Propriedades estruturais e eletrônicas de nanofilmes de TiO2 anatase: cálculos B3LYP-D* em sistemas periódicos bidimensionais

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Efeito de tratamentos térmicos nas propriedades mecânicas, eletroquímicas e citotoxidade de ligas do sistema Ti-15Mo-XNb

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Preparação e caracterização estrutural, mecânica e anelástica de ligas do sistema Ti-Ta contendo oxigênio intersticial, para uso biomédico

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Síntese e caracterização do compósito SnO2/TiO2 nanoestruturado

Pós-graduação em Ciência e Tecnologia de Materiais - FC

Um estudo sobre a preparação metalográfica da liga de aluminio AA7075-T6

The increasing technological innovation and demand for materials with better properties boosts research into new materials and new alloys. To do so, aluminum alloys are being developed, among them the AA7075-T6, having many applications in aerospace and military industries, machinery and equipment, molds for plastic injection and structures. To study and understand the properties, characteristics and especially the microstructure of the material, the metallographic preparation is essential. This paper presents new methodologies to achieve the metallography of samples of scrap alloy AA7075-T6, with emphasis on methods of polishing. For the five samples, the best results were those with specific grinding, the samples only going down on the sander. For polishing, the most effective method so far has been using the polishing cloth 16.3, of ATM enterprise, solution of diamond 3 μm, solution of diamond 1 μm, and colloidal solution of OP-S. For the etching, the reactive agent used was phosphoric acid (H3PO4) 85% P.A., as 90% in the proportion of distilled water to 10% acid. The best results were obtained in the attacks of 300 and 240 seconds, revealing the grain boundaries in most areas. Methodologies need more studies and more tests, but the results have proved to be satisfactory

Estudo do efeito do modificador Al-Sr no tratamento de modificação do eutético da liga AA356

The AA356 alloy is an alloy widely used in the automotive industry and aerospace due to its excellent mechanical properties. Refining the structure of eutectic silicon aluminum alloys is a fairly common practice in the foundry through treatment known as modification. This can be achieved by modifying agent adding chemicals such as contained in groups I and IIa of the periodic table and rare earths (europium, céreioi, praseodymium, neodymium, etc.). Has the ability to modify the structure of the eutectic, but only sodium and strontium produce an action modifier strong when used in low concentrations. The modifying effect of the shafts turn silicon into a fibrous form and branched surrounded by metallic matrix in the form of a composite structure that has the highest limit of tensile strength, ductility and machinability. In this work will be obtained ingots with and without the modifier type Al-10% Sr, made in sand molds and are generated and analyzed cooling curves and also the study of the macrostructure and microstructure of the solidified material. It was found that by adding the Al-Sr made shorten the solidification time and lower the grain size

Caracterização microestrutural de uma estrutura tubular aeronáutica submetida a sucessivos reparos de solda TIG

This work examines the possible effects of successive repair procedures on the microstructure of welded steel SAE 4130 by TIG welding process. Discussions and results were made about the metallographic analysis , non-metallic inclusions and microhardness tests , which were conducted on samples taken from the cradle engine component after the end of its life , a model airplane T-27 Tucano , made by EMBRAER and belonging were performed FAB . The choice of such component is due to the fact that this is critical to flight safety since it provides support for the aircraft engine . Thus regions of the weld metal , base metal and heat affected , with samples of the original weld bead , free of weld bead and also with four rework procedures for TIG welding zone were analyzed . It was found that after the fourth rework there is an increase in the amount of martensite , which may weaken the material with respect to resistance to fatigue. It was also found that the regions of the heat affected zone and weld metal have higher microhardness values when compared to those found in the base metal due to favoring the formation of ferritic and tempered martensite microstructures . Moreover, a welding process promotes a region with less non-metallic inclusions than metal base , which also explains the difference in the results obtained

Implementação de um tuboexpansor na refinaria do Planalto Paulista – REPLAN com objetivo do aproveitamento da energia contida nos gases residuais do FCC – Fluid Catalytic Cracking na geração de energia elétrica

The steel type AISI 4130 (ultra-high strength steel) is an alloy of low carbon and its main alloying elements are chromium and molybdenum, which improves the toughness of the weld metal. It has numerous applications, especially where the need for high mechanical strength. It is widely used in equipment used by the aviation industry, such as cradle-tomotor, and this is the motivation for this study. Cots are of fundamental importance, because the engine supports and maintains balance in the fixed landing gear. This equipment is subjected to intense loading cycles, whose fractures caused by fatigue are constantly observed. Will be determined the effects caused by re-welding the structure of aeronautical equipment, and will also study the microstructure of the metal without welding. The studies will be done on materials used in aircraft, which was given to study. The results provide knowledge of microstructure to evaluate any type of fracture that maybe caused by fatigue. Fatigue is a major cause of aircraft accidents and incidents occurred, which makes the study of the microstructure of the metal, weld and re-solder the knowledge essential to the life of the material. The prevention and control of the process of fatigue in aircraft are critical, since the components are subjected to greater responsibility cyclic loading

Alterações microestruturais decorrentes dos sucessivos reparos de solda TIG aplicados ao longo da vida útil de uma estrutura aeronáutica crítica à segurança de vôo

The steel type AISI 4130 (ultra-high strength steel) is an alloy of low carbon and its main alloying elements are chromium and molybdenum, which improves the toughness of the weld metal. It has numerous applications, especially where the need for high mechanical strength. It is widely used in equipment used by the aviation industry, such as cradle-tomotor, and this is the motivation for this study. Cots are of fundamental importance, because the engine supports and maintains balance in the fixed landing gear. This equipment is subjected to intense loading cycles, whose fractures caused by fatigue are constantly observed. Will be determined the effects caused by re-welding the structure of aeronautical equipment, and will also study the microstructure of the metal without welding. The studies will be done on materials used in aircraft, which was given to study. The results provide knowledge of microstructure to evaluate any type of fracture that maybe caused by fatigue. Fatigue is a major cause of aircraft accidents and incidents occurred, which makes the study of the microstructure of the metal, weld and re-solder the knowledge essential to the life of the material. The prevention and control of the process of fatigue in aircraft are critical, since the components are subjected to greater responsibility cyclic loading

Mapeamento geológico e petrologia dos complexos máfico-ultramáficos de Mangabal Sul e Mangabal Norte, região de Sanclerlândia, Goiás

The Mangabal Sul and Mangabal Norte mafic-ultramafic complexes are interpreted as intrusive stratiform bodies in the Goiás Magmatic Arc during the Brazilian cycle, being economically important for harboring significant amounts of nickel and copper sulfides. The main lithotypes of the complexes are gabbronorites, olivine gabbronorites, pyroxenites and peridotites, with variated degrees of deformation, recrystallization and metamorphism superimposed, with metamorphic peak of amphibolite to granulite facies evidenced mainly by the occurrence of coronitic olivine in metamafic rocks and the occurrence of syn-kinematic retrometamorphism associated with the development of the main foliation Sn. The Sn foliation planes show NE-SW preferential direction, consistent with the foliation direction of VIII the enclosing gneisses and schists, also concordant with the general elongation of mafic and ultramafic bodies displayed on map. The sulfide phase presents textures that indicate remobilization, associated with the occurrence of significant amounts of rutile within the ore which reinforces this idea. Along with the sulfides, the occurrence of expressive quantities of titanium oxides such as ilmenite and rutile, make the area more economically attractive. It can be suggested that the Mangabal Norte and Mangabal Sul complexes are contemporary, have the same genetic affinity and suffered the same deformational and metamorphic processes, evidenced by their structural and petrological similarities

Desenvolvimento de aplicativo de análise técnica e econômica para adaptação de uma roda d’água acionada por cima para geração de energia elétrica no meio rural

The steel type AISI 4130 (ultra-high strength steel) is an alloy of low carbon and its main alloying elements are chromium and molybdenum, which improves the toughness of the weld metal. It has numerous applications, especially where the need for high mechanical strength. It is widely used in equipment used by the aviation industry, such as cradle-tomotor, and this is the motivation for this study. Cots are of fundamental importance, because the engine supports and maintains balance in the fixed landing gear. This equipment is subjected to intense loading cycles, whose fractures caused by fatigue are constantly observed. Will be determined the effects caused by re-welding the structure of aeronautical equipment, and will also study the microstructure of the metal without welding. The studies will be done on materials used in aircraft, which was given to study. The results provide knowledge of microstructure to evaluate any type of fracture that maybe caused by fatigue. Fatigue is a major cause of aircraft accidents and incidents occurred, which makes the study of the microstructure of the metal, weld and re-solder the knowledge essential to the life of the material. The prevention and control of the process of fatigue in aircraft are critical, since the components are subjected to greater responsibility cyclic loading

Caracterização da liga do sistema binário Ti-15Mo para aplicações biomedicas

As they have excellent mechanical properties, corrosion resistance and biocompatibility, much research has been conducted with respect to biomedical applications of titanium alloys. This work aims to study the experimental system binary alloy Ti-15Mo, in the raw state of fusion and heat treatment after homogenization, solubilization and calcination (simulating conditions employed for nanotube growth) targeting biomedical applications. Samples were obtained by casting the components in an electric arc furnace with inert atmosphere of argon. After obtaining the alloy, it was heat treated at three different heat treatments, namely homogenizing, calcining and simulation solubilization. The phases present were analyzed by X-ray diffraction, optical microscopy and microhardness testing

Sintese e caracterização do compósito TixOy- MWCNT para fotodegradação de carbaril

In this study, a composite of titanium oxide (TixOy) and carbon nanotubes multi-walled (MWCNT) was synthesized on a titanium substrate using the sol-gel method. The electrode obtained (TixOy-MWCNT/Ti) was used to the photodegradation of Carbaryl. The morphology and structure of the TixOy-MWCNT composite were characterized by scanning electron microscopy (SEM), scanning electron microscopy by field emission (FEG-SEM) and X-ray diffraction (XRD). The electrode was evaluated for degradation of Carbaryl (0.9 mmol L-1) in phosphate buffer pH 6, and using chronoamperometry by applying a potential of +1,5 V for 1 h. Using the Ultraviolet-Visible test, the absorbance at 220 nm was collected every 15 min to calculate the percentage of Cabaryl´s degradation. Can be evaluated that the Carbaryl degradation using the TixOy-MWCNT/Ti electrode was 22% more efficient when compared with the electrode without the presence of titanium oxides (MWCNT / Ti)

Caracterização estrutural da Liga Al-1% Si

The aim of this study is to characterize the macrostructure and microstructure of Al - 1%Si alloy obtained in sand and metallic molds. Aluminium has good mechanical properties, but adding silicon, even in small quantities, can change the microstructure and improves mechanical behavior. Workpieces were castings in metallic and sand molds and one can see a difference in their cooling curve, macroscopic and microscopic structures. The sand mold casting has lower cooling rate and so its grains are larger. Due to the lower concentration of grain boundary, the hardness is lower compared to that found in metallic molds, which has smaller grains and a higher hardness. Therefore, it can be concluded that the cooling rate and alloying elements affect the final microstructure of the workpiece

Incorporação da apatita na superfície da liga Ti30ta empregando tratamento alcalino associado à eletrofiação de fibras de PCL

Pós-graduação em Engenharia Mecânica - FEG