Modelagem e simulação de sistemas de geração de energia para o setor de petróleo e gás

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Capacidade de Uso das Terras da Bacia do Ribeirão Água Fria – Bofete (SP)

A determinação da capacidade de uso das terras numa bacia é muito importante para o planejamento e uso do solo, pois o uso inadequado e sem planejamento dessas terras provocam a baixa produtividade das culturas. Este trabalho visou definir as classes homogêneas de capacidade de uso da terra da bacia do Ribeirão Água Fria - Bofete (SP) para atender ao planejamento de práticas de conservação do solo desta área. A bacia situa-se entre as coordenadas geográficas 22o 58' 30`` a 23o 04' 30`` de latitude S e 48o 09' 30`` a 48o 18' 30`` de longitude W Gr., apresentando uma área de 9.180,12 hectares. A carta de capacidade de uso da terra da bacia foi elaborada a partir da carta clinográfica obtida por Santos et al. (1999), mapa pedológico do Estado de São Paulo (Oliveira et al., 1999), da tabela de julgamento de classes de capacidade de uso do solo (França, 1963) e das recomendações constantes no manual para levantamento utilitário do meio físico e classificação das terras no sistema de capacidade de uso (Lepsch et al., 1983). A discriminação, o mapeamento e a quantificação das áreas das classes e subclasses de capacidade de uso pelo Sistema de Informação Geográfica - IDRISI apresentaram os seguintes valores: IIIe,s - 517,020 ha (5,63%); IIIs - 863,150 ha (9,40%); IVe - 846,730 ha (9,23%); VIe - 871,110 ha (9,49%) e VIIe - 6082,115 ha (66,25%). Os resultados permitiram concluir que a bacia essencialmente constituída por 2/3 pela subclasse VIIe, ou seja, são terras que podem ser utilizadas por pastagens com uso moderado ou florestas, pois apresentam problemas complexos de erosão por causa de sua declividade. O Sistema de Informação Geográfica IDRISI permitiu através de seus módulos discriminar, mapear e quantificar as áreas das classes e subclasses de capacidade de uso das terras da bacia com rapidez e confiabilidade.

Processo eletrolítico em efluente de refinaria de petróleo utilizando eletrodos de ti/tiruo2 e/ou fe/tiruo2

Consiste de uma modalidade de tratamento de efluentes líquidos de refinaria de petróleo que pode ser usado isoladamente ou preferencialmente e mais eficazmente de forma complementar e anterior ao tratamento biológico que utiliza-se de eletrodos óxidos do Ti/TiRuO~ 2~ E/OU Fe/TiRuO~ 2~ os quais atuam no processo de conversão ou combustão eletroquímica de substâncias persistentes ou tóxicas presentes nestes entes, particularmente fenol, amónia, nitrito e cloreto em outras substâncias mais degradáveis e menos tóxicas...

Emissão luminescente no titanato de cálcio dopado com íons de terras-raras

Through the polymeric precursor method were synthesized samples Ca0.98Sr0.01X0.01TiO3 (X= Eu3+, Sm3+ and Pr3+), which under different heat treatments were obtained with levels of distinct structural order-disorder. The synthesized materials were characterized by X-ray diffraction, confirming the obtaining of ahomogeneous material with perovskite-type orthorhombic structure. This characterization allowed evaluating the average crystallite size of the samples that varies depending on the rare-earth ion. The results of photoluminescence emission confirmed the presence of this optical phenomenon at room temperature and its relationship to the level of order-disorder structural system. The photoluminescence emission is more intense in samples annealed at 500 ° C (independent on the dopant ion), the variation of the dopant influence on the emission intensity due to charge transfer between the host and emitting rare-earth ion, where the doped with Pr3+ ion has charge transfer more efficient and hence more intense emission in the photoluminescence. Another factor that favors the optical property of the samples is the charge compensation, as it contributes to the increase in structural disorder due to formation of Ca2+ vacancies.

Produtividade de arroz de terras altas em função de reguladores de crescimento

The use of sprinkler-irrigation and/or high levels of fertilization in upland rice can increase plant height and hence plant lodging. Lodging can be controlled by using growth regulators, in order to reduce plant height. The objective of this study was to evaluate the efficiency of plant growth regulators applied at the stage of panicle primordium differentiation on the reduction of plant height and the impact on grain yield and its components of upland rice cultivar Primavera, under sprinkler irrigation. The experiment was arranged in a 3x4 factorial randomized blocks design with four replications. Treatments consisted of: mepiquat chloride and trinexapac-ethil applied at doses 9, 50, 100, and 200 mg a.i. ha-1, and paclobutrazol at doses of 0, 25, 50, and 100 mg a.i. ha-1. Plant growth regulators reduced rice plant height; increasing doses of regulators reduced upland rice grain yield and its components; trinexapac-ethyl was the most harmful to rice grain yield.In this study, it was not identified the dose of growth regulator that allied reduction in plant height and did not cause decrease in rice yield.

Processamento sonoquímico de materiais mesoestruturados de óxido de zinco dopados com terras-raras

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Desenvolvimento radicular e aéreo, nutrição e eficiência de absorção de macronutrientes e zinco por cultivares de arroz de terras altas afetadas pela adubação fosfatada

In Brazil, phosphorus availability is one factor that that more limit yield of upland rice under rainfed system. Then, better understanding of cultivars development at phosphorus soil fertilization is very important in the production systems making this more sustainable. The objective was to evaluate the influence of phosphorus doses applied to the soil over the root length, root and shoot dry matter, concentration and content of macronutrient and zinc in shoot and root as well as the efficiency of nutrient uptake per meter root of upland cultivars of intermediate and modern groups. The experiment was carried out in greenhouse conditions in a completely randomized design in factorial scheme 4 x 4. Treatments were four levels of P fertilization applied at the soil (0, 50, 100 and 200 mg dm(-3) of P) and four upland rice cultivars (Maravilha - modern group, IAC-201, IAC-202 and Carajas - intermediate group). There is increase in phosphorus availability in the soil with increasing levels of P fertilization. Under low phosphorus availability, cultivars of the intermediate group have better shoots and root system development in relation to the modern cultivar group. Level of phosphorus affected nutrients contents in shoots and root system of upland rice cultivars. The increasing phosphorus fertilization increased uptake of nutrients per meter of root; and although under higher phosphorus availability there was a greater root growth, in low phosphorus availability root growth was greater at the expense of shoot growth.

Acidez do solo afetando concentração de micronutrientes, atividade da enzima nitrato redutase e produtividade em plantas de arroz de terras altas

The lowest grain yield of rice under no-tillage system (NTS) in relation to the conventional system may be due to the predominance nitrate in the soil and the low nitrate reductase activity. Another reason may be caused by micronutrient deficiency because of superficially soil acidity corrections. Therefore, the objective of this study was to evaluate the changes caused by soil pH in the N forms in the soil, micronutrients concentration in rice plants, nitrate reductase activity, yield of rice and its components. The experiment was performed in a greenhouse conditions. The experimental design was a completely randomized in a factorial three (levels of soil acidity) x five (micronutrients sources) with four replications. The addition of micronutrients does not affect levels of nitrate and ammonium in the soil; soil acidity significantly affects levels of nitrate and ammonium in the soil, concentration of micronutrients in rice plants and crop yield and its components; medium soil acidity (pH 5.5) result in medium to high levels of Cu and Fe, medium level of Zn and Mn, high nitrate reductase activity, resulting in higher dry matter, tillers, panicles, spikelets, weight of 100 grains and hence grain yield.

Acúmulo de silício na parte aérea de cultivares de arroz de terras altas afetado pela aplicação de silicato e carbonato no solo

Even the element silicon being the most uptake by rice plant, many benefit effect like: increase of pest and disease tolerance, decrease of lost of water by transpiration and better the leaf architecture becoming the leafs more erect, resulting as well at the better photosynthesis efficacy. There is not too much knowledge about the uptake march in upland rice plants. This study aimed to evaluate the content of silicon in two upland rice cultivars by the influence of the application of silicate and limestone at the soil. The experiment was carried in Hapludox soil in a completely randomized experimental design in 2x2x7 factorial scheme in four replications. The treatments were consisted of calcium silicate fertilizer and limestone in interaction with seven period of physiological stage, using the upland rice cultivars Caiapo and Maravilha. At the cultivar Maravilha Si accumulation begin from tillering and achieve it better value at the microsporogenesis, while the Caiapo cultivar, occurs between tillering until the mily grain. Caiapo shows efficient Si accumulation when it was supplied to the soil. Plant organs that more accumulated silicon in both upland rice cultivars followed decreased order: stem > leaf > panicle.

Gesso aplicado na superfície do solo no desenvolvimento do arroz de terras altas sob plantio direto

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Doses, fontes e épocas de aplicação de nitrogênio em arroz de terras altas cultivado em sistema de semeadura direta

The crop demand by nitrogen varies from one crop to other as well as the amount and application time, and this nutrient can be lost by leaching, volatilization and erosion. The objective of this study was to evaluate doses, sources and times of nitrogen application in rice of high lands cropped in no till system. The work was conducted in Selviria, State of Mato Grosso do Sul, Brazil, in a soil originally under Cerrado vegetation. A randomized blocks design, with the treatments disposed in a factorial scheme 5x3x2 was used. The treatments were constituted by five nitrogen doses (0, 50, 100, 150 and 200 kg ha(-1)), three nitrogen sources (urea; ammonium sulfonitrate plus nitrification inhitor and ammonium sulfate) and two application times (at sowing or at flower bud differentiation), with four repetitions. The sources of nitrogen, as well as the application times had similar effects for most of evaluations. The N doses influenced linearly or with quadratic adjustment the plant height, N leaf content and grains yield, in the two growing seasons. The chlorophyll content and the number of ears m(-2) were affected only, in the first year. The highest yield in the growing season of 2007/08 was obtained with the dose of 149 kg ha(-1) of N. In 2008/09 growing season the increase of N doses provided increment in the grains rice yield, until the maximum dose evaluated (200 kg ha(-1) of N).

Análise da dinâmica de ocupação e uso das terras e suas implicações no sistema morfohidrográfico da Bacia do Ribeirão Bonito-SP

Os sistemas ambientais são compostos por elementos e atributos que atuam em sua dinâmica, os quais, ao longo de um dado período de tempo, podem responder às condições naturais ou às imposições antrópicas, sendo que estas últimas podem desencadear modificações no seu equilíbrio natural. Neste contexto, o objetivo principal do trabalho proposto foi identificar e analisar as alterações na dinâmica de ocupação e uso das terras e sua interferência nas características naturais da bacia do Ribeirão Bonito – SP, com ênfase à geomorfologia e hidrografia. A área em questão situa-se junto à baixa bacia do Rio Piracicaba, no Estado de São Paulo, numa área de transição entre a Depressão Periférica Paulista e as Cuestas Basálticas. Para a consolidação do objetivo proposto foram utilizados os seguintes procedimentos metodológicos: revisão de literatura referente à temática adotada; caracterização do meio físico e do processo de ocupação da área em estudo; elaboração de mapas geomorfológicos de dois cenários (1962 e 2007) de acordo com as metodologias de Tricart (1965) e Verstappen; Zuidan (1975), adaptados por Cunha (2001); elaboração de mapas de ocupação e uso das terras dos dois períodos (1962 e 2007) utilizando o sistema de classificação do IBGE (2006b) e trabalhos de campo. Para manuseio dos dados e posterior análise dos mesmos, foi utilizada a idéia de sistema ambiental, que se fundamenta na teoria dos sistemas gerais, aplicada a Geografia. Findados os levantamentos, observou-se que o aumento do nível de base local com conseqüente retomada erosiva, assim como a intensa ocupação das terras pela cultura da cana-de-açúcar, foram fatores que condicionaram as alterações geomorfológicas locais, expressas principalmente pela dinâmica erosiva e processos de denudação

Avaliação do potencial genotóxico e mutagênico do efluente de uma refinaria de petróleo e dos rios sob sua influência, por meio de bioensaios com Oreochromis niloticus (Perciformes, Cichlidae)

The petrochemical industry represents a sector of intense activity, in constant expansion and great economic importance for Brazil. In order to be used in various human activities petroleum needs to suffer a refinement process that, besides requiring large amounts of water, produces large amounts of wastes, which are discharged in hydric resources. Petroleum is a complex mixture mainly comprised by hydrocarbons, many of them are recognized as toxic chemicals, which are able to induce a considerable environmental pollution. Since water is an important resource for the maintenance of ecosystems and is also the final receiver of effluent discharges of the petroleum industry, there is an imminent need to monitor, constantly, the hydric resources that are influenced by this industrial activity, so that it can be ensured the environmental health. This study aimed, mainly, to analyze the quality of water samples derived from refinement process performed of the largest petroleum refinery in Brazil (REPLAN), in distinct steps of the industry treatment, and waters of rivers associated to its activity. Micronuclei and Nuclear Abnormalities tests were performed in erythrocytes of the fish species Oreochromis niloticus exposed to water samples derived from refinery use and to rivers under the influence of their effluents, in order to evaluate its possible toxic, genotoxic and mutagenic effects. The results obtained show that the treatment carried out by the refinery, during the evaluated periods, was effective, since the substances present in the water samples did not induce significant genotoxic and/or mutagenic alterations in the genetic material of the test organisms. On the other hand, when the substances present in the refinery effluent mix with the ones derived from other industrial activities developed upstream of this industry, the resultant compound, in some periods, presented genotoxic potencial, characterized by a rise of erythrocytic...

Modelo tectono-estrutural dos campos de petróleo Namorado, Cherne e Albacora

The main goal in this research is a tectono-estructural characterization of the Cherne, Albacora and Namorado Fields, located at Campos Basin, in order to investigate the relationship between the geologic evolution and the rock´s physical properties of the reservoir, and how they affect the hydrocarbon accumulation in those fields. Well correlations show that the inferior turbidites have a regional lateral continuity. Basic petrophysics analysis, calculated here, shows that the three fields present porosity values that range from 15 to 20%, shale volume range from 26 to 30% and formation water saturation range from 23 to 45%, based on formation water resistivity dada from Albacora Field. Petrophysics maps feature a trend in Albacora Field that increase the porosity values to SE, and in Cherne and Namorado Field the trend increase towards N. Seismic horizons where interpreted between the first appearance of the Namorado Sandstone and the top of Quissamã Formation. This interval presents normal listric faulting, in Cherne and Namorado Field with NWSE and NE-SW direction, and sedimentation trend to NW-SE, in Albacora Field the faulting presents a NNE-SSW and N-S direction, with a sedimentation trend to NE-SW. Seismic attribute maps present amplitude anomalies close to the producing wells, and on Namorado Field, it indicates a potential hydrocarbon accumulation in the NE region. For each field is indicated laboratory tests for a better characterization of the petrophysical properties, since that they don’t form the same reservoir level, therefore, not influencing the water saturation calculation

Micro-fungos de interesse para o setor de petróleo, gás e biocombustíveis

Oil is a hydrocarbon mixture of various sizes, including saturated and aromatic compounds. Natural gas is a mixture of gaseous hydrocarbons and its main component is methane. In our society, the great demand for these fuels requires fast extraction, transportation and refining, increasing the number of accidents that compromise the environment. Oil is a finite resource and it is necessary to reduce the problems related to the question concerning environmental pollution which has encouraged the search for alternative fuel sources in our country. So today we have two major biofuels: ethanol and biodiesel. Concurrently, many studies have been done directed toward the isolation of microorganisms capable of degrading petrochemical industrial wastes, most of them using as a source of isolation soil and water collected in a contaminated environment. Isolation from alternative substrates has emerged as a new strategy that has provided satisfactory results. In this work, we present the leaf-cutter ants of the Attini tribe as a source for the isolation of micro-fungi with the potential for hydrocarbon degradation. These insects have a social way of life and a highly specialized system of intra and interspecific communication, which is based on the recognition of individuals through volatile chemical compounds, the majority hydrocarbons, stored in their exoskeleton. The micro-environment exoskeleton of Attini ants (genus Atta) used in this work proved to be a rich source of microbial biodiversity, as other studies have found. The flotation isolation technique applied here allowed the achievement of 214 micro-fungi, 118 representatives of the dematiaceous fungi group and 96 hyaline filamentous fungi. They were submitted to toluene degradation tests and at least one strain of each genus presented good results, namely Teratosphaeria, Exophiala, Cladosporium, Penicillium, Aspergillus... (Complete abstract click electronic access below)