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Contiene: INQUISITIONES. INQUIRIÇÕES GERAIS DE D. DINIS: 1284. José Augusto de Sotto Mayor Pizarro (ed.) Lisboa, Academia das Ciências de Lisboa, 2007. (Portugaliae Monumenta Historica: a saeculo octavo post Christum usque ad quintum decimum, Nova Série, vol. 3). ISBN 978-972-623-101-1. 133 páginas / Inés Calderón Medina ; EL BAILE GENERAL DE ARAGÓN DURANTE EL REINADO DE PEDRO IV EL CEREMONIOSO (1336-1387). Luís Blanco Domingo. La fiscalidad regia. Institución “Fernando el Católico” (C.S.I.C.). Zaragoza. 2009. 253. I.S.B.N.: 978-84-9911-018-9 / Héctor García López ; LA ENCOMIENDA DE MARTOS DE LA ORDEN DE CALATRAVA (SIGLOS XIII-XV). Francisco Luis Ruiz Fúnez (Ed. Ayuntamiento de Martos. Martos, 2010. 164 págs. + fotos y planos) ISBN: 978-84-923864-2-0 / José Carlos Gutiérrez Pérez ; LA FRONTERA SEFARDÍ. LA RECONQUISTA Y LA COMUNIDAD JUDÍA EN LA ESPAÑA MEDIEVAL. Jonathan Ray. Alianza Editorial, Madrid, 2009, 302 p. I.S.B.N.: 978-84-206-8395-9 / Jorge Maíz Chacón ; BATTAGLIE E PROTAGONISTI DELLA SARDEGNA MEDIOEVALE. Alessandra Cioppi. AMD Edizioni, Cagliari, 2008. ISBN: 978-88-95462-15-8. 434 Págs. / Esther Martí ; LIBRO DE LA BAILÍA DE CANTAVIEJA (1428-1470). Germán Navarro Espinach y Concepción Villanueva Morte. Departamento de Historia Medieval, Ciencias y Técnicas Historiográficas y Estudios Árabes e Islámicos de la Universidad de Zaragoza, Instituto de Estudios Turolenses y Grupo de investigación CEMA, Zaragoza, 2009, 374 páginas. / Francisco Vicente Navarro ; LA NOBLEZA SEÑORIAL EN LA CORONA DE CASTILLA. Mª Concepción Quintanilla Raso. Universidad de Granada, Granada, 2008. ISSN: 978-84-338-4854-3. 357 págs. / Santiago Ponsoda López de Atalaya ; TESTAMENTI ECLESIAE PORTUGALIAE (1071-1325), COLECÇÃO HISTÓRIA RELIGIOSA: FONTES E SUBSIDIOS 6. Maria do Rosario Barbosa Morujão (coord.) Centro de estudios de Historia Religiosa da Universidade Católica Portuguesa, Lisboa, 2010. ISBN: 978-972-8361-31-0. 767 Páginas, 39 imágenes / Néstor Vigil Montes.

Copper-Free Oxime–Palladacycle-Catalyzed Sonogashira Alkynylation of Deactivated Aryl Bromides and Chlorides in Water under Microwave Irradiation

Palladium-catalyzed Heck alkynylation cross-coupling reactions between terminal alkynes and deactivated aryl chlorides and aryl bromides can be performed in the absence of copper cocatalyst with water as solvent at 130 °C under microwave irradiation. An oxime-derived chloro-bridged palladacycle is an efficient precatalyst for this transformation with 2-dicyclohexylphosphanyl-2′,4′,6′-triisopropylbiphenyl (XPhos) as ancillary ligand, pyrrolidine as base, and SBDS as surfactant. All of the reactions can be performed under air and with reagent-grade chemicals under low loading conditions (0.1–1 mol-% Pd).

Microwave-assisted palladium-catalyzed highly regio- and stereoselective head to head dimerization of terminal aryl alkynes in water

A highly regio- and stereoselective oxime palladacycle/imidazolinium-catalyzed head to head dimerization of terminal aryl alkynes in water is presented. The reaction, which is carried out at 130 °C under microwave irradiation in the presence of 1,3-bis-(2,6-diisopropylphenyl)imidazolinium chloride as ligand, triethylamine as base, and TBAB as surfactant, allows the synthesis of (E)-1,4-enynes as single stereoisomers in good isolated yields.