability of the material, due to the average grain size ideal achieved. The heat treatments do not guide the magnetic domains of the material and not influence the mechanical properties of the material due to lack of carbon in the microstructure. The annealing treatments were shown to be an alternative to raising the values of the magnetic permeability of the material and facilitate the implementation of ultra low carbon steel in the dipoles of Sirius

Desenvolvimento de extensões para um sistema de carregamento e descarregamento de navios

One of the reasons that influences the efficience of a port terminal that is especialized in movement of containers is in the process of their loading and unloading. The fundamental idea is to determine a plan, to each port in order to decrease the number of total movement of loading and unloading that are necessary during the ship route to every port so that they save time and consequently reduce costs. The goal of this research was to present improvement in the program, written in language C, used to solve to problem of loading and unloading of ships, a NP-complete problem, through the meta-heuristics Simulated Annealing. With the improvement made, an average of 50% reduction of necessary time was gotten to solve the problem in 45 analised instances and in a specific group of these instances the average reduction reached 77 and in 10 instances there was even an improvement in the solution

Preparação e caracterização de vidros contendo nanopartículas de Ag

This work consists of preparation and characterization of glasses containing transition noble metals and the study of optical properties of such materials. The glasses were prepared by quenching of the glass melt followed by heat treatment and polishing of the monoliths. The structural characterization of glasses was made using differential thermal analysis, X-ray, Raman and infrared spectroscopies, while the optical properties were studied by UV-Vis and M-Lines spectroscopies. Preliminary results have shown that the color of the glasses is dependent on both concentration of silver and the melting temperature of the melt. Controlled heat treatments have been used to induce the crystallization of Ag nanoparticles within the glass. The study of crystallization was accompanied by electron microscopy and UV-Vis spectroscopy. Data from electron diffraction, as well as chemical analysis, EDX, were obtained using a transmission electron microscope. EDX data have shown that the atomic percentage of Ag is higher on the nanoparticle. X-ray diffraction was used in order to characterize the composition of the crystals and cubic AgCl was identified as the main crystallized nanophase obtained after annealing

Método dos traços de fissão em apatita e zircão: geocronologia do Grupo Bauru

A proposta deste trabalho foi contribuir na continuação e no aprimoramento da rotina do Método de Traços de Fissão, MTF, em zircão e apatita no Grupo de Pesquisa de Detectores de traços nucleares em estados sólidos, DETRANES, DFQB/FCT- UNESP, campus Presidente Prudente. Para isto foram datadas, analisadas e determinadas as idades via o Método de Traços de Fissão, MTF, de amostras de zircão e apatita coletadas na Formação Presidente Prudente pertencente ao Grupo Bauru, Bacia do Paraná. Além de estudos na aplicação geológica, também foram realizados estudos na parte metodológica tais como experimentos para determinar a razão das eficiências de detecção dos traços fósseis e induzidos no zircão e experimentos de annealing (encurtamento do traço em função da temperatura e do tempo) para determinar um valor de L0 com amostras pertencentes ao Grupo Bauru, e compará-lo com a literatura. Quanto às idades obtidas para a formação Presidente temos como intervalo principal 100 e 600 Ma no zircão que pode indicar relação da fonte com três eventos orogênicos específicos: Orogenia Gondwânica (230 – 290 Ma), Orogenia Devoniana (330 – 390 Ma) e Orogenia Brasiliana (400 – 600 Ma). Na apatita temos uma distribuição de idades entre 10 e 70 Ma que, juntamente com os dados de...(Resumo completo, clicar acesso eletrônico abaixo)

Estudo de um ciclo de vapor utilizado para tratamento de superificies metálicas: estudo preliminar de caso

The use of heat in parallel with relative low temperatures and applied to several areas of the industry is essential for the main manufacturing processes, like drying, dehydrating, concentration, annealing, production of chemical reactions, and microbiological sterilization. Without neither the heat nor the coming of a great quantity of thermal heat, with high quality, there would not be the “modern society”, with its high standards of living plus its high consumption levels; from services to goods in general. Within an almost absolute way, the heat flows are obtained from vapor systems. Thus, in this work we are going into the operation of a vapor system, composed of two firetube boilers dimensioned to supply vapor for three processes. However, with the transfer of one of the processes to another plant, the system got over-dimensioned. But, taking advantage of this scenario, the two boilers were used to supply vapor to further processes, causing their intermittent usage. Moreover, the operational alternative adopted by the maintenance engineering of the plant for a creating a solution has been presented; both the positive points and negative ones were disclosed, likewise the possibility of improvement points

Estudo da variação do limite de resistência à tração ao longo da bobina de vergalhão de alumínio 1350 AA

Therebar of aluminum 1350 AA produced by CBA are used inthe manufacture of wires and cables for electric power transmission, which marketshows increasingly favorableto aluminum due to itslow densityand high electrical conductivity, but to ensure that this materialmeets all specifications of projectsfor electricity transmission, it must have homogeneity in the chemicaland mechanicalproperties.One of the points of improvement in the process of rod production isreducing the high variation of the limitof tensile strengthalong the coils, therefore, this work seeks a better understanding of the factors that significantly influence the mechanical properties of rebar, specifically assessing the influence oftemperatureat the output of the coils, which can cause a recovery effect on the material andif thereare relevantdifferences between the two modes of rebar production: auto and manual.Samples of six coils have been specifically produced forthis study, which weresubsequently subjected to different annealing temperatures for one hour and ten minutes, similar to what occurs in the output of the coil from the machine. The tensile tests showed that aluminum 1350 AA is significantly influenced by temperature, whose behavior was very similar to that presented in the literature. It was found that the phenomenon of recovery occurred more significantly at high temperatures. Through the optical electron microscope Zeiss, 18 surface maps were made with 100x magnification for each sample in different conditions and the images were analyzed using entropy and fractal dimension, aiming to relate the condition of surface hardening on mechanical property of the samples in that condition. The results showed that these methods can be applied, provided they do not have any kind of imperfection on the surface, once they can influence the results. The study concluded that a more efficient cooling is required in ... (Complete abstract click electronic access below)

Desenvolvimento de filmes finos de Bi3NbO7 pelo método dos precursores poliméricos em diferentes eletrodos óxidos

Technology always advances and thus the device miniaturization and improved performance, besides multifunctionality, they become extremely necessary. A wave of research on the area tends to grow in number and importance in today's market, it is necessary to search for new materials, new applicability of the existing ones and new processes for increasingly cheaper costs. Dielectric materials are considered a key element in this sector being the main electrical properties its high dielectric constant and low dielectric loss. The Polymeric Precursor Method appears as a good alternative because is a low cost, simple process with controlled stoichiometry. In this method, two steps were performed. In a first step, the precursor solution was decomposed into powders and in a second step the precursor solution was converted in thin films. In this work, was used the polymeric precursor methods to get thin films where they were heat treated and characterized by XRD, SEM and AFM. We have obtained Bi3NbO7 thin films with good homogeneity and uniform distribution of grains were noted. We observed that the best condition to obtain the tetragonal phase is annealing the film at high temperatures for a longer soaking time and with excess of bismuth. Several oxides electrodes were evaluated aiming to obtain textured dielectric thin films

Resolução do problema de sequenciamento de múltiplas linhas de montagem de modelos mistos em ambiente de produção enxuta

This work deals with the sequencing of Multi-Mixed-Model Assembly Lines in a lean manufacturing environment, where an operational structure where several kanbans support several mixed-model assembly lines, so that all assembly lines can receive parts or sub-assemblies from all suppliers. To optimize this system, the sequencing seeks to minimize the distance between the real consumption and the constant ideal consumption of parts or subassemblies, thereby reducing the scaling of kanbans and intermediate stocks. To solve the sequencing problems, the method Clustering Search was applied along with the metaheuristics Variable Neighborhood Search, Simulation Annealing and Iterative Local Search. Instances from the literature and generated instances were tested, thus allowing comparing the methods to each other and with other methods presented in the literature. The performance of the Clustering Search with Iterated Local Search stands out by the quality and robustness of their solutions, and mainly for its efficiency, whereas it converges to better results at a lower computational cost

Desenvolvimento de recobrimento submicrométrico de óxido de nióbio para aplicação em tubulações de prospecção de petróleo

Pós-graduação em Engenharia Mecânica - FEG

Very Intense Distinct Blue and Red Photoluminescence Emission in MgTiO 3 Thin Films Prepared by the Polymeric Precursor Method: An Experimental and Theoretical Approach

MgTiO3 (MTO) thin films were prepared by the polymeric precursor method with posterior spin-coating deposition. The films were deposited on Pt(111)/Ti/SiO2/Si(100) substrates and heat treated at 350 °C for 2 h and then heat treated at 400, 450, 500, 550, 600, 650 and 700 °C for 2 h. The degree of structural order−disorder, optical properties, and morphology of the MTO thin films were investigated by X-ray diffraction (XRD), micro-Raman spectroscopy (MR), ultraviolet− visible (UV−vis) absorption spectroscopy, photoluminescence (PL) measurements, and field-emission gun scanning electron microscopy (FEG-SEM) to investigate the morphology. XRD revealed that an increase in the annealing temperature resulted in a structural organization of MTO thin films. First-principles quantum mechanical calculations based on density functional theory (B3LYP level) were employed to study the electronic structure of ordered and disordered asymmetric models. The electronic properties were analyzed, and the relevance of the present theoretical and experimental results was discussed in the light of PL behavior. The presence of localized electronic levels and a charge gradient in the band gap due to a break in the symmetry are responsible for the PL in disordered MTO lattice.

Piezoresponse force microscopy behaviour of Bi4Ti3O12 ceramics with various excess bismuth

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Laser irradiation and thermal treatment inducing selective crystallization in Sb2O3-Sb2S3 glassy films

The influence of both thermal treatment and laser irradiation on the structural and optical properties of films in the Sb 2 O 3 –Sb 2 S 3 system was investigated. The films were prepared by RF-sputtering using glass compositions as raw materials. Irreversible photodarkening effect was observed after exposure the films to a 458nm solid state laser. It is shown, for the first time, the use of holographic technique to measure “in situ”, simultaneously and independently, the phase and amplitude modulations in glassy films. The films were also photo-crystallized and analysed “in situ” using a laser coupled to a micro-Raman equipment. Results showed that Sb 2 S 3 crystalline phase was obtained after irradiation. The effect of thermal annealing on the structure of the films was carried out. Different from the result obtained by irradiation, thermal annealing induces the crystallization of the Sb 2 O 3 phase. Photo and thermal induced effects on films were studied using UV–Vis and Raman spectroscopy, atomic force microscopy (AFM), thermal analysis (DSC), X-ray diffraction, scanning electron microscopy (MEV) and energy-dispersive X-ray spectroscopy (EDX).

Effect of oxidizing and reducing atmospheres on Ba(Ti0.90 Zr0.10)O3:2V ceramics as characterized by piezoresponse force microscopy

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Aços avançados de alta resistência: avaliação da microestrutura e propriedades dos aços DP 600 E DP 780

This work aims to study the Dual-Phase 600 and 780 steels, which are part of technology development project materials for the automotive industry. It is worth underscoring the antagonistic properties as the Dual-Phase steel assemble, high mechanical strength and elongation due its microstructure, ferrite and martensite. These properties are obtained by a intercritical heat treatment which facilitates the formation of a hardness metastable microstructure shaped plates of low carbon steels. The applicability of Dual Phase steel in the structure of vehicles is huge and its production is already on a commercial scale, so the study and development of this material implies lower cost in automobile manufacturing processes. The dual phase steels DP600 and DP780 underwent tensile, hardness and metallographic analysis to evaluate and comparing its properties. The results indicate that the DP780 steel has higher strength and hardness than the DP600 steel and its microstructure consists of martensite higher fraction which accounts for the higher resistance and hardness. However, the DP600 has higher conformability to DP780 steel

Deposição de filmes finos de SnO2 e GaAs, visando confecção de dispositivos baseados na heterojunção SnO2/GaAs

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)