K-Ar dating of magmatic rocks from the Urup Island, Kuril Island Chain

An isotope-geochronological study of Neogene-Quaternary igneous rocks from the Urup Island (Greater Kuril Ridge) was carried out. It was established that magmatic activity in the island developed during the last 10 my and it was not interrupted by long inactive periods. K-Ar data obtained along with results of diatomic analysis are in good agreement with the regional stratigraphic scheme of Paleogene and Neogene deposits and the intraregional correlation scheme of magmatic rocks in the Kuril Islands, which are developed for the State Geologic Map, scale 1:200 000 (Second edition). In the present-day territory of the Urup Island, the earliest Late Miocene - Early Pliocene (10.5-4.5 Ma) magmatic stage was associated with formation of the Rybakovsky andesite volcanic complex, which is represented by an effusive series (Rybakovskaya Suite) and subvolcanic rocks. Actually at the same time (6.6-4.7 Ma), but at a great depth, intrusive bodies of the Prasolovsky plagiogranite-diorite plutonic complex were intruded. The Pliocene stage of magmatism in the Urup Island is characterized by formation of rocks of the Kamuysky dacitic volcanic complex (4.0-2.1 Ma). This complex is locally represented only by subvolcanic acidic bodies, and its occurrence in the island is limited. During the Pliocene - Early Neopleistocene stage of magmatism (3.0-0.8 Ma) the Fregatsky andesibasalt volcanic complex was formed in the Urup Island. This complex includes effusive series (Fregatskaya unit) and subvolcanic bodies. Quaternary time in the Urup Island is characterized by eruptive activity in subaerial conditions with formation of effusive-pyroclastic intermediate-basic rocks of the Bogatyrsky Middle Neopleistocene - Holocene complex (<0.5 Ma). Rocks of this complex formed stratovolcano cones. Pyroclastic rocks of the Rokovsky dacitic volcanic complex were erupted simultaneously. The mentioned magmatic complexes of the Urup Island well correlate with the distinguished magmatic complexes within the bounds of contiguous insular blocks of the Greater Kuril Arc and confirm uniform geologic history of magmatic development of the region.

(Table 1) CPI17-23, hopanoic acid, and n-C35 + lycopane/n-C31 ratios as well as 17beta(H), 21beta(H) homohopane, long-chain alkanes, and alkenones concentrations in IODP Exp302

During Integrated Ocean Drilling Program Expedition 302 (Arctic Coring Expedition (ACEX)) a more than 200 m thick sequence of Paleogene organic carbon (OC)-rich (black shale type) sediments was drilled. Here we present new biomarker data determined in ACEX sediment samples to decipher processes controlling OC accumulation and their paleoenvironmental significance during periods of Paleogene global warmth and proposed increased freshwater discharge in the early Cenozoic. Specific source-related biomarkers including n-alkanes, fatty acids, isoprenoids, carotenoids, hopanes/hopenes, hopanoic acids, aromatic terpenoids, and long-chain alkenones show a high variability of components, derived from marine and terrestrial origin. The distribution of hopanoic acid isomers is dominated by compounds with the biological 17beta(H), 21beta(H) configuration indicating a low level of maturity. On the basis of the biomarker data the terrestrial OC supply was significantly enriched during the late Paleocene and part of the earliest Eocene, whereas increased aquatic contributions and euxinic conditions of variable intensity were determined for the Paleocene-Eocene thermal maximum and Eocene thermal maximum 2 events as well as the middle Eocene time interval. Furthermore, samples from the middle Eocene are characterized by the occurrence of long-chain alkenones, high proportions of lycopane, and high ratios (>0.6) of (n-C35 + lycopane)/n-C31. The occurrence of C37-alkenenones, which were first determined toward the end of the Azolla freshwater event, indicates that the OC becomes more marine in origin during the middle Eocene. Preliminary UK'37- based sea surface temperature (SST) values display a longterm temperature decrease of about 15C during the time interval 49-44.5 Ma (25° to 10°C), coinciding with the global benthic d18O cooling trend after the early Eocene climatic optimum. At about 46 Ma, parallel with onset of ice-rafted debris, SST (interpreted as summer temperatures) decreased to values <15°C. For the late early Miocene a SST of 11°-15°C was determined. Most of the middle Eocene ACEX sediments are characterized by a smooth short-chain n-alkane distribution, which may point to natural oil-type hydrocarbons from leakage of petroleum reservoirs or erosion of related source rocks and redeposition.