Study of unbound nuclei N-11 resonance energy level

The excitation functions of elastic scattering proton which were measured with inverse kinematics of elastic resonance scattering reactions in GANIL and MSU have been fitted by the multi-energy level R-matrix theory. The final result shows that the new energy levels order for nucleus N-11 should be 1/2(+), 1/2(-), 5/2(+), 3/2(+), 3/2(-), 5/2(+), 7/2(-), which is consistent with the experimental results of Be-11 (the mirror nucleus of N-11) and the theoretical calculation of N-11 with GCM theory.

利用重离子辐照技术制备锂离子电池隔膜；Preparation Lithium-ion Battery Separator by Swift Heavy Ion Irradiation Methods

用能量11.4MeV/u和注量1×108ions/cm2的197Au离子垂直辐照聚丙烯薄膜,通过电导测量法监测温度、硫酸浓度和重铬酸钾浓度对径迹蚀刻速率的影响,得到合适的蚀刻条件;成功制备出孔径范围在600—1000nm的重离子径迹聚丙烯孔膜,并用场发射扫描电镜对孔的形状及孔径大小进行了表征,对孔洞锥角的形成进行了分析,为重离子辐照技术制备锂离子电池隔膜提供了实验数据。

Shell effect on stabilization processes following multi-electron transfer in slow Arq+-Ar (g=6-9, 11) collisions

We experimentally investigate the shell effect on the stabilization processes following the multi-electron transfer in slow collisions of Arq+-Ar (q = 6-9, It) The relative cross-section ratios of multi-electron transfer and of the subsequent stabilization with respect to single-electron capture are measured meanwhile compared with the theoretical results predicted by the classical over-barrier model. Our result indicates that the multi-electron transfer is dominant when the projectile charge is large and the subsequent stabilization shows a dramatic variation if the projectile L-shell configuration becomes open. It shows that the subsequent stabilization processes of multiply excited scattering ions have a strong dependence on the projectile shell. (C) 2010 Elsevier BV All rights reserved.

不同林地清理方式对杉木林土壤肥力的影响

研究了杉木林采伐迹地及采伐后的炼山迹地的土壤物理性质、养分含量、微生物数量和酶活性.结果表明,采伐迹地的非毛管孔隙比杉木林地增加23%,自然含水量和毛管持水量则下降25%;炼山迹地土壤容重比杉木林地增加10%,非毛管孔隙、自然含水量和毛管持水量分别下降61%、48%和26%.采伐迹地有机质、全N、全P和全K含量分别比杉木林地下降14%、14%、35%和22%,炼山迹地分别下降37%、37%、47%和7%.采伐迹地碱解N和有效K含量分别比杉木林地增加24%和31%,有效P含量比杉木林地下降15%;炼山迹地的碱解N、有效P和有效K含量分别比杉木林地下降25%、43%和40%.采伐迹地的细菌、真菌和放线菌数量比杉木林地增加1.4、11.3和0.8倍;炼山迹地细菌数量比杉木林地减少24%,真菌和放线菌数量增加了5.0和0.5倍.采伐迹地脲酶、过氧化氢酶和纤维素分解酶活性分别为杉木林地1.9、1.6和2.1倍,而炼山迹地分别为后者的35.4%、90%和106%.湿润土壤有机质、全N和全P含量高,疏松多孔的土壤有利于碱解N、速效P、速效K积累和脲酶活性的增加.真菌数量随毛管孔隙的增加而减少.通气良好有利于提高土壤过氧化氢酶活性.

Sn-modified Pt/SAPO-11 catalysts for selective hydroisomerization of n-paraffins

The hydroconversion of n-paraffins is a key reaction in hydrodewaxing of lubricating base oil. In this paper, we investigate the performance of Pt/SAPO-11 catalysts for isomerization of n-paraffins by the model compound of n-dodecane. Under this experimental condition, yields of feed isomers as well as cracking products are a function of the total n-dodecane conversion. Primary products are methylundecane while multi-brancheds and cracking products are formed in successive reactions. The result shows that the addition of Sn increases the selectivity for isomerization reaction. The most ideal experimental data for hydroconversion of n-dodecane is that the selectivity of isomerized products gets 90% when conversion of n-dodecane is 90% for the Sn-promoted Pt/SAPO-11 catalyst.

Mn-containing AlPO-11 and SAPO-11 catalysts for simultaneous isomerization and dehydrogenation of n-butane

MnAPO-11 and MnAPSO-11 were synthesized hydrothermally, and supported Mn-AlPO-11 and Mn-SAPO-11 were also prepared for comparison. Characterization results showed that there were differences in acidity and reducibility caused by the different incorporation methods of manganese. The manganese species in the samples also weakened the metallic properties of the palladium particles when the latter was added into the catalysts. Catalytic testing results for dehydroisomerization of n-butane indicated that incorporation of manganese increased the selectivity toward isomerization products. The highest isobutene selectivity (34.86%) could be obtained over a Pd/MnAPO-11 catalyst. When a combined catalyst system containing Pd/SAPO-11 and MnAPSO-11 was used in a single bed of two layers, the isobutene selectivity could be greatly improved, as compared to the single catalyst alone.

干旱胁迫对沙地云杉生态型保护酶活性的影响

通过不同干旱胁迫处理,测定了3种生态型(紫果型、绿果型和红果型)沙地云杉叶片和根部的超氧化物歧化酶(SOD)、过氧化氢酶(CAT)、抗坏血酸过氧化物酶(ASP)、过氧化物酶(POD)的活性。结果表明:在叶片中,无论哪种生态型,SOD活性先上升,后下降;紫果型沙地云杉CAT活性一直上升,但变化幅度不大,红果型和绿果型则先升后降;ASP和POD活性变化趋势一致,紫果型一直以较大幅度增加,红果型和绿果型开始迅速增加,而后又迅速下降。在根部,酶活性的变化与叶片中基本一致。因此得知,紫果型沙地云杉抗旱能力最强,绿果型最弱。

南方丘陵人工林林下植物种间关系分析

在2×2联列表的基础上,应用χ2检验和联结系数,检测南方丘陵人工林林下植物种间关系,以期分析南方丘陵人工林植被恢复程度及其稳定性.结果表明,灌草两层联结程度达到显著的种对很少;灌木层极显著的有12种对,显著的有19种对,其余200种对联结程度不显著;草本层极显著和显著各有11种对,其余83种对联结程度不显著.按组间联系及种间的正负关联性,灌木层植物可分为2个种组:Ⅰ.四川红淡比、三叶赤楠、乌饭树、满树星、长托菝葜、格药柃;Ⅱ.大叶胡枝子、白马骨、牡荆.种组Ⅰ与种组Ⅱ之间许多种群间存在显著负关联.优势种往往在种间关系中起着关键作用.草本层优势种狗脊蕨、暗鳞鳞毛蕨、扇叶铁线蕨之间存在极显著正关联,且与多种群存在极显著或显著正关联;灌木层中2个种组均以优势种为联结核心.灌草层中正负关联的比例反映了灌木层和草本层物种处在动态变化中.灌木层正负关联比例为125/106,草本层42/63.最后分析了种间联结方法的几个缺陷,并对该方法的使用提出建议.

受干扰长白山阔叶红松林林分组成及冠层结构特征

通过样地调查对不同干扰方式产生的过伐天然林、次生白桦林和人工落叶松林等群落的结构组成进行分析和分类探讨 ,并选取了林窗片断和叶面积指数两个能表示群落冠层结构的指标进行分析。结果表明 ,林窗片断值分别为 :原始阔叶红松林 0 194、原始阔叶类 0 185、结构转换型 0 315、结构保留型 0 36 3、结构破坏型 0 2 35、严重干扰类型 0 5 5 0、次生白桦林0 2 13和人工落叶松林 0 2 2 7;叶面积指数分别为 :原始阔叶红松林 1 76 6、原始阔叶类 1 6 80、结构转换型 1 2 5 0、结构保留型 1 0 2 8、结构破坏型 1 5 5 0、严重干扰类型 0 6 35、次生白桦林1 731和人工落叶松林 1 4 73。

微过氧化物酶-11的聚集状态对其与Yb~(3+)相互作用的影响

研究了微过氧化物酶-11(MP-11)的聚集状态对其与Yb3+相互作用的影响。紫外-可见(UV-Vis)吸收光谱研究结果表明,在纯水溶液中,由于Yb3+与MP-11分子中血红素卟啉环上的2个丙酸基团的羧基氧发生强的键合作用,使血红素卟啉环的非平面性增加,π-π跃迁所需要的能量减少,但电子跃迁几率降低。因此,MP-11吸收光谱中的Soret带红移10nm,吸光度下降35%。

Thermal-shock resistance of LnMgAl(11)O(19) (Ln = La, Nd, Sm, Gd) with magnetoplumbite structure

Lanthanide hexaaluminates including LaMgAl11O19, NdMgAl11O19, SmMgAl11O19 and GdMgAl11O19 were synthesized via Sol-Gel method. Due to the anisotropic crystal growth, these oxides crystallize in the form of platelets and the platelet thickness increases with the decrease of rare-earth ionic radius. It was observed that the thermal-shock resistances of LaMgAl11O19, NdMgAl11O19 and SmMgAl11O19 oxides were superior to 8YSZ as proved by water quenching tests. In addition, the thinner the platelet. the more interstices are retained in the sintered specimen, and the better thermal-shock resistance the oxide has. Based on SEM images, it can be seen that the SmMgAl11O19 sample exhibits a mixture of the intergranular and transgranular fracture after thermal cycling failure.