Chemical and mineral compositions of recent and ancient sediments and sedimentary rocks from the Mariana Trench

On the bed and on the ocean slope of the southern latitudinal part of the Mariana Trench ancient sediments, as well as sedimentary and igneous rocks are exposed. In the lower part of the sampled part of the studied section Late Oligocene to Early Miocene chalk-like limestones and marls occur. Upward marly tuffites and tuffs (apparently alternating with carbonate rocks) occur. These rocks are overlain by Early Miocene tuffaceous clays and siliceous-clayey muds. In the upper part of the section there are Pleistocene pelagic clays and ethmodiscus oozes.

Chemical composition in phosphate materials from the ocean floor

Content, distribution patterns, and speciation of Cl in phosphorites and bone phosphate from the ocean floor, as well as in a set of samples from the land are studied. Total Cl content varies from 0.05 to 4.25% in phosphorites and from 2.48 to 2.75% in recent phosphate-bearing sediments. Recent phosphorites are enriched in Cl relative to ancient ones. Bound Cl content (not extractable by washing), which increases with lithification, varies from 0.17 to 0.60% in ocean and land phosphorites and from 0.02% to 1.30% in bone phosphate. Na content in most samples is higher relative to Na of NaCl due to its incorporation into the crystal lattice of apatite. However, the opposite relationship is observed in some samples indicating partial Cl incorporation into the anion complex of phosphate. Behavior of Cl in phosphorites from the present-day ocean floor is controlled by early diagenetic processes, whereas the role of weathering, catagenesis, and hydrogeological factors may be crucial for phosphorites on continents.

Chemical composition of rocks and minerals from the Mid-Atlantic Ridge near 15°20'N

The monograph summarizes results of petrological and geochemical studies of rocks from the ocean floor collected by the authors during expeditions to the Central Atlantic. Detailed work in the Capa Verde transform fault zone gave a large amount of new information about magmatic and hydrothermal systems of the Mid-Atlantic Ridge.

Chemical composition of ultrabasites and gabbro from rift zones of the Indian Ocean

Results of petrographic studies of ultrabasites and gabbro from rift zones of the Indian Ocean are discussed using materials of Cruise 36 of R/V Vityaz. Rocks sampled from two sites 2700 km apart are close to each other in their composition. Petrographically ultrabasic rocks are divided into four subgroups: I - dunite; II - harzburgite, serpentinite; III - plagioclase lherzolite; and IV - metamorphically altered rocks. Petrographic description and chemical composition of basic rock varieties are presented as well as description of rock-forming minerals and their optical properties. Formation of pyroxene and plagioclase is shown to be related to autometasomatosis. Formation of ultrabasite in rift zones is related to complicated processes.

Volcanic rocks from the submarine Vityaz Ridge: their age, chemical and isotopic compositions

Results of geological studies at the submarine Vityaz Ridge carried out during cruises 37 and 41 of R/V Akademik Lavrent'ev in 2005 and 2006 are reported. The studied area is located at an near-island trench of the slope in the central part of the Kuril Island arc. Morphologically it consists of two parts: an inner volcanic arc represented by the Great Kuril Range and an outer arc corresponding to the submarine Vityaz Ridge. Diverse rocks composing the basement and the sedimentary cover of the ridge were recovered by dredging. Based on K-Ar dating and geochemistry, volcanics were divided into Paleocene, Eocene, late Oligocene, and Pliocene-Pleistocene complexes. Each of the complexes reflects a tectonomagmatic stage in the ridge evolution. Geochemical and isotope data on the volcanics indicate contribution of ancient crustal material in the magma source and, correspondingly, formation of this structure on the continental basement. Two-stage model ages (TDM2) vary in a wide range from zero values in mafic rocks to 0.77 Ga in felsic varieties, pointing to presence of Precambrian protolith in the source of the felsic rocks of the Vityaz Ridge. The Pliocene-Pleistocene volcanics are classed with tholeiitic, calc-alkaline, and subalkaline series, which differ in alkali contents and REE fractionation. Values of (La/Sm)_n and (La/Yb)_n ratios vary from 0.74 and 0.84 in the tholeiitic varieties to 1.19 and 1.44 in the calc-alkaline and 2.32 and 3.73 in the subalkaline rocks. All three varieties occur within the same volcanic edifices and formed during differentiation of magmatic melts that were channeled along fault zones from the mantle source slightly enriched in crustal component.

Chemical composition of sediments from DSDP Legs 45 and 71

Results of mineralogical and geochemical investigations of post-Middle Jurassic deposits of the Atlantic Ocean are based on materials of the Deep Sea Drilling Project. Comparative characteristics of primary matter for ''black shales'' are given. Exhalative origin of heavy metal accumulation in near-axial sedimentary deeps of the Mid-Atlantic Ridge (23°N) are shown. History of post-Middle Jurassic sedimentation is considered on the base of clay mineral-, clastic component-, trace and rare- chemical element studies.

Chemical composition and K-Ar age of basalts from the floor of the Indian Ocean

Petrographic description as well as data on chemical composition and K-Ar age of basalts from the floor of the Indian Ocean are reported in the paper.

Chemical composition of ultrabasite and gabbro from the rift zones of the Arabian-Indian and Western Indian ridges

Results of petrographic studies of ultrabasite and gabbro from the rift zones of the Indian Ocean ridges are discussed using materials of R/V Vityaz Cruise 36. Rocks sampled from two sites 2700 km apart are close to each other in their composition. Petrographically ultrabasic rocks are divided into four subgroups: I - dunite; II - harzburgite, serpentinite; III - plagioclase lherzolite; and IV - metamorphically altered rocks. Petrographic description and chemical composition of basic rock varieties are presented as well as description of rock-forming minerals and their optical properties. Formation of pyroxene and plagioclase is shown to be related to autometasomatosis, which concludes the magmatic phase proper in rock mass formation accompanied by activity of residual intragranular liquid. Formation of ultrabasite in the rift zones is related to complicated processes.

Chemical composition of Fe-Mn nodules and crusts from the Pacific Ocean

The book is devoted to study of diagenetic changes of organic matter and mineral part of sediments and interstitial waters of the Pacific Ocean due to physical-chemical and microbiological processes. Microbiological studies deal with different groups of bacteria. Regularities of quantitative distribution and the role of microorganisms in geochemical processes are under consideration. Geochemical studies highlight redox processes of the early stages of sediment diagenesis, alterations of interstitial waters, regularities of variations in chemical composition of iron-manganese nodules.