760 resultados para acrylonitrile butadiene(NBR) rubbers


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This work deals in a general way, the history and advantages of steel buildings, as well as its increasing usage in Brazil in the last century. This work also generally describes some types and its uses of metal frame. It also demonstrates the use of the NBR 8800: 2008 standard and its calculation methods through the scale out materials regulated in Brazil for an industrial warehouse project small and simple portico metal frame. Given that the construction requirements include a locational influence following the normative indications of the NBR 6123, for the winding scale out, since this effect combined with the permanent loads must be seriously evaluated due to the shape type effort about acting simultaneous axial force and bending moments obeying the limitations applied to the structure according to NBR 8800. As it has been explained the calculations that ensures mechanical stability and suggesting an analysis of the efficiency of the used materials

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A espécie amazônica Paricá (Schizolobium amazonicum Herb) apresenta rápidos incrementos em altura e diâmetro em poucos anos de cultivo e desenvolve uma madeira com pequena quantidade de nós e defeitos, característica fundamental na sua utilização para fins estruturais. O objetivo deste trabalho foi determinar as propriedades de resistência e rigidez de peças da madeira Paricá em dimensões estruturais, de acordo com a norma ABNT NBR 7190: 2011, bem como realizar a classificação visual das peças para determinação de defeitos como: nós, inclinação de fibras, empenamentos, rachas e fendas. Conclui-se que a madeira de Paricá é classificada como classe C 20 das dicotiledôneas e possui baixa densidade, boa resistência à compressão paralela, grande potencial de utilização na construção civil quando comparada com outras espécies e, em relação à classificação visual, poucos nós, grã direita e poucos empenamentos e distorções.

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São apresentadas análises das recomendações para estimar a resistência ao puncionamento de lajes lisas de acordo com a versão atual da norma brasileira, a NBR 6118:2003, que não considera o efeito da retangularidade de pilares internos, e sua predecessora, a NBR 6118:1980. Em seções transversais retangulares, o índice de polarização das tensões de cisalhamento é crescente. Isto altera a forma de ruptura da laje, já que a punção se inicia em torno das extremidades da seção do pilar, não se estendendo para os lados maiores, como prescreve a norma, comportamento este que reduz a resistência última das lajes frente às estimativas normativas. São apresentados os resultados de uma análise numérica por elementos finitos (M.E.F.) e uma proposta para melhorar a ductilidade das lajes lisas através das dimensões mínimas dos pilares. Observou-se que a NBR 6118:1980 mostrou-se conservadora e que as estimativas da NBR 6118: 2003 podem ser melhoradas.

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Living anionic polymerization of 4-vinylbenzocylobutene was performed in benzene at room temperature using sec-butyllithium as the initiator. Results of the kinetic studies indicated the termination- and transfer-free nature of the polymerization. Homopolymers with predictable molecular weights and narrow molecular weight distributions were produced, excluding the interference of the cyclobutene rings during initiation and propagation. Thermogravimetric analysis of poly(4-vinylbenzocyclobutene) in air showed a small weight gain at ~200 °C, a rapid decomposition at ~455 °C, and a gradual decomposition at ~566 °C. This behavior was attributed to the formation of radicals from the pendent benzocyclobutene functionality through o-quinodimethane intermediates and simultaneous decomposition/cross-linking reactions at high temperature. The living nature of the polymerization was also examined via sequential copolymerization with butadiene to form diblock copolymers.

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Black fungi are able to adapt to extreme environmental conditions, such as: high temperatures, the presence of toxic chemical substances and lack of nutrients. Besides, they are also potential pathogens to humans. The natural environment of many black fungi is still unknown and some studies are being conducted to evaluate the biodiversity of this group and their different habitats. This study aimed to isolate black fungi in domestic environments and facilities, such as toothbrushes, fridge sealing rubbers, bathroom strainers and divisions, windows, wall tiles and bath sponge. For the collection, material surfaces were scratched with a scalpel and the resulting fragments were sewed in Mycosel agar (DifcoTM), supplemented with actidione to inhibit the growth of highly-sporulating fungi. Plates were incubated at 25ºC for three weeks. The 46 isolated fungi were maintained on MA2% slants at 8ºC and cryopreserved at -80ºC. Fungal identification was performed through the analysis of macro and microscopic features and ITS rDNA sequencing. The following black fungi taxa were found: Ascomycota sp., Cladosporium spp., Dothideomycete sp., Exophiala alcalophila, Ochroconis mirabilis and Rhinocladiella atrovirens. Non-melanized fungi were also found, such as Geosmithia sp., Penicillium sp. and Rhodotorula mucilaginosa. The temperature tests showed that isolated black fungi were not able to grow at 37°C, however, this temperature proved to be fungistatic to 43% of them. According to literature, all black fungi isolated in this study are opportunistic pathogens and additional studies are necessary to evaluate the risk that these micro-organisms offer to health, once they were isolated from domestic environments

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This work talks about the importance of the steel adhesion to concrete, reinforced concrete structures, their testing and forms of measurement used and how the results are used in the structural design, which uses as a reference the NBR 6118 and NBR 7480. It also deals with the importance of a reliable assessment, discussing failures that the test used, NBR 7477, features in specific circumstances, as discussed under the EC-094. It also presents an initial proposal for simplified pullout test, which aims to analyze the grip on steel bars with diameter less than 10 mm, which results when used standardized testing by ABNT NBT 7477, has shown excessive variability, the main criticism of the trial today used without distinction to be established thick or thin bars. The proposal also presented methodology is in the consolidation phase, given the time and the volume of necessary tests. For this reason it is not possible to make a comparison between the values obtained and the results of the test used on the basis of the standard in force, this can only be done once the front with a continuation of this work

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In this work, we discuss the procedures adopted for the design of built-up columns (laced and battened columns). Built-up columns are widely used in steel construction generally when the compression forces are relatively low and the column buckling lengths are large. They are commonly used in industrial buildings, for example, as posts for cladding, or as columns supporting a crane girder. Unlike columns with full section, in the case of built-up columns, it is necessary to evaluate the shear stiffness. In fact, the shear strength leads to a significant reduction of the critical load. In the context of this work, the components of the columns (chords, diagonals, posts, etc.) are formed by cold-formed members. In order to systematize and rationalize the verification of the built-up columns, this work aim to develop a computer program based on the standards NBR 14762, NBR 6355 and Eurocode 3, basically the considerations of the part EN 1993-1-1

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There are regulations that establish conditions and enable the design of armor columns. The NBR 6118 features statements relating to the transverse reinforcement as spacing, reinforcement diameters provision in structural elements and others. However, the norm in force does not provide an explicit methodology for the design of stirrups in different situations. We do not propose even a calculation model for this equipment and provides normative considerations for maximum or minimum values of spacings and armor in diameter. It is noteworthy that the classical references also do not provide a calculation routine sizing of transverse reinforcement and only makes the checks as the normative conditions for the given data. Based on this assumption and the problems that may occur in sizing error, both for spacing and for the proposal of the stirrup diameter, this study demonstrates that armor calculation method already established in the literature and then through an intuitive tool and available develops a spreadsheet based on this calculation routine. It takes as reference the one developed by Emil Moersch (1902) and the calculation model proposed by BUFFONI E SILVA (2006). Finally the paper presents a rational design of shear reinforcement and confronts these values with some numerical examples to show its truth

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This work deals in a general way, the history and advantages of steel buildings, as well as its increasing usage in Brazil in the last century. This work also generally describes some types and its uses of metal frame. It also demonstrates the use of the NBR 8800: 2008 standard and its calculation methods through the scale out materials regulated in Brazil for an industrial warehouse project small and simple portico metal frame. Given that the construction requirements include a locational influence following the normative indications of the NBR 6123, for the winding scale out, since this effect combined with the permanent loads must be seriously evaluated due to the shape type effort about acting simultaneous axial force and bending moments obeying the limitations applied to the structure according to NBR 8800. As it has been explained the calculations that ensures mechanical stability and suggesting an analysis of the efficiency of the used materials

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This paper presents a study on the potential use of coconut fiber as material to produce particleboards, with two different densities (0.8 g/cm(3) and 1.0 g/cm3), using castor oil-based polyurethane adhesive and urea-formaldehyde. The quality of the product that can be produced by industry was evaluated according to the normative NBR 14.810:2006, where density, thickness swell (TS), absorption, modulus of elasticity (MOE), modulus of rupture (MOR) in static bending and internal bond (IB) were determined. From the results, there was a decrease in TS and increase in MOR of coconut fiber panels with polyurethane resin panels compared with coconut fiber and resin urea-formaldehyde. Scanning microscopy electronic images (SEM) indicated that castor oil-based polyurethane adhesive occupies the gaps between the particles, a factor that contributes to improved physical and mechanical properties of the panels. The assessment of durability through accelerated aging tests shows that panels protected with waterproofing material can be used in environments that have contact with moisture. (C) 2012 Elsevier B.V. All rights reserved.

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This work aimed to study the characteristics of the fibres of the species Bactris setosa ('tucum') used by close-knit social groups, located in Sorocaba - Sao Paulo - Brazil, in basket-making techniques, for possible applications in textile activity. Optical microscopy (NBR 13 538:1995) and Tensile Properties (ASTM D 3 822-2001) were used to assess properties such as the fibre structre, linear density, breaking force, elongation at break and breaking tenacity of each species. Bactris setosa showed a longitudinal view similar to that of sisal; an average linear density of 41.2 tex, a tenacity average of 11.96 cN/tex, closer to fiberglass, and an elongation ranging between 1.35 and 3.87%. It is important to clarify the delicacy and detail of the tests, and from this we highlight the importance of carrying out these studies, based on which science and technology must be linked with socio-environmental aspects.

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Gas-phase reactions of model carbosulfonium ions (CH3-S+?=?CH2; CH3CH2-S+?=?CH2 and Ph-S+?=?CH2) and an O-analogue carboxonium ion (CH3-O+?=?CH2) with acyclic (isoprene, 1,3-butadiene, methyl vinyl ketone) and cyclic (1,3-cyclohexadiene, thiophene, furan) conjugated dienes were systematically investigated by pentaquadrupole mass spectrometry. As corroborated by B3LYP/6-311?G(d,p) calculations, the carbosulfonium ions first react at large extents with the dienes forming adducts via simple addition. The nascent adducts, depending on their stability and internal energy, react further via two competitive channels: (1) in reactions with acyclic dienes via cyclization that yields formally [4?+?2+] cycloadducts, or (2) in reactions with the cyclic dienes via dissociation by HSR loss that yields methylenation (net CH+ transfer) products. In great contrast to its S-analogues, CH3-O+?=?CH2 (as well as C2H5-O+?=?CH2 and Ph-O+?=?CH2 in reactions with isoprene) forms little or no adduct and proton transfer is the dominant reaction channel. Isomerization to more acidic protonated aldehydes in the course of reaction seems to be the most plausible cause of the contrasting reactivity of carboxonium ions. The CH2?=?CH-O+?=?CH2 ion forms an abundant [4?+?2+] cycloadduct with isoprene, but similar to the behavior of such alpha,beta-unsaturated carboxonium ions in solution, seems to occur across the C?=?C bond. Copyright (c) 2012 John Wiley & Sons, Ltd.

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Because discomfort caused by different approximal caries detection methods can influence their performance, the assessment of this discomfort is important. Thus, this study aimed to evaluate the discomfort reported by children after the use of different diagnostic methods to detect approximal caries lesions in primary teeth: visual inspection, bitewing radiography, laser fluorescence (DIAGNOdent pen - LFpen) and temporary separation with orthodontic rubbers. Seventy-six children aged 4 to 12 years were examined using these methods. Their discomfort was assessed using the Wong-Baker scale and compared among the methods. Visual inspection caused less discomfort than did other methods. Radiography and the LFpen presented similar levels of discomfort. Older children reported higher discomfort using temporary separation, whereas younger children reported less discomfort with the LFpen. In conclusion, radiographic, temporary separation and LFpen methods provoke higher discomfort than visual inspection.

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Bearing pads are used in precast concrete connections to avoid concentrated stresses in the contact area between the precast elements. In the present research, the bearing pads are Portland cement mortar with styrene-butadiene latex (SB), lightweight aggregate (expanded vermiculite-term) and short fibers (polypropylene, glass and PVA), in order to obtain a material with low modulus of elasticity and high tenacity, compared with normal Portland cement mortar. The objective of this paper is to analyze the influence of surface roughness on the pads and test other types of polypropylene fibers. Tests were carried out to characterize the composite and test on bearing pads. Characterization tests show compressive strength of 41MPa and modulus of elasticity of 12.8GPa. The bearing pads tests present 30% reduction of stiffness in relation to a reference mortar. The bearing pads with roughness on both sides present a reduction up to 30% in stiffness and an increase in accumulated deformation of more than 120%, regarding bearing pads with both sides smooth.

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A proposed adequation of NBR 6118, Item 7.4, related to shear strength of reinforced concrete beams is presented with aims to application on circular cross-section. The actual expressions are most suitable to rectangular cross-section and some misleading occurs when applied to circular sections at determination of VRd2, Vc and Vsw, as consequence of bw (beam width) and d (effective depth) definitions as well as the real effectiveness of circular stirrups. The proposed adequation is based on extensive bibliographic review and practical experience with a great number of infrastructure elements, such as anchored retaining pile walls, where the use of circular reinforced concrete members is frequent.