Polymer-clay nanocomposites thermal stability: experimental evidence of the radical trapping effect

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Free radical entrapment and crystallinity of resin composites after accelerated aging as a function of the expiration date

This study evaluated the spin concentration and the crystallinity in different classifications of dental composites as a function of the material condition (new, aged and expired). Specimens were obtained according to the factors: composites: Filtek P60, Filtek Z250, Filtek Z350XT, and Filtek Silorane; and material conditions: new, aged, and expired. The syringe composites underwent an accelerated aging protocol (Arrhenius model). The magnetic properties of the composites were characterized using Electron Paramagnetic Resonance (EPR) and the concentration of spins (number of spins/mass) was calculated. The crystallinity of the composites tested was characterized with X-ray diffraction (XRD). Filtek P60 and Filtek Z250 presented similarities in terms of spin concentration and crystallinity, irrespective of the material condition. The aging protocol influenced the composite Filmic Z350XT that exhibited a significant increase in the spin concentration. Besides, lower intensity peaks of the organic matrix and amorphous silica were also observed for both aged and expired Filtek Z350XT. Although a significant lower spin concentration was observed for the silorane composite in comparison to that of the methacrylates, a decrease in the relative intensity of peaks of the amorphous region related to the organic components in the diffractograms was observed. The material conditions tested influence the crystallinity and the magnetic properties of the composites evaluated. (C) 2014 Elsevier Ltd. All rights reserved.

Molecular properties of the PCO radical: heat of formation and the isomerization pathways

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

HPLC-DAD based method for the quantification of flavonoids in the hydroethanolic extract of Tonina fluviatilis Aubl. (Eriocaulaceae) and their radical scavenging activity

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Em que sentido(s) é radical o Behaviorismo Radical?

The use of the adjective radical to identify the variety of behaviorism proposed by Skinner is current nowadays. However, historically, this qualifier was not exclusively applied to Skinner's proposal and its polysemy tends to generate inaccuracies in the interpretation of what characterizes Skinner's Radical Behaviorism. This article aims to clarify the most appropriate sense of radical when applied to Skinner's behaviorism by means of four articulated activities: (1) the description of the etymological origins of the word radical and its different meanings in Portuguese, Spanish and English, (2) a reconstruction and analysis of the evolution of a historical setting that culminated in the use of the term in the behaviorist context, (3) an analysis of the main meanings of radical when associated with behaviorism, (4) an examination of some ways in which the use of the term associated with behaviorism is consistent, and the current and future implications for Radical Behaviorism and Behavior Analysis in a scientific context.

O novíssimo Príncipe: Gramsci e a reconstrução da teoria marxista do Partido

It is only in his Prison Notebooks, through the political formula crystallized in the 'Modern Prince', that gramscian theory of the political party reaches its final configuration. Beyond to direct dialogue with the leninian formulations and those subsequently developed by the Communist International, is also noticeable echoes of critical dialogue with elitist sociology of the political party of Robert Michels. Largely, is thanks to this critical and nonsectarian approach that Gramsci could produce one of the most original reflection on the party organization within the Marxist tradition, facing the issues previously neglected of oligarchyzation and bureaucratization of workers' parties, thus providing a possible theoretical overrun for the inevitability of elitist thesis of split between the party leader's core interests and the interests of their social reference. The objective of this work is to restore some contributions of Gramsci to the reconstruction of theory of the revolutionary party today.

Estudo de temperatura de plasma de álcool através de espectroscopia de emissão natural radical C2*

Non-intrusive methods of diagnosis, such as spectral analysis of the radiation emitted by the system, have been used as a viable alternative for determining the temperature of combustion systems. Among them, the determination of temperature by natural emission spectroscopy has the advantage of requiring relatively simple experimental devices. Once Chemiluminescent species are formed directly in the excited state, the collection and recording of radiation emission spectrum is enough to determine the temperature (CARINHANA, 2008). In this study we used the process of making direct comparisons between the experimental spectra obtained in the laboratory from the plasma of alcohol, and the theoretical spectra plotted from a computer program developed at the IEAv. The objective was to establish a fast and reliable method to measure the rotational temperature of the radical C2*. The results showed that the temperature of the plasma, which in turn can be taken as the rotational temperature of the system, is proportional to the pressure. The temperature values ranged from ca. 2300 ~ 2500 K at a pressure of 19 mmHg to 3100 ~ 3500 K for the pressure of 46 mmHg. The temperature values are somewhat smaller when we consider the theoretical spectrum as a Lorentzian curve. The overlap of the spectra was better when using the profile curve, but still were not exactly superimposed. The solution to improve the overlap of the theoretical with the experimental spectra is the use of a curve that has the convolution of two profiles analyzed: Lorentzian and Gaussian. This curve is called the Voigt profile, which will also be implemented by programmers and studied in a next work

Mídia radical: análise comparativa entre a opinião da grande imprensa e da mídia radical no novo código florestal

The objective of this work is to compare how manifests the ideological positioning in the hegemonic media productions, according to Gramsci's conception, in relation to the radical alternative media, proposed by John Downing. The research has as opinionated content sample printed newspaper O Estado de s. Paulo, contrasting with the expressions of NON-PROFIT bauruense environmental “Instituto Ambiental Vidágua on the proposals of the new Brazilian forest Code. The analysis will hold in an interval between the adoption of the code by the Chamber of deputies in April 2012, and the provisional measure of President Dilma Rousseff with 32 modifications, after vetoing 12 articles proposed initially in may 2012. To support the study, will be crafted Gramsci hegemony; What is the alternative and radical media as it manifests itself; the relationship between the environmental journalism with the environmental NGOs; opinionated journalism and journalistic genres opinionated; theories of journalism and framing of matter

Análisis organizacional del partido de la democracia social brasileña en el estado de San Pablo (1988-2006)

The article represents a theoretical and methodological approach to the analysis of organizational dynamics of political parties today, based on a study of the Party of Brazilian Social Democracy (PSDB) in the State of Sao Pãulo (period between 1988 to 2006). It is hypothesized that the structure and the institutional rules of a particular party, or even their election results, are insufficient to explain the inner workings, such as the role of party organization in the electoral system. An approach that articulates the relationship patterns, election results and posts held in the party, identified the factors that explain the political capital that circulated within the party and ensured its organizational dynamics over the period analyzed.

As origens do novo conservadorismo estadunidense em um sistema federativo: Barry Goldwater e a tentativa de coalizão entre tradicionalistas e libertários

A tradição do novo conservadorismo nos EUA foi determinante para a ampliação do debate político durante as últimas décadas, uma vez que, a partir da década de 1950 inseriu e fomentou uma série de ideias que, até então, pareciam excluídas e marginalizadas da discussão política devido ao grande sucesso eleitoral do modelo liberal creditado ao Partido Democrata. Para aprofundar esse debate, o artigo discute a importância da campanha eleitoral de Barry Goldwater, em 1964, e sua relação com a consolidação do movimento conservador no país, compreendendo como a partir dela amarrou-se uma aliança entre variadas correntes que compunham o espectro conservador, o que possibilitou ao Partido Republicano disputar novamente as eleições em um patamar de igualdade com o partido rival. Para realizar essa análise, em um primeiro momento, partimos de uma abordagem sobre o sistema federalista, com o intuito de compreender alguns de seus princípios básicos e sua influência na formação dos EUA como nação. Esse debate serve como base para uma releitura melhor contextualizada em torno de temas presentes na campanha de 1964, principalmente, no que se refere as propostas em torno do papel do Estado e relacionadas ao discurso em defesa dos interesses dos estados e da defesa da Constituição recorrentes no pleito eleitoral estadunidense. Junto a isso, aprofundamos a análise sobre as correntes que compunham o conservadorismo no país, demonstrando como elas, embora fossem muitas vezes antagônicas, se acomodaram em um projeto político conservador.

Radical management of solid ameloblastoma of the mandible: report of a case with 5-year follow-up

Ameloblastoma is a true neoplasm of odontogenic epithelial origin. This pathology can be classified into 4 groups: unicystic, solid or multicystic, peripheral, and malignant. Solid ameloblastomas of the mandible are the most common of them, and represent a challenging group of tumours to treat; in addition the follicular histopathological subtype has a high likelihood of recurrence. Thus, the challenges in the management of this tumour are to provide complete excision in addition to reconstruct the bony defect, in order to provide the patient with reasonable cosmetic and functional outcome. With this in mind, this paper aimed to describe the management of a solid multilocular ameloblastoma of follicular subtype in a 39-year-old female. Case report The authors report a case of a solid multilocular ameloblastoma of follicular subtype in a 39-year-old female who was successfully treated by partial resection of the mandible with immediate reconstruction using an iliac crest, as a donor site. After 15 months, the patient was rehabilitated using titanium implant dentistry, and has been followed up for 5 years without signs or symptoms of recurrence. Conclusion Correct surgical planning is the key for successful management of solid ameloblastoma with multilocular features, which is best treated using radical resection with immediate reconstruction, which ensures complete tumour excision, prevents recurrence, and enables fast and safe dental rehabilitation. Biomedical prototypes should be used since they provide acceptable precision and are useful for surgical planning.

Physicochemical characterisation and radical-scavenging activity of Cucurbitaceae seed oils

Oils extracted from Cucurbitaceae seeds were characterised for their fatty acid and tocopherol compositions. In addition, some physicochemical characteristics, total phenolic contents and the radical-scavenging activities were determined. Oil content amounted to 23.9% and 27.1% in melon and watermelon seeds, respectively. Physicochemical characteristics were similar to those of other edible oils and the oils showed significant antioxidant activities. Fatty acid composition showed total unsaturated fatty acid content of 85.2–83.5%, with linoleic acid being the dominant fatty acid (62.4–72.5%), followed by oleic acid (10.8–22.7%) and palmitic acid (9.2–9.8%). The oils, especially watermelon seed oil, showed high total tocopherol and phenolic contents. The γ-tocopherol was the predominant tocopherol in both oils representing 90.9 and 95.6% of the total tocopherols in melon and watermelon seed oils, respectively. The potential utilisation of melon and watermelon seed oils as a raw material for food, chemical and pharmaceutical industries appears to be favourable.

Reabilitação do assoalho pélvico em pacientes com incontinência urinária pós prostatectomia radical

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

Uso de viscum album no ponto de acupuntura VG14 como terapia adjuvante à mastectomia radical em cadelas com neoplasias mamárias

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)