Ensayos acelerados de fiabilidad de células solares de concentración

SUMMARY Concentration Photovoltaic Systems (CPV) have been proposed as an alternative to conventional systems. During the last years, there has been a boom of the CPV industry caused by the technological progress in all the elements of the system. and mainly caused by the use of multijunction solar cells based on III-V semiconductors, with efficiencies exceeding to 43%. III-V solar cells have been used with high reliability results in a great number of space missions without concentration. However, there are no previous results regarding their reliability in concentration terrestrial applications, where the working conditions are completely different. This lack of experience, together with the important industrial interest, has generated the need to evaluate the reliability of the cells. For this reason, nowadays there are several research centers around the undertaking this task. The evaluation of the reliability of this type of devices by means of accelerated tests is especially problematic when they work at medium or high concentration, because it is practically impossible to emulate real working conditions of the cell inside climatic chambers. In fact, as far as we know, the results that appear in this Thesis are the first estimating the Activation Energy of the failure mechanism involved, as well as the warranty of the III-V concentrator solar cells tested here. To evaluate the reliability of III-V very high concentrator solar cells by means of accelerated tests, a variety of activities, described in this Thesis have been carried out. The First Part of the memory presents the theoretical part of the Doctoral Thesis. After the Introduction, chapter 2 presents the state of the art in degradation and reliability of CPV systems and solar cells. Chapter 3 introduces some reliability definitions and the application of specific statistical functions to the evaluation of the reliability and parameters. From these functions, important parameters will be calculated to be used later in the experimental results of Thesis. The Second Part of the memory contains the experimental. Chapter 4 shows the types of accelerated tests and the main goals pursuit with them when carried out over CPV systems and solar cells. In order to evaluate quantitatively the reliability of the III-V concentrator solar cells used in these tests, some modifications have been introduced which discussion will be tackled here. Based on this analysis the working plan of the tests carried out in this Doctoral Thesis is presented. Chapter 5 presents a new methodology as well as the necessary instrumentation to carry out the tests described here. This new methodology takes into account the adaptation, improvement and novel techniques needed to test concentrator solar cells. The core of this memory is chapter 6, which presents the results of the characterization of the cells during the accelerated life tests and the analysis of the aforementioned results with the purpose of getting quantitative values of reliability in real working conditions. The acceleration factor of the accelerated life tests, under nominal working conditions has been calculated. Accordingly, the validity of the methodology as well as the calculations based on the reliability assessment, have also been demonstrated. Finally, quantitative values of degradation, reliability and warranty of the solar cells under field nominal working conditions have been calculated. With the development of this Doctoral Thesis the reliability of very high concentrator GaAs solar cells of small area has been evaluated. It is very interesting to generalize the procedures described up to this point to III-V multijunction solar cells of greater area. Therefore, chapter 7 develops this generalization and introduces also a useful thermal modeling by means of finite elements of the test cells’ circuits. In the last chapter, the summary of the results and the main contributions of this Thesis are outlined and future research activities are identified. RESUMEN Los Sistemas Fotovoltaicos de Concentración (SFC) han sido propuestos como una alternativa a los sistemas convencionales de generación de energía. Durante los últimos años ha habido un auge de los SFC debido a las mejoras tecnológicas en todos los elementos del sistema, y principalmente por el uso de células multiunión III-V que superan el 43% de rendimiento. Las células solares III-V han sido utilizadas con elevada fiabilidad en aplicaciones espaciales sin concentración, pero no existe experiencia de su fiabilidad en ambiente terrestre a altos niveles de concentración solar. Esta falta de experiencia junto al gran interés industrial ha generado la necesidad de evaluar la fiabilidad de las células, y actualmente hay un significativo número de centros de investigación trabajando en esta área. La evaluación de la fiabilidad de este tipo de dispositivos mediante ensayos acelerados es especialmente problemática cuando trabajan a media o alta concentración por la casi imposibilidad de emular las condiciones de trabajo reales de la célula dentro de cámaras climáticas. De hecho, que sepamos, en los resultados de esta Tesis se evalúa por primera vez la Energía de Activación del mecanismo de fallo de las células, así como la garantía en campo de las células de concentración III-V analizadas. Para evaluar la fiabilidad de células solares III-V de muy alta concentración mediante ensayos de vida acelerada se han realizado diversas actividades que han sido descritas en la memoria de la Tesis. En la Primera Parte de la memoria se presenta la parte teórica de la Tesis Doctoral. Tras la Introducción, en el capítulo 2 se muestra el estado del arte en degradación y fiabilidad de células y Sistemas Fotovoltaicos de Concentración. En el capítulo 3 se exponen de forma resumida las definiciones de fiabilidad y funciones estadísticas que se utilizan para la evaluación de la fiabilidad y sus parámetros, las cuales se emplearán posteriormente en los ensayos descritos en este Tesis. La Segunda Parte de la memoria es experimental. En el capítulo 4 se describen los tipos y objetivos de los ensayos acelerados actualmente aplicados a SFC y a las células, así como las modificaciones necesarias que permitan evaluar cuantitativamente la fiabilidad de las células solares de concentración III-V. En base a este análisis se presenta la planificación de los trabajos realizados en esta Tesis Doctoral. A partir de esta planificación y debido a la necesidad de adaptar, mejorar e innovar las técnicas de ensayos de vida acelerada para una adecuada aplicación a este tipo de dispositivos, en el capítulo 5 se muestra la metodología empleada y la instrumentación necesaria para realizar los ensayos de esta Tesis Doctoral. El núcleo de la memoria es el capítulo 6, en él se presentan los resultados de caracterización de las células durante los ensayos de vida acelerada y el análisis de dichos resultados con el objetivo de obtener valores cuantitativos de fiabilidad en condiciones reales de trabajo. Se calcula el Factor de Aceleración de los ensayos acelerados con respecto a las condiciones nominales de funcionamiento a partir de la Energía de Activación obtenida, y se demuestra la validez de la metodología y cálculos empleados, que son la base de la evaluación de la fiabilidad. Finalmente se calculan valores cuantitativos de degradación, fiabilidad y garantía de las células en condiciones nominales en campo durante toda la vida de la célula. Con el desarrollo de esta Tesis Doctoral se ha evaluado la fiabilidad de células III-V de área pequeña, pero es muy interesante generalizar los procedimientos aquí desarrollados para las células III-V comerciales de área grande. Por este motivo, en el capítulo 7 se analiza dicha generalización, incluyendo el modelado térmico mediante elementos finitos de los circuitos de ensayo de las células. En el último capítulo se realiza un resume del trabajo y las aportaciones realizadas, y se identifican las líneas de trabajo a emprender en el futuro.

Improvement of compatibility and stability on polyethylene-modified bitumen by use of an aromatic extra as compatibilizer.

Bitumen modification by polyethylene addition usually improves the mechanical properties of the binder and, therefore, the behavior in service of the bituminous mix: thermal susceptibility and rutting can be diminished, whilst the resistance to low temperature cracking may increase. To achieve this improvement it is necessary a good compatibility between the base bitumen and the polyethylene. Low compatibility between bitumen and polyethylene can lead to phase separation: the polymer- asphalt incompatibility translates into a deterioration of ultimate properties. The object of this research project was to determine if these problems can be diminished by using certain compatibilizer agents, e.g. an aromatic extract from the oil refinery. Compatibility and stability of the polyethylene modified bitumen were studied using conventional test methods and dynamic shear reometer (DSR). Blends of bitumen and polyethylene were prepared with neat bitumen (PMB) or bitumen with compatibilizer as component of the binder (PMBC) and then compared. The experimental results show that “colloid instability index”(IC) is a parameter that can be used to control the compatibility between bitumen and polyethylene. From polyethylene point of view, one of the parameters that govern is the “melt flow index” (MFI). Experimental results show that PMBC formulated with low IC bitumen and hi gh MFI lineal polyethylene can be considered as stable binder.

Simulation Tool and Case Study for Planning Wireless Sensor Network

In this paper, a simulation tool for assisting the deployment of wireless sensor network is introduced and simulation results are verified under a specific indoor environment. The simulation tool supports two modes: deterministic mode and stochastic mode. The deterministic mode is environment dependent in which the information of environment should be provided beforehand. Ray tracing method and deterministic propagation model are employed in order to increase the accuracy of the estimated coverage, connectivity and routing; the stochastic mode is useful for large scale random deployment without previous knowledge on geographic information. Dynamic Source Routing protocol (DSR) and Ad hoc On-Demand Distance Vector Routing protocol (AODV) are implemented in order to calculate the topology of WSN. Hence this tool gives direct view on the performance of WSN and assists users in finding the potential problems of wireless sensor network before real deployment. At the end, a case study is realized in Centro de Electronica Industrial (CEI), the simulation results on coverage, connectivity and routing are verified by the measurement.

Desarrollo de aplicaciones de comunicaciones inalámbricas en sistemas de monitorización estructural desarrollados en aeronáutica.

Los Sistemas de SHM o de monitorización de la integridad estructural surgen ante la necesidad de mejorar los métodos de evaluación y de test no destructivos convencionales. De esta manera, se puede tener controlado todo tipo de estructuras en las cuales su correcto estado o funcionamiento suponga un factor crítico. Un Sistema SHM permite analizar una estructura concreta capturando de manera periódica el estado de la integridad estructural, que en este proyecto se ha aplicado a estructuras aeronáuticas. P.A.M.E.L.A. (Phase Array Monitoring for Enhanced Life Assessment) es la denominación utilizada para definir una serie de equipos electrónicos para Sistemas SHM desarrollados por AERNOVA y los Grupos de Diseño Electrónico de las universidades UPV/EHU y UPM. Los dispositivos P.A.M.E.L.A. originalmente no cuentan con tecnología Wi-Fi, por lo que incorporan un módulo hardware independiente que se encarga de las comunicaciones inalámbricas, a los que se les denomina Nodos. Estos Nodos poseen un Sistema Operativo propio y todo lo necesario para administrar y organizar la red Mallada Wi-Fi. De esta manera se obtiene una red mallada inalámbrica compuesta por Nodos que interconectan los Sistemas SHM y que se encargan de transmitir los datos a los equipos que procesan los resultados adquiridos por P.A.M.E.L.A. Los Nodos son dispositivos empotrados que llevan instalados un firmware basado en una distribución de Linux para Nodos (o Routers), llamado Openwrt. Que para disponer de una red mallada necesitan de un protocolo orientado a este tipo de redes. Entre las opciones de protocolo más destacadas se puede mencionar: DSDV (Destination Sequenced Distance Vector), OLSR (Optimized Link State Routing), B.A.T.M.A.N-Adv (Better Approach To Mobile Adhoc Networking Advance), BMX (una versión de B.A.T.M.A.N-Adv), AODV (Ad hoc On-Demand Distance Vector) y el DSR (Dynamic Source Routing). Además de la existencia de protocolos orientados a las redes malladas, también hay organizaciones que se dedican a desarrollar firmware que los utilizan, como es el caso del firmware llamado Nightwing que utiliza BMX, Freifunk que utiliza OLSR o Potato Mesh que utiliza B.A.T.M.A.N-Adv. La ventaja de estos tres firmwares mencionados es que las agrupaciones que las desarrollan proporcionan las imágenes precompiladas del sistema,listas para cargarlas en distintos modelos de Nodos. En este proyecto se han instalado las imágenes en los Nodos y se han probado los protocolos BMX, OLSR y B.A.T.M.A.N.-Adv. Concluyendo que la red gestionada por B.A.T.M.A.N.-Adv era la que mejor rendimiento obtenía en cuanto a estabilidad y ancho de banda. Después de haber definido el protocolo a usar, se procedió a desarrollar una distribución basada en Openwrt, que utilice B.A.T.M.A.N.-Adv para crear la red mallada, pero que se ajuste mejor a las necesidades del proyecto, ya que Nightwing, Freifunk y Potato Mesh no lo hacían. Además se implementan aplicaciones en lenguaje ANSI C y en LabVIEW para interactuar con los Nodos y los Sistemas SHM. También se procede a hacer alguna modificación en el Hardware de P.A.M.E.L.A. y del Nodo para obtener una mejor integración entre los dos dispositivos. Y por ultimo, se prueba la transferencia de datos de los Nodos en distintos escenarios. ABSTRACT. Structural Health Monitoring (SHM) systems arise from the need of improving assessment methods and conventional nondestructive tests. Critical structures can be monitored using SHM. A SHM system analyzes periodically a specific structure capturing the state of structural integrity. The aim of this project is to contribute in the implementation of Mesh network for SHM system in aircraft structures. P.A.M.E.L.A. (Phase Array Monitoring for Enhanced Life Assessment) is the name for electronic equipment developed by AERNOVA, the Electronic Design Groups of university UPV/EHU and the Instrumentation and Applied Acoustics research group from UPM. P.A.M.E.L.A. devices were not originally equipped with Wi-Fi interface. In this project a separate hardware module that handles wireless communications (nodes) has been added. The nodes include an operating system for manage the Wi-Fi Mesh Network and they form the wireless mesh network to link SHM systems with monitoring equipment. Nodes are embedded devices with an installed firmware based on special Linux distribution used in routers or nodes, called OpenWRT. They need a Mesh Protocol to stablish the network. The most common protocols options are: DSDV (Destination Sequenced Distance Vector), OLSR (Optimized Link State Routing), BATMAN-Adv (Better Approach To Mobile Ad-hoc Networking Advance), BMX (a version of BATMAN-Adv) AODV (Ad hoc on-Demand Distance Vector) and DSR (Dynamic Source Routing). In addition, there are organizations that are dedicated to develope firmware using these Mesh Protocols, for instance: Nightwing uses BMX, Freifunk use OLSR and Potato Mesh uses BATMAN-Adv. The advantage of these three firmwares is that these groups develop pre-compiled images of the system ready to be loaded in several models of Nodes. In this project the images were installed in the nodes. In this way, BMX, OLSR and BATMAN-Adv have been tested. We conclude that the protocol BATMAN-Adv has better performance in terms of stability and bandwidth. After choosing the protocol, the objective was to develop a distribution based on OpenWRT, using BATMAN-Adv to create the mesh network. This distribution is fitted to the requirements of this project. Besides, in this project it has been developed applications in C language and LabVIEW to interact with the Nodes and the SHM systems. The project also address some modifications to the PAMELA hardware and the Node, for better integration between both elements. Finally, data transfer tests among the different nodes in different scenarios has been carried out.

Desnervação simpática renal e sua utilização no tratamento da hipertensão resistente : caso clínico

Trabalho Final do Curso de Mestrado Integrado em Medicina, Faculdade de Medicina, Universidade de Lisboa, 2014

Abundance and biomass of protozooplankton from the iron-induced phytoplankton bloom during the EisenEx experiment in 2000 in the Southern Ocean

The responses of larger (>50 µm in diameter) protozooplankton groups to a phytoplankton bloom induced by in situ iron fertilization (EisenEx) in the Polar Frontal Zone (PFZ) of the Southern Ocean in austral spring are presented. During the 21 days of the experiment, samples were collected from seven discrete depths in the upper 150 m inside and outside the fertilized patch for the enumeration of acantharia, foraminifera, radiolaria, heliozoa, tintinnid ciliates and aplastidic thecate dinoflagellates. Inside the patch, acantharian numbers increased twofold, but only negligibly in surrounding waters. This finding is of major interest, since acantharia are suggested to be involved in the formation of barite (BaSO_4 ) found in sediments and which is a palaeoindicator of both ancient and modern high productivity regimes. Foraminifera increased significantly in abundance inside and outside the fertilized patch. However the marked increase of juveniles after a full moon event suggests a lunar periodicity in the reproduction cycle of some foraminiferan species rather than a reproductive response to enhanced food availability. In contrast, adult radiolaria showed no clear trend during the experiment, but juveniles increased threefold indicating elevated reproduction. Aplastidic thecate dinoflagellates almost doubled in numbers and biomass, but also increased outside the patch. Tintinnid numbers decreased twofold, although biomass remained constant due to a shift in the size spectrum. Empty tintinnid loricae, however, increased by a factor of two indicating that grazing pressure on this group mainly by copepods intensified during EisenEx. The results show that iron-fertilization experiments can shed light on the biology and the role of these larger protists in pelagic ecosystem which will improve their use as proxies in palaeoceanography.