QUADRUPOLE CENTRAL TRANSITION NMR SPECTROSCOPY OF QUADRUPOLAR NUCLEI IN SOLUTION

This thesis reports on 17O (I = 5/2) and 59Co (I = 7/2) quadrupole central transition (QCT) NMR studies of three classes of biologically important molecules: glucose, nicotinamide and Vitamin B12 derivatives. Extensive QCT NMR experiments were performed over a wide range of molecular motion by changing solvent viscosity and temperature. 17O-labels were introduced at the 5- and 6-positions respectively: D-[5-17O]-glucose and D-[6-17O]-glucose following the literature method. QCT NMR greatly increased the molecular size limit obtained by ordinary solution NMR. It requires much lower temperatures to get the optimal spectral resolution, which are preferable for biological molecules. In addition, quadrupolar product parameter (PQ) and shielding anisotropy product parameter (PSA) were obtained for hydroxide group and amide group for the first time. For conventional NMR studies of quadrupolar nuclei, only PQ is accessible while QCT NMR obtained both PQ and PSA simultaneously. Our experiments also suggest the resolution of QCT NMR can be even better than that obtained by conventional NMR. We observed for the first time that the second-order quadrupolar interaction becomes a dominant relaxation mechanism under ultraslow motion. All these observations suggest that QCT NMR can become a standard technique for studying quadrupolar nuclei in solution.

Accelerated and natural carbonation of concretes with internal curing and shrinkage/viscosity modifiers

Abstract In many parts of the world, corrosion of reinforcing steel in concrete induced by carbonation of the concrete continues to be a major durability concern. This paper investigates the accelerated and natural carbonation resistance of a set of seven concretes, specifically evaluating the effects of internal curing and/or shrinkage/viscosity modifiers on carbonation resistance. In addition to five different ordinary portland cement (OPC) concretes, two concretes containing 20 % of a Class F fly ash as replacement for cement on a mass basis are also evaluated. For all seven concrete mixtures, a good correlation between accelerated (lab) and natural (field) measured carbonation coefficients is observed. Conversely, there is less correlation observed between the specimens’ carbonation resistance and their respective 28 days compressive strengths, with the mixtures containing the shrinkage/viscosity modifier specifically exhibiting an anomalous behavior of higher carbonation resistance at lower strength levels. For both the accelerated and natural exposures, the lowest carbonation coefficients are obtained for two mixtures, one containing the shrinkage/viscosity modifier added in the mixing water and the other containing a solution of the same admixture used to pre-wet fine lightweight aggregate. Additionally, the fly ash mixtures exhibited a significantly higher carbonation coefficient in both exposures than their corresponding OPC concretes.

About a Vanishing Viscosity-Capillarity Method

We consider a class of nonlinear dissipative-dispersive perturbations of the scalar conservation law @tu + div f (u) = 01 and we study the convergence of the approximated solutions to its entropy solution. In particular, we obtain conditions under which the balance between dissipation and dispersion gives rise to the convergence (by DiPerna's measure-valued solution technique).

An approximate method for the solution of an influence function foil rolling model

Fleck and Johnson (Int. J. Mech. Sci. 29 (1987) 507) and Fleck et al. (Proc. Inst. Mech. Eng. 206 (1992) 119) have developed foil rolling models which allow for large deformations in the roll profile, including the possibility that the rolls flatten completely. However, these models require computationally expensive iterative solution techniques. A new approach to the approximate solution of the Fleck et al. (1992) Influence Function Model has been developed using both analytic and approximation techniques. The numerical difficulties arising from solving an integral equation in the flattened region have been reduced by applying an Inverse Hilbert Transform to get an analytic expression for the pressure. The method described in this paper is applicable to cases where there is or there is not a flat region.

An Efficient and Verifiable Solution to the Millionaire Problem

A new solution to the millionaire problem is designed on the base of two new techniques: zero test and batch equation. Zero test is a technique used to test whether one or more ciphertext contains a zero without revealing other information. Batch equation is a technique used to test equality of multiple integers. Combination of these two techniques produces the only known solution to the millionaire problem that is correct, private, publicly verifiable and efficient at the same time.