Composition of carbonaceous sediments from the Late Jurassic Volgian Basin of the East European Platform (Kostroma Region, Russia)

Lithological, geochemical, stratigraphic, and paleoecological features of carbonaceous sediments in the Late Jurassic Volgian Basin of the East European Platform (Kostroma Region) are considered. The shale-bearing sequence studied is characterized by greater sedimentological completeness as compared with its stratotype sections in the Middle Volga region (Gorodishche, Kashpir). Stratigraphic position and stratigraphy of the shale-bearing sequence, as well as distribution of biota in different sedimentation settings are specified. It is shown that Volgian sediments show distinct cyclic structure. The lower and upper elements of cyclites consist of high-carbonaceous shales and clayey-calcareous sediments, respectively, separated by transitional varieties. Bioturbation structures in different rocks are discussed. Microcomponent composition and pyrolytic parameters of organic matter, as well as distribution of chemical elements in lithologically variable sediments are analyzed. Possible reasons responsible for appearance of cyclicity and accumulation of organic-rich sediments are discussed.

Miocene to Pleistocene sedimentation at ODP Site 133-823

More than 2000 turbidite, debris-flow, and slump deposits recovered at Site 823 record the history of the Queensland Trough since the middle Miocene and provide new insights about turbidites, debris flow, and slump deposits (herein termed gravity deposits). Changes in the composition and nature of gravity deposits through time can be related to tectonic movements, fluctuations in eustatic sea level, and sedimentological factors. The Queensland Trough is a long, relatively narrow, structural depression that formed as a result of Cretaceous to Tertiary rifting of the northeastern Australia continental margin. Thus, tectonics established the geometry of this marginal basin, and its steep slopes set the stage for repeated slope failures. Seismic data indicate that renewed faulting, subsidence, and associated tectonic tilting occurred during the early late Miocene (continuing into the early Pliocene), resulting in unstable slopes that were prone to slope failures and to generation of gravity deposits. Tectonic subsidence, together with a second-order eustatic highstand, resulted in platform drowning during the late Miocene. The composition of turbidites reflects their origin and provides insights about the nature of sedimentation on adjacent shelf areas. During relative highstands and times of platform drowning, planktonic foraminifers were reworked from slopes and/or drowned shelves and were redeposited in turbidites. During relative lowstands, quartz and other terrigenous sediment was shed into the basin. Quartzose turbidites and clay-rich hemipelagic muds also can record increased supply of terrigenous sediment from mainland Australia. Limestone fragments were eroded from carbonate platforms until the drowned platforms were buried under hemipelagic sediments following the late Miocene drowning event. Bioclastic grains and neritic foraminifers were reworked from neritic shelves during relative lowstands. During the late Pliocene (2.6 Ma), the increased abundance of bioclasts and quartz in turbidites signaled the shallowing and rejuvenation of the northeastern Australia continental shelf. However, a one-for-one relationship cannot be recognized between eustatic sea-level fluctuations and any single sedimentologic parameter. Perhaps, tectonism and sedimentological factors along the Queensland Trough played an equally important role in generating gravity deposits. Turbidites and other gravity deposits (such as those at Site 823) do not necessarily represent submarine fan deposits, particularly if they are composed of hemipelagic sediments reworked from drowned platforms and slopes. When shelves are drowned and terrigenous sediment is not directly supplied by nearby rivers/point sources, muddy terrigenous sediments blanket the entire slope and basin, rather than forming localized fans. Slope failures affect the entire slope, rather than localized submarine canyons. Slopes may become destabilized as a result of tectonic activity, inherent sediment weaknesses, and/or during relative sea-level lowstands. For this reason, sediment deposits in this setting reflect tectonic and eustatic events that caused slope instabilities, rather than migration of different submarine fan facies.

Sediment composition and sedimentation rates of four Holes in ODP Leg 166

To date, work on the Great Bahama Bank's western, leeward margin has centred chiefly on seismic-scale expressions of carbonate sequences and systems tracts. However, periplatform, slope sediments also exhibit very well developed cyclicity on scales of decimetres to several metres. It is these small-scale, high-frequency cycles within the larger-scale facies successions of the Quaternary which form the main topic of this paper. Previous studies have shown that the small-scale cycles correlate to the orbitally forced, high-frequency sea-level changes. Therefore these cycles should indicate how sea level has affected the slope development and thus platform-margin evolution during this period. Through detailed, high-resolution sequence stratigraphy of the Great Bahama Bank's leeward margin, obtained via delta18O isotope and mineralogical (XRD) analyses, confined by U/Th dating and nannofossil bioevents, a greater understanding of the bedding geometries within the Pleistocene-Holocene seismic sequences and clues as to the nature of the slope development has been achieved. The high-resolution seismic profiles indicate that since the Plio-Pleistocene change in geometry, in which the Great Bahama Bank developed into a rimmed platform, continued steepening and subsequent progradation of the leeward margin has typified slope development during the Quaternary, which is described as an accretionary slope. However, on the basis of our observations we conclude that only the early to lower middle Pleistocene section (isotope stages 45-20) and the Holocene (isotope stage 1) of the leeward margin is accretionary. This indicates that a degree of erosion and/or by-passing has occurred on the leeward margin since the lower middle Pleistocene (isotope stage 19). During the first part of this period (isotope stages 19-12) erosion and/or by-passing occurred in the middle to lower slope regions and toe-of-slope. By the end of the upper middle to late Pleistocene phase (isotope stages 11-2) erosion also occurred on the upper slope. This erosion by currents at the toe-of-slope and oversteepening of the upper and middle slopes have led to back-cutting upslope and resulted in the progressive retreat of the toe-of-slope towards the platform to the east. However, the rise in sea level since the Last Glacial Maximum to its present-day level has allowed high productivity on the platform top during the Holocene and the deposition of a thick sediment wedge on the slope and sedimentation across the entire leeward flanks. This has led to the redevelopment of an accretionary slope and continued westward progradation of the Great Bahama Bank's western, leeward margin.

Present-day King George Island ice cap geometry measured by ground penetrating radar in 2008/09

We present a consistent data set for the ice thickness, the bedrock topography and the ice surface topography of the King George Island ice cap (Arctowski Icefield and the adjacent central part). The data set is composed of groundbased and airborne Ground Penetrating Radar (GPR) and differential GPS (DGPS) measurements, obtained during several field campaigns. The data set incorporates groundbased measurements in the safely accessible inner parts and airborne measurements in the heavily crevassed coastal areas of the ice cap. In particular, the inclusion of airborne GPR measurements with the 30MHz BGR-P30-System developed at the Institute of Geophysics (University of Münster) completes the picture of the ice geometry substantially. The compiled digital elevation model of the bedrock shows a rough, highly variable topography with pronounced valleys, ridges, and troughs. The mean ice thickness is approx. 238m, with a maximum value of approx. 400m in the surveyed area. Noticeable are bounded areas in the bedrock topography below sea level where marine based ice exists.

Effects of pCO2 and iron on the elemental composition and cell geometry of the marine diatom Pseudo-nitzschia pseudodelicatissima//(Bacillariophyceae)

Partial pressure of CO2 (pCO2) and iron availability in seawater show corresponding changes due to biological and anthropogenic activities. The simultaneous change in these factors precludes an understanding of their independent effects on the ecophysiology of phytoplankton. In addition, there is a lack of data regarding the interactive effects of these factors on phytoplankton cellular stoichiometry, which is a key driving factor for the biogeochemical cycling of oceanic nutrients. Here, we investigated the effects of pCO2 and iron availability on the elemental composition (C, N, P, and Si) of the diatom Pseudo-nitzschia pseudodelicatissima (Hasle) Hasle by dilute batch cultures under 4 pCO2 (~200, ~380, ~600, and ~800 µatm) and five dissolved inorganic iron (Fe'; ~5, ~10, ~20, ~50, and ~100 pmol /L) conditions. Our experimental procedure successfully overcame the problems associated with simultaneous changes in pCO2 and Fe' by independently manipulating carbonate chemistry and iron speciation, which allowed us to evaluate the individual effects of pCO2 and iron availability. We found that the C:N ratio decreased significantly only with an increase in Fe', whereas the C:P ratio increased significantly only with an increase in pCO2. Both Si:C and Si:N ratios decreased with increasing pCO2 and Fe'. Our results indicate that changes in pCO2 and iron availability could influence the biogeochemical cycling of nutrients in future oceans with high- CO2 levels, and, similarly, during the time course of phytoplankton blooms. Moreover, pCO2 and iron availability may also have affected oceanic nutrient biogeochemistry in the past, as these conditions have changed markedly over the Earth's history.

Sedimentary and subsidence history of ODP Sites 135-840 and 135-841

Sedimentary sections recovered from the Tonga platform and forearc during Ocean Drilling Program Leg 135 provide a record of the sedimentary evolution of the active margin of the Indo-Australian Plate from late Eocene time to the Present. Facies analyses of the sediments, coupled with interpretations of downhole Formation MicroScanner logs, allow the complete sedimentary and subsidence history of each site to be reconstructed. After taking into account the water depths in which the sediments were deposited and their subsequent compaction, the forearc region of the Tofua Arc (Site 841) can be seen to have experienced an initial period of tectonic subsidence dating from 35.5 Ma. Subsidence has probably been gradual since that time, with possible phases of accelerated subsidence, starting at 16.2 and 10.0 Ma. The Tonga Platform (Site 840) records only the last 7.0 Ma of arc evolution. However, the increased accuracy of paleowater depth determinations possible with shallow-water platform sediments allows the resolution of a distinct increase in subsidence rates at 5.30 Ma. Thus, sedimentology and subsidence analyses show the existence of at least two, and possibly four, separate subsidence events in the forearc region. Subsidence dating from 35.5 Ma is linked to rifting of the South Fiji Basin. Any subsidence dating from 16.2 Ma at Site 841 does not correlate with another known tectonic event and is perhaps linked to localized extensional faulting related to slab roll back during steady-state subduction. Subsidence from 10.0 Ma coincides with the breakup of the early Tertiary Vitiaz Arc because of the subduction polarity reversal in the New Hebrides and the subsequent readjustment of the plate boundary geometry. More recently, rapid subsidence and deposition of a upward-fining cycle from 5.30 Ma to the Present at Site 840 is thought to relate to rifting of the Lau Basin. Sedimentation is principally controlled by tectonic activity, with variations in eustatic sea level playing a significant, but subordinate role. Subduction of the Louisville Seamount Chain seems to have disrupted the forearc region locally, although it had only a modest effect on the subsidence history and sedimentation of the Tonga Platform as a whole.

Late Pleistocene sediment record of the Maldives carbonate platform

A piston core from the Maldives carbonate platform was investigated for carbonate mineralogy, grain-size distributions, calcium carbonate content and organic carbon. The sedimentary record was linked to Late Pleistocene sea-level variations, using an age model based on oxygen isotopes obtained from planktonic foramanifera, nannofossil biostratigraphy and 14C age determinations. The correlation between the sedimentary record and Late Pleistocene sea-level showed that variations in aragonite and mud during the past 150 000 years were clearly related to flooding and sea floor exposure of the main lagoons of the atolls of the Maldives carbonate platform. Platform flooding events were characterized by strongly increased deposition of aragonite and mud within the Inner Sea of the Maldives. Exposure events, in contrast, can be recognized by rapid decreases in the values of both proxy records. The results show that sediments on the Maldives carbonate platform contain a continuous record of Pleistocene sea-level variations. These sediments may, therefore, contribute to a better understanding of regional and even global sea-level changes, and yield new insights into the interplay between ocean currents and carbonate platform morphology.

Boron, carbonate carbon and oxygen isotope analyses of samples from the Yangtze Platform (China), Congo craton (Namibia), and Karatau microcontinent (Kazakhstan) of the Marinoan glaciation

Boron isotope patterns preserved in cap carbonates deposited in the aftermath of the younger Cryogenian (Marinoan, ca. 635 Ma) glaciation confirm a temporary ocean acidification event on the continental margin of the southern Congo craton, Namibia. To test the significance of this acidification event and reconstruct Earth's global seawater pH states at the Cryogenian-Ediacaran transition, we present a new boron isotope data set recorded in cap carbonates deposited on the Yangtze Platform in south China and on the Karatau microcontinent in Kazakhstan. Our compiled d11B data reveal similar ocean pH patterns for all investigated cratons and confirm the presence of a global and synchronous ocean acidification event during the Marinoan deglacial period, compatible with elevated postglacial pCO2 concentrations. Differences in the details of the ocean acidification event point to regional distinctions in the buffering capacity of Ediacaran seawater.