972 resultados para SrSnO3, Sr (x) Ba (1-x) and SNO3 BaSnO3
Resumo:
Fibrous calcite veins with organic inclusions have been widely considered as indicators of oil and gas generation and migration under overpressure. Abundant fibrous calcite veins containing organic-bearing inclusions occur in faulted Lower Paleozoic through Triassic hydrocarbon source rocks in the Dabashan Foreland Belt (DBF). d13CPDB and d18OPDB values of the fibrous calcite range from - 4.8 to -1.9 to per mil and - 12.8 to - 8.4 per mil respectively, which is lighter than that of associated carbonate host rocks ranging from - 1.7 to + 3.1 per mil and - 8.7 to - 4.5 per mil. A linear relationship between d13CPDB and d18OPDB indicates that the calcite veins were precipitated from a mixture of basinal and surface fluids. The fibrous calcite contains a variety of inclusions, such as solid bitumen, methane bearing all-liquid inclusions, and vapor-liquid aqueous inclusions. Homogenization temperatures of aqueous inclusions range from 140 to 196° with an average of 179°. Salinities of aqueous inclusions average 9.7 wt% NaCl. Independent temperatures from bitumen reflectance and inclusion phase relationships of aqueous and methane inclusions were used to determine fluid pressures. Results indicate high pressures, elevated above typical lithostatic confining pressure, from 150 to 200 MPa. The elevated salinity and high temperature and pressure conditions of the fibrous calcite veins argue against an origin solely from burial overpressure resulting from clay transformation and dehydration reactions. Instead fluid inclusion P-T data and geochemistry results and regional geology indicate abnormally high pressures during fluid migration. These findings indicate that tectonic stress generated fracture and fault fluid pathways and caused migration of organic bearing fluids from the DBF during the Yanshan orogeny.
Resumo:
In the lower part of DSDP core 53.0, partly recrystallized carbonate sediments and well recrystallized limestone breccias of Oligo-Miocene age are associated with altered volcanic flows, lithified tuffs, and tuff breccias, suggesting that carbonate alteration was the result of thermal metamorphism. However, the oxygen isotope compositions of these carbonates (-3.4 to +0.6 per mil rel. PDB) are not compatible with recrystallization and isotope exchange with sea water at high temperatures. Evaluating the effects of the composition of the water which exchanged with the carbonates and of carbonate-water isotope exchange in closed systems yields the following approximate maximum temperature of recrystallization: limestone breccias, 100°C; calcite veins rimming breccia clasts, 30°C; and unconsolidated sediments overlying the breccias, 20°C. Therefore, the volcanics at site 53.0 must have been emplaced into the primary carbonate sediments at relatively low temperatures. Subsequent carbonate alteration was probably a consequence of chemical changes in ambient pore waters resulting from the submarine weathering of volcanic material.
Resumo:
A detailed oxygen and carbon isotope study of the upper Maestrichtian-lower Paleocene section of Hole 516F from the Rio Grande Rise reveals that large isotopic anomalies are clearly associated with the Cretaceous/Tertiary boundary. Across the Cretaceous/Tertiary boundary, the total carbonate content reaches a maximum exceeding 80% before rapidly decreasing in covariance with the carbon isotope record. This strong covariance between d13C and percent CaCO3 suggests either a significant reduction in primary productivity or a rapid shoaling of the calcium carbonate compensation depth. Importantly, the d13C record 2 Ma after the Cretaceous/Tertiary boundary remained depleted in 13C by at least 0.5 per mil compared to the late Maestrichtian.
Resumo:
The Advanced Land Observation System (ALOS) Phased-Array Synthetic-Aperture Radar (PALSAR) is an L-band frequency (1.27 GHz) radar capable of continental-scale interferometric observations of ice sheet motion. Here, we show that PALSAR data yield excellent measurements of ice motion compared to C-band (5.6 GHz) radar data because of greater temporal coherence over snow and firn. We compare PALSAR velocities from year 2006 in Pine Island Bay, West Antarctica with those spanning years 1974 to 2007. Between 1996 and 2007, Pine Island Glacier sped up 42% and ungrounded over most of its ice plain. Smith Glacier accelerated 83% and ungrounded as well. Their largest speed up are recorded in 2007. Thwaites Glacier is not accelerating but widening with time and its eastern ice shelf doubled its speed. Total ice discharge from these glaciers increased 30% in 12 yr and the net mass loss increased 170% from 39 ± 15 Gt/yr to 105 ± 27 Gt/yr. Longer-term velocity changes suggest only a moderate loss in the 1970s. As the glaciers unground into the deeper, smoother beds inland, the mass loss from this region will grow considerably larger in years to come.
Resumo:
Combined geodetic, geophysical and glaciological in situ measurements are interpreted regarding surface height changes over subglacial Lake Vostok and the local mass balance of the ice sheet at Vostok station. Repeated GPS observations spanning 5 years and long-term surface accumulation data show that the height of the lake surface has not changed over the observation period. The application of the mass conservation equation to purely observational data yields an ice mass balance for Vostok station close to equilibrium.