新型吡唑类化合物DL-1的硝化抑制效应初探

以国内外应用较为广泛的硝化抑制剂双氰胺(DCD)为参比对象,采用室内培养方法,对新型吡唑类化合物DL-1的硝化抑制效应进行初步探讨.结果表明,DL-1对土壤中铵的氧化过程具有显著的抑制效应,前3周的硝化抑制率可达70%以上,且硝化抑制能力在第14天至28天最强.与等量DCD相比,施用量为(NH4)2SO4氮量1.0%的DL-1在14、21和28d使土壤中的NO3--N含量分别下降26.23%、33.27%和23.31%;与不加抑制剂的对照处理相比,土壤NO3--N含量则分别下降了71.12%、69.10%和55.14%.当DL-1用量为(NH4)2SO4氮量的2.0%时,土壤的硝化作用受到了更强烈的抑制,到培养第90天试验结束,土壤中的NO3--N含量始终维持在较低水平.

Synthesis and characterization of hyperbranched poly(ester-amide)s based on gallic acid and DL-2-aminobutyric acid

A novel AB(3)-type monomer was prepared from gallic acid and DL-2-aminobutyric acid, and used for the synthesis of the biocompatible hyperbranched poly(ester-amide)s by self-polycondensation. The polymers were characterized via FTIR and NMR spectroscopy and thermal analysis, and the average degree of branching of the polymers was estimated to be 0.75. The polymers with abundant acetyl end groups were found to be amorphous with lower intrinsic viscosity, better thermal stability and excellent solubility.

Enzymatic degradation of poly(epsilon-caprolactone)/poly(DL-lactide) blends in phosphate buffer solution

Blend films of poly(epsilon-caprolactone) (PCL) and poly(DL-lactide) (PDLLA) with 0.5 weight fraction of PCL were prepared by means of solution casting and their degradation behavior was studied in phosphate buffer solution containing Pseudomonas (PS) lipase. Enzymatic degradation of the blend films occurred continuously within the first 6 days and finally stopped when the film weight loss reached 50%, showing that only PCL in the blends degraded under the action of PS lipase in the buffer solution. These results indicate the selectivity of PS lipase on the promotion of degradation for PCL and PDLLA. The thermal properties and morphology of the blend films were investigated by differential scanning calorimetry, wide-angle X-ray diffraction and scanning electron microscopy (SEM). The morphology resulting from aggregate structures of PCL in the blends was destroyed in the enzymatic degradation process, as observed by SEM. These results confirm again the enzymatic degradation of PCL in the blends in the presence of PS lipase. (C) 1999 Published by Elsevier Science Ltd. All rights reserved.

pH-potentiometric study on rare earths and calcium binary and ternary complexes with DL-malic acid and L-hydroxyproline

The stability constants of M-L binary system and M-L-L' (M = La3+ similar to Yb3+, Y3+ and Ca2+; L= DL-malic aicd, L' = L-hydroxyproline) ternary system were determined by pH-(0)-tentiometric method under the simulating physiological condition(37 degrees C, I=0.15 mol/L NaCl). The complex species MpLqLr'H-s(abbr as pqrs) in the sytems were ascertained by program COMPLEX. The results show that there are three species(1101, 1100 and 1200) in M-L binary system and one species(1010) in M-L' binary system. In addition to the above four species, a new species, 1112 was found in the M-L-L' ternary system, which is the only species of mixed ligands. Rare earth ions form more stable complexes than calcium ion does and the stability differences between their complexes in the ternary system are less than that in the binary system. The distributions of all the species in La-L-L' ternary system vs pH are discussed.

稀土、钙的DL-苹果酸和L-羟脯氨酸混配配合物研究

在模拟生理条件下（３７℃，０１５ｍｏｌ·Ｌ－１ＮａＣｌ），用ｐＨ电位法测定了１４种稀土、钙的ＤＬ苹果酸和Ｌ羟脯氨酸二元、三元配合物的稳定常数，用计算机优化确定了二元体系，苹果酸配合物存在１１０１、１１００和１２００型，羟脯氨酸配合物存在１０１０型混配配合物，苹果酸配合物的稳定常数大于羟脯氨酸。三元体系中仅生成１１１２型混配配合物。各体系中稀土配合物稳定常数均大于钙的。讨论了各物种随ｐＨ的转化过程，探讨了生物体内稀土与钙可能发生的竞争、取代作用及特点。

Studies on the coordination of lanthanide with L-hydroxyproline and DL-citrulline

The stability constants of binary and ternary complexes of lanthanide with L-hydroxyproline and DL-citrulline were obtained by using potentiometric titration under the physiological condition(37 degrees C, 0.15 mol/L NaCl). The coordination of lanthanide with the two ligands was discussed.

TETRAKIS(MU-DL-ALANINE-O-O')OCTA-AGUADIERBIUM(III) HEXAPERCHLORATE

The structure of the title compound, [Er-2(C3H7NO2)(4)- (H2O)(8)](ClO4)(6), consists of dimeric [Er-2(DL-alanine)(4)-(H2O)(8)](6+) cations and perchlorate anions. The four alanine molecules act as bridging ligands linking two Er3+ ions through their carboxyl O atoms. Each Er3+ ion is also coordinated by four water molecules to complete eightfold coordination in a square antiprism fashion. The perchlorate anions and the methyl groups of the alanine ligands are disordered.

CRYSTAL-STRUCTURE AND THERMODYNAMIC PARAMETERS OF NYLON-1010

WAXD, SAXS, FTIR, DSC and density techniques have been used to investigate the crystal structure, crystal density rho(c), amorphous density rho(a), equilibrium heat of fusion DELTAH(m)degrees and equilibrium melting temperature T(m)degrees. By extrapolating the straight lines in the FTIR absorbance against density plot to zero intensity, rho(c) and rho(a) were estimated to be 1.098 and 1.003 g/cm3 respectively. The rho(c) obtained was too low in value. From X-ray diffraction patterns of uniaxially oriented fibres, the crystal structure of Nylon-1010 was determined. The Nylon-1010 crystallized in the triclinic system, with lattice dimensions: a = 4.9 angstrom, b = 5.4 angstrom, c = 27.8 angstrom, alpha = 49-degrees, beta = 77-degrees, gamma = 63.5-degrees. The unit cell contained one monomeric unit, the space group was P1BAR, and the correct value of rho(c) was 1.135 g/cm3. The degree of crystallinity of the polymer was determined as about 60% (at RT) using Ruland's method. SAXS has been used to investigate the crystalline lamellar thickness, long period, transition zone, the specific inner surface and the electron density difference between the crystalline and amorphous regions for Nylon-1010. The analysis of data was based upon a one-dimensional electron-density correlation function. DELTAH(m)degrees was estimated to be 244.0 J/g by extrapolation of DELTAH(m)degrees in the plot of heat of fusion against specific volume of semicrystalline specimens to the completely crystalline condition (V(sp)c = 1/rho(c)). Owing to the ease of recrystallization of melt-crystallized Nylon-1010 specimens, the well-known Hoffman's T(m)-T(c) method failed in determining T(m)degrees and a Kamide double extrapolation method was adopted. The T(m)degrees value so obtained was 487 K.

高氯酸四(DL-a-缬氨酸)八水合二钐的合成和结构

α-氨基酸在人体有极为重要的生理作用,近年来人们对其稀土配合物进行了广泛的研究。进一步研究稀土氨基酸配合物的单晶结构对于探讨稀土离子与生物体的作用是很有意义的。将高氯酸钐溶液与生化试剂DL-a-缬氨酸以1:1摩尔比混合,在75℃水浴中反应6小时,加热浓缩后,室温下缓慢挥发,即得到浅黄色透明棱状晶体。 结果与讨论

pH电位法研究稀土与N—乙酰基—DL���缬氨酸的配位作用

本文以pH电位法在25.0±0.1℃及0.10mol/dm_3(NaClO_4)离子强度下测定了N—乙酰基—DL���缬氨酸的质子化常数,并系统地研究了该配体与十五种稀土元素的配应作用。发现在所研究的pH范围内,生成1:1配合物。稀土与N—乙酰基—DL���缬氨酸配合物的稳定性呈现明显的“钆断效应”。

NMR-STUDIES ON THE COORDINATION OF RARE-EARTHS WITH GLYCYL-DL-VALINE AND THE CONFORMATION OF THEIR COMPLEX IN AQUEOUS-SOLUTION

In this paper lanthanide-induced shifts have been measured for C-13 and H-1 nuclei of glycyl-DL-valine in the presence of three lanthanide cations (La3+, Ho3+ and Yb3+) in aqueous solution. The stability constants of the coordination compounds of rare earths (Ho, Yb) with glycyl-DL-valine have been calculated. The coordination of rare earths with the ligand has been discussed. The simulation for conformation of lanthanide coordination compounds with glycyl-DL-valine shows that the ligand is coordinated to lanthanide ion through oxygen atoms of carboxyl group and the bond length of Ln-O is 0.226 nm. In the coordination compounds glycyl-DL-valine is in extended state with minimal steric hindrance.