Espessura da zona de transição do manto sob a Província Borborema, NE Brasil, através de conversões Ps telessísmicas

The mantle transition zone is defined by two seismic discontinuities, nominally at 410 and 660 km depth, which result from transformations in the mineral olivine. The topography of these discontinuities provides information about lateral temperature changes in the transition zone. In this work, P-to-S conversions from teleseismic events recorded at 32 broadband stations in the Borborema Province were used to determine the transition zone thickness beneath this region and to investigate whether there are lateral temperature changes within this depth range. For this analysis, stacking and migration of receiver functions was performed. In the Borborema Province, geophysical studies have revealed a geoid anomaly which could reflect the presence of a thermal anomaly related to the origin of intraplate volcanism and uplift that marked the evolution of the Province in the Cenozoic. Several models have been proposed to explain these phenomena, which include those invoking the presence of a deep-seated mantle plume and those invoking shallower sources, such as small-scale convection cells. The results of this work show that no thermal anomalies are present at transition zone depths, as significant variations in the transition zone thickness were not observed. However, regions of depressed topography for both discontinuities (410 and 660 km) that approximately overlap in space were identified, suggesting that lower-thanaverage, lateral variations in seismic velocity above 410 km depth may exist below the the Borborema Province. This is consistent with the presence of a thermally-induced, low-density body independently inferred from analysis of geoid anomalies. Therefore, the magma source responsible for the Cenozoic intraplate volcanism and related uplift in the Province, is likely to be confined above the upper mantle transition zone.

História da matemática e teatro nas aulas sobre Teorema de Tales: um script proposto

This study will present the results of an investigation of how the history of mathematics and theater can contribute to the construction of mathematical knowledge of students in the 9th year of elementary school, through the experience, preparation and execution of a play, beyond presentation of the script. This brings a historical approach, defining space and time of events, putting the reader and viewer to do the route in the biography of Thales of Miletus (624-546 a.C), creating situations that led to the study and discussion of the content related to the episode possible to measure the height of the pyramid Khufu and the Theorem of Thales. That said, the pedagogical proposal implemented in this work was based on theoretical and methodological assumptions of the History of Mathematics and Theatre, drawing upon authors such as Mendes (2006), Miguel (1993), Gutierre (2010), Desgrandes (2011), Cabral (2012). Regarding the methodological procedures used qualitative research because it responds to particular issues, analyzing and interpreting the data generated in the research field. As methodological tools we have used participant observation, the questionnaire given to the students, field diary and dissertativos texts produced by students. The processing and analysis of data collected through the questionnaires were organized, classified and quantified in tables and graphs for easy viewing, interpretation, understanding and analysis of data. Data analysis corroborated our hypothesis and contributed to improving the use and display of the play as a motivating activity in mathematics classrooms. Thus, we consider that the script developed, ie the educational product proposed will bring significant contributions to the teaching of Mathematics in Primary Education

Sismicidade e esforços tectônicos na zona sísmica Acaraú, Nordeste do Brasil

Inside the Borborema Province the Northwestern Ceará (NC) is one of the most seismic active regions. There are reports of an earthquake occurred in 1810 in the Granja town. On January, 2008 the seismic activity in NC has increased and it was deployed a seismographic network with 11 digital stations. In 2009, another earthquake sequence began and it was deployed another seismographic network in the Santana do Acaraú town with 6 stations. This thesis presents the results obtained by analyzing the data recorded in these two networks. The epicentral areas are located near the northeastern part of the Transbrasiliano Lineament, a shear zone with NE-SW-trending that cuts the study area. The hypocenters are located between 1km and 8km. The strike-slip focal mechanisms were found, which is predominant in the Borborema Province. An integration of seismological, geological and geophysical data was performed and it show that the seismogenic faults found are oriented in the same direction to the local brittle structures observed in field and magnetic lineaments. The SHmax (maximum compressional stress) direction in NC was estimated using an inversion of seven focal mechanisms. The horizontal maximum compression stress (σ1 = 300°) with orientation NW-SE and extension (σ3 = 210°) with NE-SW and σ2 vertical. These results are consistent with results of previous studies. The seismic activity recorded in NC is not related to a possible reactivation of the Transbrasiliano Lineament, by now.

Antecedentes do engajamento em boca a boca eletrônico positivo entre turistas

This study examined the influence of the tourism destination image as well as satisfaction and motivation in the intention of engaging in a positive electronic word of mouth (eWOM) by tourists through Facebook. In addition, it was also specifically expected to assess the sociodemographic profile and frequency of eWOM publications from those who answered the questions; it also assessed the adequacy of the manifested variables for composition of the following dimensions: Quality, Satisfaction, Image, Motivations and Positive Electronic Word of Mouth (eWOM). And finally, it analyzed a relational model where there are relationships between Quality, Satisfaction, Image and Motivations in the explanation of engagement in the Positive Electronic Word of Mouth (eWOM). With this aim it was conducted a study, based on a hypothetical-deductive logic, which was descriptive in relation to its goals. The analytical approach was quantitative (a survey). The sampling procedure was non-probabilistic, by the convenience method of sampling specifically, having the choice of the subject been made through the probabilistic systematic method, and using time as a factor of systematization in an attempt of making randomly the selection of the interviewed people. The study sample consisted of 355 tourists. The used instrument to collect information was the structured questionnaire whose answers were collected in the main points of entry, exit and rides of tourists on the Pipa’s Beach/RN. Data analysis was carried out using descriptive and multivariate statistics, mainly exploratory and confirmatory factor analysis and structural equation modeling. Among the main results, it was possible to confirm that the Motivations, Satisfaction and Image strongly affect the intention of engaging in positive electronic word of mouth (eWOM). Emphasis is given to the motivations, as they demonstrate bigger impact in explaining the dependent variable; they are followed by the satisfaction and the image. The latter, however, is inversely proportional. Among the motivations, the one with the highest percentage of variance were the social benefits sought by tourists; and presenting the same percentage appears the desire to help other tourists and to vent Positive Emotions. The manifested variables demonstrate to be fully acceptable to be taken as reflexes of their respective factors.

Estudo da deposição de filmes finos de BaTi(1-X)Zr(X)O3 por meio de planejamento Box-Behnken

Ferroelectric ceramics with perovskite structure (ABO3) are widely used in solid state memories (FeRAM’s and DRAM's) as well as multilayered capacitors, especially as a thin films. When doped with zirconium ions, BaTiO3-based materials form a solid solution known as barium zirconate titanate (BaTi1-xZrxO3). Also called BZT, this material can undergo significant changes in their electrical properties for a small variation of zirconium content in the crystal lattice. The present work is the study of the effects of deposition parameters of BaTi0,75Zr0,25O3 thin films by spin-coating method on their morphology and physical properties, through an experimental design of the Box-Behnken type. The resin used in the process has been synthesized by the polymeric precursor method (Pechini) and subsequently split into three portions each of which has its viscosity adjusted to 10, 20 and 30 mPa∙s by means of a rotary viscometer. The resins were then deposited on Pt/Ti/SiO2/Si substrates by spin-coating method on 15 different combinations of viscosity, spin speed (3000, 5500 and 8000 rpm) and the number of deposited layers (5, 8 and 11 layers) and then calcined at 800 ° C for 1 h. The phase composition of the films was analyzed by X-ray diffraction (XRD) and indexed with the JCPDS 36-0019. Surface morphology and grain size were observed by atomic force microscopy (AFM) indicating uniform films and average grain size around 40 nm. Images of the cross section of the films were obtained by scanning electron microscopy field emission (SEM-FEG), indicating very uniform thicknesses ranging from 140-700 nm between samples. Capacitance measurements were performed at room temperature using an impedance analyzer. The films presented dielectric constant values of 55-305 at 100kHz and low dielectric loss. The design indicated no significant interaction effects between the deposition parameters on the thickness of the films. The response surface methodology enabled better observes the simultaneous effect of variables.

Síntese e caracterização de nanopartículas magnéticas de Co e Ni com aplicação em magneto hipertermia

Nanoparticles are importante for the study of new phenomena and for the development of new applications. Metallic magnetic nanoparticles like Cobalt and Nickel are important for their applications in nanoscience and nanotechnology. In this work, we report on the synthesis and characterization of Ni and Co nanoparticles. The nanoparticles were prepared by the modi- ed sol-gel method and were formed in the pore-network of the biopolymer quitosan. The reduction occurred in absence of H2 ux. The metallic particles and their monoxides have a face-centered- cubic structure. The metallic particles sizes ranged from 59 to 77 nm and from 19 to 50 nm for Ni and Co, respectively. Their monoxides chemically passivated the metallic cores, and after several weeks we have not observed further increase in oxidation. The synthesis method was tuned to obtain mainly the ferromagnetic phase. The system behaves like a core/shell structure with a ferromagnetic core and an antiferromagnetic shell. Exchange bias e ect was observed at temperatures below the Néel temperature. Both systems were submitted to an alternated magnetic eld and the heat released by the particles increased the temperature to 140°C in an interval of 5 min. Similar studies in samples dispersed in water increased the temperatures to 40-59°C, these results suggest that these materials are candidates for magnetic hyperthermia.

Estudo experimental sobre o comportamento do escoamento bifásico água - ar para a medição de vazão em placa de orifício

The measurement of flow through the prediction of differential pressure is widely used in industrial day-to-day, this happens mainly due to the fact that it is used for various types of fluids, such as gas flow and liquid with viscosity distinct even flow of fluids with particles in suspension. The suitability of this equipment for measuring mass flow in two-phase flow is of paramount importance for technological development and reliability of results. When it comes to two-phase flow the relationship between the fluids and their interactions are of paramount importance in predicting the flow. In this paper, we propose the use of concentric orifice plate used in small diameter pipes of 25.4 mm order where a two-phase flow flows between water-air. The measurement of single-phase flow was made with the use of data in NBR 5167-1 which was used to Stolz equation for measuring discharge coefficient. In the two-phase flow was used two correlations widely used in the prognosis of mass flow, the pattern of Zhang (1992) and the model of Chisholm (1967), to the homogeneous flow model. It was observed that the behavior found in Zhang model are consistent more realistic way the mass flow of two-phase flow, since the model Chisholm extrapolate the parameters for the downstream pressure P2, the orifice plate, and the rated discharge coefficient. The use of the change in pressure drop P1-P2 and discharge coefficient, led to a better convergence of the values obtained for the two-phase air-water stream.

Avaliação do desempenho da paligorsquita modificada e do carvão da pirólise do lodo de esgoto no processo de degradação fotocatalítica do fenol

The uncontrolled disposal of wastewaters containing phenolic compounds by the industry has caused irreversible damage to the environment. Because of this, it is now mandatory to develop new methods to treat these effluents before they are disposed of. One of the most promising and low cost approaches is the degradation of phenolic compounds via photocatalysis. This work, in particular, has as the main goal, the customization of a bench scale photoreactor and the preparation of catalysts via utilization of char originated from the fast pyrolysis of sewage sludge. The experiments were carried out at constant temperature (50°C) under oxygen (410, 515, 650 and 750 ml min-1). The reaction took place in the liquid phase (3.4 liters), where the catalyst concentration was 1g L-1 and the initial concentration of phenol was 500 mg L-1 and the reaction time was set to 3 hours. A 400 W lamp was adapted to the reactor. The flow of oxygen was optimized to 650 ml min-1. The pH of the liquid and the nature of the catalyst (acidified and calcined palygorskite, palygorskite impregnated with 3.8% Fe and the pyrolysis char) were investigated. The catalytic materials were characterized by XRD, XRF, and BET. In the process of photocatalytic degradation of phenol, the results showed that the pH has a significant influence on the phenol conversion, with best results for pH equal to 5.5. The phenol conversion ranged from 51.78% for the char sewage sludge to 58.02% (for palygorskite acidified calcined). Liquid samples analyzed by liquid chromatography and the following compounds were identified: hydroquinone, catechol and maleic acid. A mechanism of the reaction was proposed, whereas the phenol is transformed into the homogeneous phase and the others react on the catalyst surface. For the latter, the Langmuir-Hinshelwood model was applied, whose mass balances led to a system of differential equations and these were solved using numerical methods in order to get estimates for the kinetic and adsorption parameters. The model was adjusted satisfactorily to the experimental results. From the proposed mechanism and the operating conditions used in this study, the most favored step, regardless of the catalyst, was the acid group (originated from quinone compounds), being transformed into CO2 and water, whose rate constant k4 presented value of 0.578 mol L-1 min-1 for acidified calcined palygorskite, 0.472 mol L-1 min-1 for Fe2O3/palygorskite and 1.276 mol L-1 min-1 for the sludge to char, the latter being the best catalyst for mineralization of acid to CO2 and water. The quinones were adsorbed to the acidic sites of the calcined palygorskite and Fe2O3/palygorskite whose adsorption constants were similar (~ 4.45 L mol-1) and higher than that of the sewage sludge char (3.77 L mol-1).

Avaliação do desempenho da paligorsquita modificada e do carvão da pirólise do lodo de esgoto no processo de degradação fotocatalítica do fenol

The uncontrolled disposal of wastewaters containing phenolic compounds by the industry has caused irreversible damage to the environment. Because of this, it is now mandatory to develop new methods to treat these effluents before they are disposed of. One of the most promising and low cost approaches is the degradation of phenolic compounds via photocatalysis. This work, in particular, has as the main goal, the customization of a bench scale photoreactor and the preparation of catalysts via utilization of char originated from the fast pyrolysis of sewage sludge. The experiments were carried out at constant temperature (50°C) under oxygen (410, 515, 650 and 750 ml min-1). The reaction took place in the liquid phase (3.4 liters), where the catalyst concentration was 1g L-1 and the initial concentration of phenol was 500 mg L-1 and the reaction time was set to 3 hours. A 400 W lamp was adapted to the reactor. The flow of oxygen was optimized to 650 ml min-1. The pH of the liquid and the nature of the catalyst (acidified and calcined palygorskite, palygorskite impregnated with 3.8% Fe and the pyrolysis char) were investigated. The catalytic materials were characterized by XRD, XRF, and BET. In the process of photocatalytic degradation of phenol, the results showed that the pH has a significant influence on the phenol conversion, with best results for pH equal to 5.5. The phenol conversion ranged from 51.78% for the char sewage sludge to 58.02% (for palygorskite acidified calcined). Liquid samples analyzed by liquid chromatography and the following compounds were identified: hydroquinone, catechol and maleic acid. A mechanism of the reaction was proposed, whereas the phenol is transformed into the homogeneous phase and the others react on the catalyst surface. For the latter, the Langmuir-Hinshelwood model was applied, whose mass balances led to a system of differential equations and these were solved using numerical methods in order to get estimates for the kinetic and adsorption parameters. The model was adjusted satisfactorily to the experimental results. From the proposed mechanism and the operating conditions used in this study, the most favored step, regardless of the catalyst, was the acid group (originated from quinone compounds), being transformed into CO2 and water, whose rate constant k4 presented value of 0.578 mol L-1 min-1 for acidified calcined palygorskite, 0.472 mol L-1 min-1 for Fe2O3/palygorskite and 1.276 mol L-1 min-1 for the sludge to char, the latter being the best catalyst for mineralization of acid to CO2 and water. The quinones were adsorbed to the acidic sites of the calcined palygorskite and Fe2O3/palygorskite whose adsorption constants were similar (~ 4.45 L mol-1) and higher than that of the sewage sludge char (3.77 L mol-1).

Da arenga ao debate: o aprimoramento da competência argumentativa por estudantes do ensino médio

In order to understand the factors involved in the improvement process of argumentative competence by students of 2nd year of high school, we undertook a qualitative approach research and interventional nature, during which we adopted the conduct of participant observation in a school belonging to the state schools of Rio Grande do Norte, located on the outskirts of the city of Natal. The analyzed corpus consisted in the interim intervention and entails the answers to a semi-structured questionnaire, fourteen opinion articles and three regrados debates, produced by the students, in addition to video recordings of ten sessions and personal notes pertaining to another six, totaling sixteen sessions observed during the school year 2014. As the most important bibliographical references we study skills and reasoning from the perspective of discursive social interactionism. Analyzing the data we loan the principle of categorization, opting for critical-descriptive presentation and were revealed to us, via the classified evidences, that among the factors involved in the study process, it appears with more relevance to set up an effective intellectual community, which meets in constant interaction subjects, which alternate assuming the conditions of speakers and audience. The constitution of this community depends largely on the teaching mediation and is indispensable to the (re)design of the studied competence, in interactions with her the subjects afforded learn and develop their competence, reshaping the limits of their zone of proximal development.

Da arenga ao debate: o aprimoramento da competência argumentativa por estudantes do ensino médio

In order to understand the factors involved in the improvement process of argumentative competence by students of 2nd year of high school, we undertook a qualitative approach research and interventional nature, during which we adopted the conduct of participant observation in a school belonging to the state schools of Rio Grande do Norte, located on the outskirts of the city of Natal. The analyzed corpus consisted in the interim intervention and entails the answers to a semi-structured questionnaire, fourteen opinion articles and three regrados debates, produced by the students, in addition to video recordings of ten sessions and personal notes pertaining to another six, totaling sixteen sessions observed during the school year 2014. As the most important bibliographical references we study skills and reasoning from the perspective of discursive social interactionism. Analyzing the data we loan the principle of categorization, opting for critical-descriptive presentation and were revealed to us, via the classified evidences, that among the factors involved in the study process, it appears with more relevance to set up an effective intellectual community, which meets in constant interaction subjects, which alternate assuming the conditions of speakers and audience. The constitution of this community depends largely on the teaching mediation and is indispensable to the (re)design of the studied competence, in interactions with her the subjects afforded learn and develop their competence, reshaping the limits of their zone of proximal development.

Caracterização de um compósito utilizando cimento com agregado de resíduo plástico e resíduo de gesso

The demand for environmental comfort in construction systems within the insulation and thermal comfort, plus the advent of new laws regulating the minimum requirements of comfort, disposal of solid industrial waste, construction waste, the requirements of consumers by adopting construction methods "cleaner", encouraged the development of this work. Aims technologically characterize the composite proposed in three types of samples (10%, 30% and 50% of thermoset plastic industrial waste) and raw materials: gypsum waste, cement and plastic thermosetting industrial waste in order to produce the composite with properties of thermal insulation: conductivity, thermal diffusivity, specific heat and resistivity. The physical, structural and morphological properties of the raw materials were investigated by thermogravimetry analysis (TG / DSC), X-ray diffraction (DRX), X-ray fluorescence (FXR) and scanning electron microscopy (MEV). Obtaining mechanical properties through the compression strength test. The analysis results indicate characteristics suitable for cement matrix composite production with the addition of thermosetting plastic industrial waste and gypsum waste, with potential application of these materials in composites with properties of thermal insulation. Finally, assessing what proportion showed up with better performance. Considering the analysis and testing carried out.

Caracterização de um compósito utilizando cimento com agregado de resíduo plástico e resíduo de gesso

The demand for environmental comfort in construction systems within the insulation and thermal comfort, plus the advent of new laws regulating the minimum requirements of comfort, disposal of solid industrial waste, construction waste, the requirements of consumers by adopting construction methods "cleaner", encouraged the development of this work. Aims technologically characterize the composite proposed in three types of samples (10%, 30% and 50% of thermoset plastic industrial waste) and raw materials: gypsum waste, cement and plastic thermosetting industrial waste in order to produce the composite with properties of thermal insulation: conductivity, thermal diffusivity, specific heat and resistivity. The physical, structural and morphological properties of the raw materials were investigated by thermogravimetry analysis (TG / DSC), X-ray diffraction (DRX), X-ray fluorescence (FXR) and scanning electron microscopy (MEV). Obtaining mechanical properties through the compression strength test. The analysis results indicate characteristics suitable for cement matrix composite production with the addition of thermosetting plastic industrial waste and gypsum waste, with potential application of these materials in composites with properties of thermal insulation. Finally, assessing what proportion showed up with better performance. Considering the analysis and testing carried out.

Implementação LEAN: padronização e auditorias numa linha de pintura industrial

O presente relatório centra-se na aplicação de um sistema de padronização numa célula de pintura industrial. Assim, e como a célula estudada não tinha no momento um sistema de padronização implementado, a principal motivação deste trabalho prendeu-se com a obtenção de benefícios que a normalização de boas práticas pode trazer aos processos, principalmente em indústrias extremamente competitivas, como é o caso do setor em que a empresa em estudo se insere. Para sustentar a implementação da padronização na célula de pintura foi primariamente realizado um estudo teórico sobre a metodologia de base: o LEAN, assim como sobre algumas das suas principais ferramentas. Em particular, destaca-se o Standard Work, ou Padronização, e a Auditoria. Fazendo uso deste levantamento bibliográfico e dos recursos presentes na empresa de acolhimento, foi assim gerado e implementado um sistema padronizado na célula de pintura, composto essencialmente por padrões de tarefas e documentação. Estes têm como principal função criar fundações de base fiável e íntegra, servindo de apoio ao controlo da qualidade, resolução de problemas, e implementação de melhorias no futuro industrial da célula visada. De modo complementar, foi também produzido um conjunto de propostas de implementações de novos métodos, incidindo principalmente na melhoria da qualidade de execução das operações de setup.