卡林型金矿不可见金与超压流体（Overpressured fluid）关系探讨——以贵州贞丰水银洞金矿为例

贵州水银洞(岩上)微细浸染型金矿产于贵州省贞丰县境内，是目前我国第一个成功地从原生硫化物矿石中商业性生产出金的微细浸染型金矿矿山。该矿床的矿体产于灰家堡背斜东段核部的上二叠统龙潭组地层中及其与中二叠统茅口组灰岩的接触带，呈几层基本平行排布的似层状和透镜状产出。金矿化主要赋存于硅化白云石化生物碎屑灰岩和泥灰岩(85％)和强硅化角砾状粘土岩(14％)中。

Total analytical method for Radix astragali extract using two-binary multi-segment gradient elution liquid chromatography

There is an urgent need for thorough analysis of Radix astragali, a widely used Chinese herb, for quality control purposes. This paper describes the development of a total analytical method for Radix astragali extract, a multi-component complex mixture. Twenty-four components were separated step by step from the extract using a series of isocratic isopropanol-methanol elutions, and then 42 components were separated similarly using methanol-water elutions. Based on the log k(w) and -S of the 66 components obtained from the above procedure and the optimization software developed in our laboratory, an optimum elution program consisting of seven methanol-water segments and four isopropanol-methanol segments was developed to finish the task of analyzing the total components in a single run. Under optimized gradient conditions, the sample of Radix astragali extract was analyzed. As expected, most of the components were well separated and the experimental chromatogram was in a good agreement with the predicted one.