Cretaceous-Tertiary ichthyoliths of brown clay intervals

The pattern of ichthyolith distribution established in sequences with stratigraphies based on calcareous or siliceous microfossils is used to provide age correlations for three deep-sea pelagic clay intervals that lack the better known microfossils. At Site 637, approximately 25 m of brown clay in Cores 103-637A-21R through 103-637A-23R underlies upper Miocene sediments and is of Paleocene to early Eocene age. At Site 639, 1.7 m of brown clay in Core 103-639C-2R is Eocene to Oligocene. At Site 640, 3.5 m of clay in Cores 103-640A-1R and 103-640A-2R contains a Cretaceous to Paleocene sequence, with the Cretaceous/Tertiary boundary between 84 and 103 cm in Section 103-640A-2R-1.

Silicate content in sediment ofthe Santa Monica Basin, California

Seafloor recycling of organic materials in Santa Monica Basin, California was examined through in situ benthic chamber experiments, shipboard whole-core incubations and pore water studies. Mass balance calculations indicate that the data are internally consistent and that the estimated benthic exchange rates compare well with those derived from deep, moored conical sediment traps and hydrographic modeling. Pore water and benthic flux observations indicate that the metabolizable organic matter at the seafloor must be composed of at least two fractions of very different reactivities. While the majority of reactive organic compounds degrade quickly, with a half-life of <=6.5 years, 1/4 of the total metabolizable organic matter appears to react more slowly, with a half-life on the order of 1700 years. Down-core changes in pore water sulfate and titration alkalinity are not explained by stoichiometric models of organic matter diagenesis and suggest that reactions not considered previously must be influencing the pore water concentrations. Measured recycling and burial rates indicate that 43% of the organic carbon reaching the basin seafloor is permanently buried. The results for Santa Monica Basin are compared to those reported for other California Borderland Basins that differ in sedimentation rate and bottom water oxygen content. Organic carbon burial rates for the Borderland Basins are strongly correlated with total organic carbon deposition rate and bulk sedimentation rate. No significant correlation is observed between carbon burial and bottom water oxygen, extent of oxic mineralization and sediment mixing. Thus, for the California Borderlands, it appears that carbon burial rates are primarily controlled by input rates and not by variations in preservation.

Grain-size and bulk and clay mineralogy of ODP Leg 204 sediments

We present grain size, granulometric statistical parameters, and calcium carbonate content of sediment samples from the summit and east and west flanks of southern Hydrate Ridge (Sites 1244-1250). These data are compared with magnetic susceptibility measurements from the same intervals. Bulk and clay mineralogy from Sites 1244 (east flank), 1247 (west flank), and 1250 (summit) are also presented. The integration of these data allows us to characterize the main sedimentary facies and composition of the Quaternary age sediments from southern Hydrate Ridge.

Silicate in marine sediments from the Emerland Basin, North Atlantic

A method was developed to measure porosity and dissolved interstitial silicate at millimeter intervals or less in a sediment core. In cores from Emerald Basin (Scotian Shelf), interstitial concentrations near the sediment surface did not drop rapidly to bottom-water concentrations as measured in bottle casts (28 µM) but remained as high as 166 µM in the upper 0.5 mm of sediment High rates of benthic silicate release were measured which could not be accounted for by interstitial concentration gradients or by ventilation of macro-invertebrate burrows. The silicate discontinuity observed between the sediments and water column suggests that a diffusive sublayer exists in a zone of viscous flow above the sediment surface. This is possible only if a surface reaction is primarily responsible for silicate release. By assuming a linear concentration gradient across this diffusive sublayer, the silicate release rates were used to estimate the thickness of the sublayer to be about 2 mm.

Clay minerals at DSDP Sites 71-511 and 71-513

The distribution of clay minerals, determined by X-ray diffraction, is given for Jurassic to Holocene sediments recovered at DSDP Sites 511 and 513 in the Southwest Atlantic. These data, plus the lithologic and paleoenvironmental information gathered by the shipboard scientists, are used to subdivide the sedimentary sequence into genetic lithologic facies labeled series, seven for Site 511 and two for Site 513. Sediments of these series reflect the main historical and paleoenvironmental events which other means of study have determined to affect this region; particularly important was the opening of the South Atlantic during the Early Cretaceous.