Distribution of Cretaceous redeposited benthic foraminifers at DSDP Site 89-585

Cretaceous benthic foraminifers from Site 585 in the East Mariana Basin, western Pacific Ocean, provide an environmental and tectonic history of the Basin and the surrounding seamounts. Age diagnostic species (from a fauna of 155 benthic species identified) range from late Aptian to Maestrichtian in age. Displaced species in sediments derived from the tops and flanks of nearby seamounts were deposited sporadically on the Basin floor well below the carbonate compensation depth (CCD) at abyssal depths of 5000 to 6000 m. These depths, characterized by an indigenous assemblage of benthic foraminifers, recrystallized radiolarians, fish debris, and sponge spicules, existed in the Mariana Basin from late Aptian to the present. Early Albian and older edifice-building volcanism had reached the photic zone with associated shallow-water bank or reef environments. By middle Albian, the dominant source areas subsided to outer-neritic to upper-bathyal depths. Major volcanic activity ceased and fine-grained sediments were deposited by distal turbidites, although intermittent volcanism and the influx of rare neritic material continued until the late Albian. By the Cenomanian to Turonian, upper- to middle-bathyal depths were reached by the dominant source areas, and the sediments recovered from this interval include organic carbon-rich layers. Rare benthic foraminifers from the Coniacian-Santonian interval indicate a continuation of dominantly middle-bathyal source areas. A change in sedimentation during the Campanian-Maestrichtian from older zeolitic claystone to abundant chert in the Campanian, and nannofossil chalk and claystone in the Maestrichtian resulted from migration of the site beneath the equatorial productive zone due to northwestward plate motion. The appearance of rare middle-neritic and upper-bathyal species in the Maestrichtian interval associated with volcanogenic debris gives evidence of the remobilization and downslope transport of pelagic deposits due to thermally induced uplift. Episodic redeposition of shallow-water material during the Aptian-Albian was produced by edifice-building volcanism perhaps combined with eustatic lowering of sea level. The Cenomanian-Turonian pulse coincided with a low global sea-level stand as does the transported material during the Coniacian-Santonian. The Maestrichtian pulse was caused by renewed midplate volcanism that extended over a large area of the central Pacific.

Hydrogen isotope composition of pore waters and interlayer water in sediments of ODP Leg 129 holes

Hydrogen isotope compositions have been measured on pore waters from sediments of Leg 129 sites in the Pigafetta and East Mariana basins (central western Pacific). Total water (pore + sorbed waters) contents and their dD have been analyzed for three samples that contain smectite but no zeolite so that sorbed water can be attributed to interlayer water. The H budget for pore and total waters implies that interlayer water is 20 per mil to 30 per mil depleted in D compared to pore water. Because the interlayer/total water molar ratio (0.25 to 0.5) in smectitic sediments is very high, interlayer water represents an important reservoir of D-depleted water in sediments. dD depth profiles for pore water at Sites 800 and 801 show breaks related to chert and radiolarite layers and are relatively vertical below. Above these chert units, pore waters are similar to modern seawater but below, they are between -10 per mil and -5.5 per mil. These values could represent little modified pre-Miocene seawater values, which were D-depleted because of the absence of polar caps, and were preserved from diffusive exchange with modern seawater by the relatively impermeable overlying chert layers. At Site 802, dD values of the pore waters show a decrease in the Miocene tuffs from 0 per mil values at the top to -8 per mil at 250 mbsf. Below, dD values are relatively uniform at about -8ë. Miocene tuffs are undergoing low water/rock alteration. A positive covariation of dD and Cl content of pore water in the tuffs suggests that the increase of dD values could result from secondary smectite formation. Low diffusive exchange coupled with D enrichment due to alteration of preglacial waters could explain the observed profile.

Zeolite and silica diagenesis and sandstone petrography at DSDP Sites 57-438 and 57-439

We detected authigenic clinoptilolites in two core samples of tuffaceous, siliceous mudstone in the lower Miocene section of Hole 439. They occur as prismatic and tabular crystals as long as 0.03 mm in various voids of dissolved glass shards, radiolarian shells, calcareous foraminifers, and calcareous algae. They are high in alkalies, especially Na, and in silica varieties. There is a slight difference in composition among them. The Si : (Al+ Fe3+) ratio is highest (4.65) in radiolarian voids, intermediate (4.34) in dissolved glass voids, and lowest (4.26) in voids of calcareous organisms. This difference corresponds to the association of authigenic silica minerals revealed by the scanning electron microscope: There are abundant opal-CT lepispheres in radiolarian voids, low cristobalite and some lepispheres in dissolved glass voids, and a lack of silica minerals in the voids of calcareous organisms. Although it contains some silica from biogenic opal and alkalies from trapped sea water, clinoptilolite derives principally from dissolved glass. Although they are scattered in core samples of Quaternary through lower Miocene diatomaceous and siliceous deposits, acidic glass fragments react with interstitial water to form clinoptilolite only at a sub-bottom depth of 935 meters at approximately 25°C. Analcimes occur in sand-sized clasts of altered acidic vitric tuff in the uppermost Oligocene sandstones. The analcimic tuff clasts were probably reworked from the Upper Cretaceous terrain adjacent to Site 439. Low cristobalite and opal-CT are found in tuffaceous, siliceous mudstone of the middle and lower Miocene sections at Sites 438 and 439. Low cristobalite derives from acidic volcanic glass and opal-CT from biogenic silica. Both siliceous organic remains and acidic glass fragments occur in sediments from the Quaternary through lower Miocene sections. However, the shallowest occurrence is at 700 meters subbottom in Hole 438A, where temperature is estimated to be 21°C. The d(101) spacing of opal-CT varies from 4.09 to 4.11 Å and that of low cristobalite from 4.04 to 4.06 Å. Some opal-CT lepispheres are precipitated onto clinoptilolites in the voids of radiolarian shells at a sub-bottom depth of 950 meters in Hole 439. Sandstone interlaminated with Upper Cretaceous shale is chlorite- calcite cemented and feldspathic. Sandstones in the uppermost Oligocene section are lithic graywacke and consist of large amounts of lithic clasts grouped into older sedimentary and weakly metamorphosed rocks, younger sedimentary rocks, and acidic volcanic rocks. The acidic volcanic clasts probably originated from the volcanic high, which supplied the basal conglomerate with dacite gravels. The older sedimentary and weakly metamorphosed rocks and green rock correspond to the lithologies of the lower Mesozoic to upper Paleozoic Sorachi Group, including the chert, limestone, and slate in south-central Hokkaido. However, the angular shape and coarseness of the clasts and the abundance of carbonate rock fragments indicate a nearby provenance, which is probably the southern offshore extension of the Sorachi Group. The younger sedimentary rocks, including mudstone, carbonaceous shale, and analcime-bearing tuff, correspond to the lithologies of the Upper Cretaceous strata in south-central Hokkaido. Their clasts were reworked from the southern offshore extension of the strata. Because of the discontinuity of the zeolite zoning due to burial diagenesis, an overburden several kilometers thick must have been denuded before the deposition of sediments in the early Oligocene.