Produção de mudas de goiabeira (Psidium guajava L.), inoculadas com o fungo micorrízico arbuscular Glomus clarum, em substrato agro-industrial

Conduziu-se um experimento em casa de vegetação, com o objetivo de avaliar o crescimento de mudas de goiabeira (Psidium guajava L.), produzidas em blocos prensados, confeccionados com resíduos agro-industriais, e inoculadas com o fungo micorrízico arbuscular (FMA) Glomus clarum Nicolson & Schenck. O delineamento experimental utilizado foi o inteiramente casualizado, em esquema fatorial 2 x 2, sendo 2 tratamentos microbiológicos: controle e FMA; e 2 sistemas de produção de mudas: blocos prensados (nova metodologia) e tubetes plásticos (tradicional), com 5 repetições. O substrato utilizado para a confecção dos blocos prensados e enchimento dos tubetes foi constituído por uma mistura de bagaço de cana-de-açúcar e torta de filtro (3:1 v/v). O FMA proporcionou aumentos significativos na produção de matéria seca, conteúdo de N e P da parte aérea da goiabeira, apenas no sistema de produção das mudas em blocos prensados. Mudas produzidas e inoculadas em blocos prensados mostraram um aumento de 88% na matéria seca da parte aérea, 82% e 89% para os conteúdos de nitrogênio e fósforo da parte aérea, respectivamente, em relação ao tratamento-controle.

High-performance liquid chromatography of the renal blood flow marker p-aminohippuric acid (PAH) and its metabolite N-acetyl PAH improves PAH clearance measurements.

PAH (N-(4-aminobenzoyl)glycin) clearance measurements have been used for 50 years in clinical research for the determination of renal plasma flow. The quantitation of PAH in plasma or urine is generally performed by colorimetric method after diazotation reaction but the measurements must be corrected for the unspecific residual response observed in blank plasma. We have developed a HPLC method to specifically determine PAH and its metabolite NAc-PAH using a gradient elution ion-pair reversed-phase chromatography with UV detection at 273 and 265 nm, respectively. The separations were performed at room temperature on a ChromCart (125 mmx4 mm I.D.) Nucleosil 100-5 microm C18AB cartridge column, using a gradient elution of MeOH-buffer pH 3.9 1:99-->15:85 over 15 min. The pH 3.9 buffered aqueous solution consisted in a mixture of 375 ml sodium citrate-citric acid solution (21.01 g citric acid and 8.0 g NaOH per liter), added up with 2.7 ml H3PO4 85%, 1.0 g of sodium heptanesulfonate and completed ad 1000 ml with ultrapure water. The N-acetyltransferase activity does not seem to notably affect PAH clearances, although NAc-PAH represents 10.2+/-2.7% of PAH excreted unchanged in 12 healthy subjects. The performance of the HPLC and the colorimetric method have been compared using urine and plasma samples collected from healthy volunteers. Good correlations (r=0.94 and 0.97, for plasma and urine, respectively) are found between the results obtained with both techniques. However, the colorimetric method gives higher concentrations of PAH in urine and lower concentrations in plasma than those determined by HPLC. Hence, both renal (ClR) and systemic (Cls) clearances are systematically higher (35.1 and 17.8%, respectively) with the colorimetric method. The fraction of PAH excreted by the kidney ClR/ClS calculated from HPLC data (n=143) is, as expected, always <1 (mean=0.73+/-0.11), whereas the colorimetric method gives a mean extraction ratio of 0.87+/-0.13 implying some unphysiological values (>1). In conclusion, HPLC not only enables the simultaneous quantitation of PAH and NAc-PAH, but may also provide more accurate and precise PAH clearance measurements.

Projecte d'una instal·lació elèctrica i una instal·lació solar fotovoltaica connectada a la xarxa de baixa tensió, en una nau industrial

Dissenyar la xarxa elèctrica d'una nau industrial i dissenyar una instal·lació solar fotovoltaica connectada a la xarxa de baixa tensió. Per a la instal·lació de la nova xarxa elèctrica s'ha aprofitat tot l'enllumenat, els endolls i els interruptors existents en la nau, de l'anterior instal·lació, que s'ha quedat obsoleta degut a la instal·lació de noves màquines. S'ha escollit una instal·lació solar fotovoltaica connectada a la xarxa elèctrica perquè s'utilitza una energia purament neta i inesgotable, perquè té una bona rentabilitat.

Cálculo y diseño de la estructura de una nave industrial destinada a un centro de mecanizado

En el siguiente proyecto se pretende realizar los cálculos correctos para determinar cual ha de ser la estructura y las cimentaciones de una nave industrial perfectamente diseñada. El àmbito de aplicación del proyecto es la arquitectura industrial.

Características físicas e físico-químicas de um tipo de bacuri (Platonia insignis Mart.) com rendimento industrial superior

Efetuou-se a caracterização física do fruto e físico-química da polpa do bacuri CPATU 207-3, oriundo de uma planta-matriz do Banco de Germoplasma de Bacurizeiro da Embrapa Amazônia Oriental. Para a caracterização física foi utilizada uma amostra de 50 frutos, os quais foram individualmente analisados quanto aos seguintes aspectos: cor do epicarpo, formato, peso, comprimento, diâmetro, espessura da casca, volume da cavidade interna, número de sementes e de segmentos partenocárpicos, rendimentos porcentuais (p/p) de casca, polpa, sementes e do conjunto representado pela coluna placentária e óvulos abortados. A caracterização físico-química foi efetuada em três amostras de polpa congelada a 18ºC negativos, provenientes de frutos em completo estádio de maturação, coletados nos meses de janeiro, fevereiro e março de 2001, tendo sido consideradas as seguintes variáveis: teores de umidade, de sólidos totais e de sólidos solúveis totais (ºBrix), pH, acidez total e a relação sólidos solúveis totais/acidez total titulável. O bacuri CPATU 207-3 apresentou formato ovalado e com ápice ligeiramente pontiagudo, epicarpo de coloração amarelada, fruto de tamanho considerado médio e peso médio de 265,8 g. As principais características diferenciais desse tipo de bacuri são: a espessura da casca (0,75cm), o rendimento porcentual de polpa (27,7%) e o número de segmentos partenocárpicos (2,8 unidades/fruto). A polpa do bacuri CPATU 207-3 apresentou boas características físico-químicas, com 84,35% de umidade, 15,65% de sólidos totais, teor de sólidos solúveis totais de 14,53ºBrix, pH 3,34, acidez total titulável de 1,24% e relação ºBrix/acidez total titulável igual a 11,4. As características físicas e físico-químicas desse tipo de bacuri permitem sua utilização tanto para consumo na forma de fruta fresca como na forma industrializada. Nesse último caso, é particularmente indicado para fabricação de compota, em decorrência do elevado número de segmentos partenocárpicos que apresenta.

Disseny d'una nau bioclimàtica sense ús determinat, ubicat al Polígon Industrial "Camí dels Frares" de Lleida

L'objecte del present projecte tècnic és la descripció de la climatització d'una nau industrial bioclimàtica, fent ús de sistemes passius i si fos necessari, de sistemes actius. El concepte de bioclimàtic procedeix de bios-vida i clima - orientació. El propòsit d'aquest disseny arquitectònic és que des del punt de vista energètic permeti que la nau mantingui un nivell de confort tant en hivern com en estiu, aplicant una sèrie de criteris de disseny a fi d'utilitzar els elements constructius i funcionals propis de l'edifici per tal d'aconseguir un bon control del seu comportament energètic.

Disseny de la instal·lació de climatització de l'ampliació d'una nau industrial destinada a oficines

L'objectiu del projecte és dissenyar la instal·lació de climatització. Es durà a terme utilitzant terra radiant per la calefacció, fent ús de l'energia solar per escalfar l'aigua. També es durà a terme el sistema de refrigeració i ventilació, així­ com la instal·lació solar d'ACS.

Diseño de una nave industrial sin uso específico en la localidad de Vilamalla

En el proyecto se ha diseñado una nave industrial teniendo en cuenta la normativa vigente en el sector y una serie de consideraciones realizadas, como la posibilidad de una futua ampliación o la existencia de puente grúa y de un altillo. También se han estudiado las distintas alternativas que nos ofrece el mercado para construir la estructura de la nave industrial, eligiendo el hormigón prefabricado y el panel sandwich de cubierta como los más apropiados para nuetro caso. Finalmente, se ha justificado el conjunto de acciones (cargas) existentes en la nave, el cálculo de las principales piezas de alimentación requerida.

Influence of stationary phase and eluent properties on chromatographic separation of carbohydrates

In this thesis, the sorption and elastic properties of the cation-exchange resins were studied to explain the liquid chromatographic separation of carbohydrates. Na+, Ca2+ and La3+ form strong poly(styrene-co-divinylbenzene) (SCE) as well as Na+ and Ca2+ form weak acrylic (WCE) cation-exchange resins at different cross-link densities were treated within this work. The focus was on the effects of water-alcohol mixtures, mostly aqueous ethanol, and that of the carbohydrates. The carbohydrates examined were rhamnose, xylose, glucose, fructose, arabinose, sucrose, xylitol and sorbitol. In addition to linear chromatographic conditions, non-linear conditions more typical for industrial applications were studied. Both experimental and modeling aspectswere covered. The aqueous alcohol sorption on the cation-exchangers were experimentally determined and theoretically calculated. The sorption model includes elastic parameters, which were obtained from sorption data combined with elasticity measurements. As hydrophilic materials cation-exchangers are water selective and shrink when an organic solvent is added. At a certain deswelling degree the elastic resins go through glass transition and become as glass-like material. Theincreasing cross-link level and the valence of the counterion decrease the sorption of solvent components in the water-rich solutions. The cross-linkage or thecounterions have less effect on the water selectivity than the resin type or the used alcohol. The amount of water sorbed is higher in the WCE resin and, moreover, the WCE resin is more water selective than the corresponding SCE resin. Theincreased aliphatic part of lower alcohols tend to increase the water selectivity, i.e. the resins are more water selective in 2-propanol than in ethanol solutions. Both the sorption behavior of carbohydrates and the sorption differences between carbohydrates are considerably affected by the eluent composition and theresin characteristics. The carbohydrate sorption was experimentally examined and modeled. In all cases, sorption and moreover the separation of carbohydrates are dominated by three phenomena: partition, ligand exchange and size exclusion. The sorption of hydrophilic carbohydrates increases when alcohol is added into the eluent or when carbohydrate is able to form coordination complexes with the counterions, especially with multivalent counterions. Decreasing polarity of the eluent enhances the complex stability. Size exclusion effect is more prominent when the resin becomes tighter or carbohydrate size increases. On the other hand,the elution volumes between different sized carbohydrates decreases with the decreasing polarity of the eluent. The chromatographic separation of carbohydrateswas modeled, using rhamnose and xylose as target molecules. The thermodynamic sorption model was successfully implemented in the rate-based column model. The experimental chromatographic data were fitted by using only one adjustable parameter. In addition to the fitted data also simulated data were generated and utilized in explaining the effect of the eluent composition and of the resin characteristics on the carbohydrate separation.

Projecte d’urbanització del sector 22 – Polígon industrial de Can Sunyer

L’objecte del projecte és la renovació de les infraestructures i serveis d’un polígon industrial de 28, 5 hectàrees situat al municipi de Sant Andreu de la Barca. Amb les millores es preveu millorar la qualitat de vida dels principals usuaris i la integració del polígon dins la xarxa de polígons de la resta del municipi, per altra banda, es planteja que determinades zones del polígon puguin ser utilitzades com a zones de lleure. La millora de les infraestructures comprén: Xarxa de sanejament, xarxa d’aigua potable, xarxa elèctrica , xarxa d’enllumenat públic, millora del ferm i projecció d’un espai verd públic.

Competitor Information andCompetitive Knowledge Management in a Large Industrial Organization

Thisthesis supplements the systematic approach to competitive intelligence and competitor analysis by introducing an information-processing perspective on management of the competitive environment and competitors therein. The cognitive questions connected to the intelligence process and also the means that organizational actors use in sharing information are discussed. The ultimate aim has been to deepen knowledge of the different intraorganizational processes that are used in acorporate organization to manage and exploit the vast amount of competitor information that is received from the environment. Competitor information and competitive knowledge management is examined as a process, where organizational actorsidentify and perceive the competitive environment by using cognitive simplification, make interpretations resulting in learning and finally utilize competitor information and competitive knowledge in their work processes. The sharing of competitive information and competitive knowledge is facilitated by intraorganizational networks that evolve as a means of developing a shared, organizational level knowledge structure and ensuring that the right information is in the right place at the right time. This thesis approaches competitor information and competitive knowledge management both theoretically and empirically. Based on the conceptual framework developed by theoretical elaboration, further understanding of the studied phenomena is sought by an empirical study. The empirical research was carried out in a multinationally operating forest industry company. This thesis makes some preliminary suggestions of improving the competitive intelligence process. It is concluded that managing competitor information and competitive knowledge is not simply a question of managing information flow or improving sophistication of competitor analysis, but the crucial question to be solved is rather, how to improve the cognitive capabilities connected to identifying and making interpretations of the competitive environment and how to increase learning. It is claimed that competitive intelligence can not be treated like an organizational function or assigned solely to a specialized intelligence unit.

Permanent magnet synchronous motor for industrial inverter applications - analysis and design

During the latest few years the need for new motor types has grown, since both high efficiency and an accurate dynamic performance are demanded in industrial applications. For this reason, new effective control systems such as direct torque control (DTC) have been developed. Permanent magnet synchronous motors (PMSM) are well suitable for new adjustable speed AC inverter drives, because their efficiency and power factor are not depending on the pole pair number and speed to the same extent as it is the case in induction motors. Therefore, an induction motor (IM) with a mechanical gearbox can often be replaced with a direct PM motor drive. Space as well as costs will be saved, because the efficiency increases and the cost of maintenance decreases as well. This thesis deals with design criterion, analytical calculation and analysis of the permanent magnet synchronous motor for both sinusoidal air-gap flux density and rectangular air-gapflux density. It is examined how the air-gap flux, flux densities, inductances and torque can be estimated analytically for salient pole and non-salient pole motors. It has been sought by means of analytical calculations for the ultimate construction for machines rotating at relative low 300 rpm to 600 rpm speeds, which are suitable speeds e.g. in Pulp&Paper industry. The calculations are verified by using Finite Element calculations and by measuring of prototype motor. The prototype motor is a 45 kW, 600 rpm PMSM with buried V-magnets, which is a very appropriate construction for high torque motors with a high performance. With the purposebuilt prototype machine it is possible not only to verify the analytical calculations but also to show whether the 600 rpm PMSM can replace the 1500 rpm IM with a gear. It can also be tested if the outer dimensions of the PMSM may be the same as for the IM and if the PMSM in this case can produce a 2.5 fold torque, in consequence of which it may be possible to achieve the same power. The thesis also considers the question how to design a permanent magnet synchronous motor for relatively low speed applications that require a high motor torqueand efficiency as well as bearable costs of permanent magnet materials. It is shown how a selection of different parameters affects the motor properties. Key words: Permanent magnet synchronous motor, PMSM, surface magnets, buried magnets

Ion-exchange resins as stationary phase in reactive chromatography

Dynamic behavior of bothisothermal and non-isothermal single-column chromatographic reactors with an ion-exchange resin as the stationary phase was investigated. The reactor performance was interpreted by using results obtained when studying the effect of the resin properties on the equilibrium and kinetic phenomena occurring simultaneously in the reactor. Mathematical models were derived for each phenomenon and combined to simulate the chromatographic reactor. The phenomena studied includes phase equilibria in multicomponent liquid mixture¿ion-exchange resin systems, chemicalequilibrium in the presence of a resin catalyst, diffusion of liquids in gel-type and macroporous resins, and chemical reaction kinetics. Above all, attention was paid to the swelling behavior of the resins and how it affects the kinetic phenomena. Several poly(styrene-co-divinylbenzene) resins with different cross-link densities and internal porosities were used. Esterification of acetic acid with ethanol to produce ethyl acetate and water was used as a model reaction system. Choosing an ion-exchange resin with a low cross-link density is beneficial inthe case of the present reaction system: the amount of ethyl acetate as well the ethyl acetate to water mole ratio in the effluent stream increase with decreasing cross-link density. The enhanced performance of the reactor is mainly attributed to increasing reaction rate, which in turn originates from the phase equilibrium behavior of the system. Also mass transfer considerations favor the use ofresins with low cross-link density. The diffusion coefficients of liquids in the gel-type ion-exchange resins were found to fall rapidly when the extent of swelling became low. Glass transition of the polymer was not found to significantlyretard the diffusion in sulfonated PS¿DVB ion-exchange resins. It was also shown that non-isothermal operation of a chromatographic reactor could be used to significantly enhance the reactor performance. In the case of the exothermic modelreaction system and a near-adiabatic column, a positive thermal wave (higher temperature than in the initial state) was found to travel together with the reactive front. This further increased the conversion of the reactants. Diffusion-induced volume changes of the ion-exchange resins were studied in a flow-through cell. It was shown that describing the swelling and shrinking kinetics of the particles calls for a mass transfer model that explicitly includes the limited expansibility of the polymer network. A good description of the process was obtained by combining the generalized Maxwell-Stefan approach and an activity model that was derived from the thermodynamics of polymer solutions and gels. The swelling pressure in the resin phase was evaluated by using a non-Gaussian expression forthe polymer chain length distribution. Dimensional changes of the resin particles necessitate the use of non-standard mathematical tools for dynamic simulations. A transformed coordinate system, where the mass of the polymer was used as a spatial variable, was applied when simulating the chromatographic reactor columns as well as the swelling and shrinking kinetics of the resin particles. Shrinking of the particles in a column leads to formation of dead volume on top of the resin bed. In ordinary Eulerian coordinates, this results in a moving discontinuity that in turn causes numerical difficulties in the solution of the PDE system. The motion of the discontinuity was eliminated by spanning two calculation grids in the column that overlapped at the top of the resin bed. The reactive and non-reactive phase equilibrium data were correlated with a model derived from thethermodynamics of polymer solution and gels. The thermodynamic approach used inthis work is best suited at high degrees of swelling because the polymer matrixmay be in the glassy state when the extent of swelling is low.

Unas reflexiones sobre localización industrial aplicadas a la industria catalana

El trabajo es una reflexión sobre las pautas de localización industrial,con una especial referencia a la industria de la economía catalana. En el estudio se realiza una revisión de los principales factores explicativos de la localización y aglomeración industrial defendidos por las teorías de la localización. Con estos argumentos de base, posteriormente el análisis se aplica a una división de catorce grandes sectores industriales catalanes. El objetivo es llegar a conclusiones acerca de si los sectores en los que la industria catalana muestra mayor grado de especialización son también aquellos que, a tenor de los principales factores que inciden en la localización industrial, tienen mayor riesgo de sufrir futuras deslocalizaciones.