784 resultados para ELECTROCHEMICAL POLARIZATION PHENOMENA
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We discuss the Gupta-Bleuler quantization of the free electromagnetic field outside static black holes in the Boulware vacuum. We use a gauge which reduces to the Feynman gauge in Minkowski spacetime. We also discuss its relation with gauges used previously. Then we apply the low-energy sector of this held theory to investigate some low-energy phenomena. First, we discuss the response rate of a static charge outside the Schwarzschild black hole in four dimensions. Next, motivated by string physics, we compute the absorption cross sections of low-energy plane waves for the Schwarzschild and extreme Reissner-Nordstrom black holes in arbitrary dimensions higher than three.
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We derive the equation of state (EOS) for electrically charged neutral dense matter using the quantum hadrodynamics (QHD) model. This is carried out in a non-perturbative manner including quantum corrections for baryons through a realignment of vacuum with baryon-antibaryon condensates. This yields the results of relativistic Hartree approximation of summing over baryonic tadpole diagrams. The quantum corrections from the scalar meson is also taken into account in a similar way. This leads to a softening of the EOS for the hyperonic matter. The formalism also allows Lis to make a self-consistent calculation of the in-medium sigma meson mass. The effects of such quantum corrections on the composition of charged neutral dense matter is considered. The effect of the resulting EOS on the structure of neutron stars is also studied.
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The effect of lepton transverse polarization in B-0-->D(-)l(+)nu(l), B+-->(D) over bar (0)l(+)nu(l) decays (l=tau,mu) is analyzed within the framework of the standard model in the leading order of heavy quark effective theory. It is shown that a nonzero transverse polarization appears due to the electromagnetic final state interaction. The diagrams with intermediate D,D* mesons contributing to the nonvanishing P-T are considered. Regarding only the contribution of these mesons, the values of the tau-lepton transverse polarization averaged over the physical region in the B-0-->D(-)tau(+)nu(l) and B+-->(D) over bar (0)tau(+)nu(l) decays are equal to 2.60x10(-3) and -1.59x10(-3), respectively. In the case of muon decay modes the values of [P-T] are equal to 2.97x10(-4) and -6.79x10(-4).
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The use of light front coordinates in quantum field theories (QFT) always brought some problems and controversies. In this work we explore some aspects of its formalism with respect to the employment of dimensional regularization in the computation of the photon's self-energy at the one-loop level and how the fermion propagator has an important role in the outcoming results.
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)
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The electrochemical behaviour of cold-rolled low carbon steel was studied on both active and passive potential regions in borate buffer solutions with and without the addition of sodium citrate (NaCit). In the active region anodic charges increased significantly and RCT values decreased with citrate, due to the formation of soluble complexes. In the passive potential region the film formed at +0.4 V in borate buffer solution with and without 0.010 M NaCit is probably enriched by Fe3O4 oxide, while films formed at +0.8 V are probably enriched by gamma-Fe2O3. The equivalent circuit [R-s(R(CT)Q)] fitted all experimental impedance data. (C) 2003 Elsevier Ltd. All rights reserved.
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Comparative wear and corrosion properties of Cr3C2-NiCr (CC-TS) (a high-velocity oxyfuel [HVOF]) and hard chromium (HC) coating's obtained on a steel substrate have been studied. The structural characterization was done before and after measurements by optical microscopy, scanning electron microscopy, and scanning white light interferometry. Wear and corrosion properties were evaluated by ball on disk (ASTM G99-90), rubber wheel (ASTM G65-91), and electrochemical measurements of open circuit and polarization curves. The best corrosion and wear resistance was for the CC-TS obtained by HVOF. The open-circuit potential values measured for both samples after 18 h of immersion we're: -0.240 and -0.550 V, respectively, for CC-TS and HC, versus Ag/AgCl,KClsat. Three orders of magnitude lower volume loss were found for CC-TS (HVOF) after friction tests compared with HC.
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The electrochemical behavior in 0.5 M H2SO4 at 25 degreesC of a Cu-Al(9.3 wt%)-Ag(4.7 wt%) alloy submitted to different heat treatments and an annealed Cu- Al(9.7 wt%)-Ag(34.2 wt%) were studied by means of open circuit potential (E-mix) measurements, potentiodynamic polarizations and cyclic voltammetry. SEM and EDX microanalysis were used to examine the changes caused by the electrochemical perturbations. The steady state potentials observed for the studied samples were correlated in terms of the phases present in the alloys surface. The resulting E/I potentiodynamic profiles were explained in terms of the potentiodynamic behavior of pure copper and pure silver. The presence of aluminum decreased the extent of copper oxidation. In the apparent Tafel potential region, two anodic Tafel slopes were obtained: 40 mV dec(-1) in the low potential region and 130 mV dec(-1) in the high potential region, which were related with the electrochemical processes involving copper oxidation. (C) 2001 Elsevier B.V. Ltd. All rights reserved.
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Stainless steel coatings obtained by High Velocity Oxygen Fuel (HVOF) were characterized using optical (OM) and scanning electron microscopy (SEM), electron probe micro-analysis, X-ray diffraction (XRD), open-circuit potential (E-OC) measurements, electrochemical impedance spectroscopy (EIS) and polarisation tests. Differences among coated steels were mainly related with the gun-substrate distance parameter (310 nm for samples A and B and 260 min for C and D). The open-circuit potential values measured for all the samples after 18 h of immersion in aerated and unstirred 3.4% NaCl solution were: - 0.334, - 0.360, - 0.379 and - 0.412 V vs. Ag/AgCl,KClsat. for samples A to D, respectively. For EIS measurements, Nyquist plots showed higher capacitive semi-circle for samples sprayed at longer distance, indicating higher corrosion resistance in NaCl solution. (c) 2005 Elsevier B.V. All rights reserved.
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The analysis of the faradaic impedance of electroactive films provides a characteristic point from which it is possible to estimate the thickness of thin films. Thus, electrochemical impedance spectroscopy was used in this paper as a fast and easy technique to estimate this thickness. The proposed method was checked on PB films. (c) 2006 Elsevier B.V. All rights reserved.