Absorption of sound in cellular foams

To further enhance the sound absorption of metal foams via combining the high sound absorption and good heat conductivity of the cellular foam metals, the use and acoustic modeling of these materials are reviewed. The predictions made by three viscous models developed by the authors for the propagation of sound through open-cell metal foams are compared with an experiment both for the metal foams and for the polymer substrates used to manufacture the foam. All models are valid in the limit of low Reynold's number which is valid for the typical cell dimensions found in metal foams provided the amplitude of the waves is below 160 dB. The first model considers the drag experienced by acoustic waves as they propagate passing rigid cylinders parallel to their axes, the second considers the propagation normal to their axes, and the third considers the propagation passing the spherical joints. All three are combined together to give a general model of the acoustic behavior of the foams. In particular, the sound absorption is found to be significant and well predicted by the combined model. In addition, a post-processing technique is described for the experiment used to extract the fundamental wave propagation characteristics of the material.

Ni-silicide growth kinetics in Si and Si/SiO2 core/shell nanowires.

A systematic study of the kinetics of axial Ni silicidation of as-grown and oxidized Si nanowires (SiNWs) with different crystallographic orientations and core diameters ranging from ∼ 10 to 100 nm is presented. For temperatures between 300 and 440 °C the length of the total axial silicide intrusion varies with the square root of time, which provides clear evidence that the rate limiting step is diffusion of Ni through the growing silicide phase(s). A retardation of Ni-silicide formation for oxidized SiNWs is found, indicative of a stress induced lowering of the diffusion coefficients. Extrapolated growth constants indicate that the Ni flux through the silicided NW is dominated by surface diffusion, which is consistent with an inverse square root dependence of the silicide length on the NW diameter as observed for (111) orientated SiNWs. In situ TEM silicidation experiments show that NiSi(2) is the first forming phase for as-grown and oxidized SiNWs. The silicide-SiNW interface is thereby atomically abrupt and typically planar. Ni-rich silicide phases subsequently nucleate close to the Ni reservoir, which for as-grown SiNWs can lead to a complete channel break-off for prolonged silicidation due to significant volume expansion and morphological changes.

Two-photon absorption and self-phase modulation in InGaAsP/InP multi-quantum-well waveguides

We report the first measurement of two-photon absorption (TPA) and self-phase modulation in an InGaAsP/InP multi-quantum-well waveguide. The TPA coefficient, β2, was found to be 60±10 cm/GW at 1.55 μm. Despite operating at 200 nm from the band edge, self-phase modulation as high as 8±2 rad was observed for 30-ps optical pulses at 3.8-W peak input power. A theoretical calculation indicates that this enhanced phase modulation is primarily due to bandfilling in the quantum wells and the free-carrier plasma effect.