1000 resultados para Termo-mecânica. Interconector cerâmico. Interconector metálico. Cromita de lantânio. PaCOS
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Pós-graduação em Engenharia Mecânica - FEG
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This work presents a proposal to create a Polo Ceramic Craft in the town of Indiana - SP, through the potter’s organization in a cooperative that will coordinate activities to add value to ceramic pieces. To achieve this, two things are essential: improving the ceramic body and improve the properties of the ceramic material. For the first action it’s necessary to create a Central Mass Production of Ceramics, to provide raw materials and homogeneous composition that results in differentiated ceramic after burning process (sintering). To this end, we propose the incorporation of additives (which act as fluxes) to the clay material. These additives can be mineral such as feldspar and nefelinas or leavings, such as glass powder obtained from disposable containers. For the second action is necessary to acquire an oven, electric or gas, it reaches higher temperatures (around 1200 ° C). The presence of the additive and burning at higher temperatures will enable better production of sintered ceramic material with less porosity and water absorption and higher mechanical strength, and pieces vitrified and glazed, allowing them to assign a higher value. For the production of these materials (thinner walls) requires a smaller volume of clayey raw materials. Besides benefiting the ceramic pieces, the proposed changes reduce the environmental impact caused by burning wood, since it will be replaced by natural gas (or electricity), and even will reduce the disposal of glass containers in the environment by recycling and incorporating this material in the clay. From a social standpoint, the cooperative is crucial to the viability of the proposed project, to coordinate activities and commercial production, which will result in better wages and profits for companies and consequently for the city and its population
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Na reabilitação protética com implantes, a reconstituição das características anatômicas do tecido peri-implantar é fundamental para a obtenção de uma estética ótima. Como os componentes metálicos não transmitem a luz, fazem com que os pacientes com fenótipos gengivais finos apresentem uma coloração escurecida, resultante da limitação estética desses componentes. Pilares cerâmicos (alumina ou zircônia) têm sido utilizados para resolver esse problema, os quais possibilitam a complementação com próteses metal free. A indústria fornece, para alguns sistemas, componentes pré-fabricados cerâmicos a serem personalizados por desgastes e componentes personalizados confeccionados com sistemas CAD/CAM e CAD/MAN. Tendo em vista as limitações de algumas das conexões desses componentes, o objetivo desse estudo é apresentar a técnica laboratorial para confecção de um pilar personalizado cerâmico realizado sobre pilar UCLA de sobrefundição. Concluiu-se que a utilização da cerâmica feldspática proporciona ótima estética, boa transparência, resistência mecânica, baixo custo, melhor capacidade adesiva, com utilização de cimentos resinosos, e, principalmente, técnica de amplo domínio dos laboratórios.
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Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)
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The main goal of this work is to investigate the effects of a nonlinear cubic term inserted in the Schrödinger equation for one-dimensional potentials studied in Quantum Mechanics textbooks. Being the main tool the numerical analysis in a large number of works, the analysis of this effect by this term in the potential itself, in order to work with an analytical solution, can be considered something new. For the harmonic oscillator potential, the analysis was made from a numerical method, comparing the result with the known results in the literature. In the case of the infinite well potential and the step potential, hoping to work with an analytical solution, by construction we started with the known wavefunction for the linear case noting the effects in the other physical quantities. The coupling of the physical quantities involved in this work has yielded, besides many complications in the calculations, a series of conditions on the existence and validity of the solutions in regard to the system possible configurations
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This work deals in a general way, the history and advantages of steel buildings, as well as its increasing usage in Brazil in the last century. This work also generally describes some types and its uses of metal frame. It also demonstrates the use of the NBR 8800: 2008 standard and its calculation methods through the scale out materials regulated in Brazil for an industrial warehouse project small and simple portico metal frame. Given that the construction requirements include a locational influence following the normative indications of the NBR 6123, for the winding scale out, since this effect combined with the permanent loads must be seriously evaluated due to the shape type effort about acting simultaneous axial force and bending moments obeying the limitations applied to the structure according to NBR 8800. As it has been explained the calculations that ensures mechanical stability and suggesting an analysis of the efficiency of the used materials
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The main goal of this work is to investigate the effects of a nonlinear cubic term inserted in the Schrödinger equation for one-dimensional potentials studied in Quantum Mechanics textbooks. Being the main tool the numerical analysis in a large number of works, the analysis of this effect by this term in the potential itself, in order to work with an analytical solution, can be considered something new. For the harmonic oscillator potential, the analysis was made from a numerical method, comparing the result with the known results in the literature. In the case of the infinite well potential and the step potential, hoping to work with an analytical solution, by construction we started with the known wavefunction for the linear case noting the effects in the other physical quantities. The coupling of the physical quantities involved in this work has yielded, besides many complications in the calculations, a series of conditions on the existence and validity of the solutions in regard to the system possible configurations
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This work deals in a general way, the history and advantages of steel buildings, as well as its increasing usage in Brazil in the last century. This work also generally describes some types and its uses of metal frame. It also demonstrates the use of the NBR 8800: 2008 standard and its calculation methods through the scale out materials regulated in Brazil for an industrial warehouse project small and simple portico metal frame. Given that the construction requirements include a locational influence following the normative indications of the NBR 6123, for the winding scale out, since this effect combined with the permanent loads must be seriously evaluated due to the shape type effort about acting simultaneous axial force and bending moments obeying the limitations applied to the structure according to NBR 8800. As it has been explained the calculations that ensures mechanical stability and suggesting an analysis of the efficiency of the used materials
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La motivación principal de este trabajo fin de máster es el estudio del comportamiento en rotura de un material metálico muy dúctil como es una aleación de aluminio. El conocimiento del comportamiento de los materiales en su régimen plástico es muy valioso, puesto que el concepto de ductilidad de un material está relacionado directamente con la seguridad de una estructura. Un material dúctil es aquel que resiste estados tensionales elevados y alcanza altos niveles de deformación, siendo capaz de absorber gran cantidad de energía antes de su rotura y permitiendo una redistribución de esfuerzos entre elementos estructurales. Por tanto, la utilización de materiales dúctiles en el mundo de la construcción supone en general un incremento de la seguridad estructural por su “capacidad de aviso”, es decir, la deformación que estos materiales experimentan antes de su rotura. Al contrario que los materiales frágiles, que carecen de esta capacidad de aviso antes de su rotura, produciéndose ésta de forma repentina y sin apenas deformación previa. En relación a esto, el ensayo de tracción simple se considera una de las técnicas más sencillas y utilizadas en la caracterización de materiales metálicos, puesto que a partir de la curva fuerza-desplazamiento que este ensayo proporciona, permite obtener de forma precisa la curva tensión-deformación desde el instante de carga máxima. No obstante, existen dificultades para la definición del comportamiento del material desde el instante de carga máxima hasta rotura, lo que provoca que habitualmente no se considere este último tramo de la curva tensión-deformación cuando, tal y como sabemos, contiene una información muy importante y valiosa. Y es que, este último tramo de la curva tensión-deformación es primordial a la hora de determinar la energía máxima que un elemento es capaz de absorber antes de su rotura, aspecto elemental, por ejemplo para conocer si una rotura ha sido accidental o intencionada. Por tanto, el tramo final de la curva tensión-deformación proporciona información muy interesante sobre el comportamiento del material frente a situaciones límite de carga. El objetivo por tanto va a ser continuar con el trabajo realizado por el doctor Ingeniero de Caminos, Canales y Puertos, Fernando Suárez Guerra, el cual estudió en su Tesis Doctoral el comportamiento en rotura de dos materiales metálicos como son, un Material 1: acero perlítico empleado en la fabricación de alambres de pretensado, y un Material 2: acero tipo B 500 SD empleado como armadura pasiva en hormigón armado. Estos materiales presentan un comportamiento a rotura claramente diferenciado, siendo más dúctil el Material 2 que el Material 1. Tomando como partida esta Tesis Doctoral, este Trabajo Fin de Máster pretende continuar con el estudio del comportamiento en rotura de un material metálico mucho más dúctil que los experimentados anteriormente, como es el aluminio. Analizando el último tramo de la curva tensión-deformación, que corresponde al tramo entre el instante de carga máxima y el de rotura del material. Atendiendo a los mecanismos de rotura de un material metálico, es necesario distinguir dos comportamientos distintos. Uno que corresponde a una rotura en forma de copa y cono, y otro que corresponde a una superficie de rotura plana perpendicular a la dirección de aplicación de la carga.
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La madera termotratada es madera modificada mediante un proceso térmico a elevadas temperaturas que le proporciona mayor estabilidad dimensional y durabilidad sin incorporar productos químicos perjudiciales para el medio ambiente. Hasta el momento se ha aplicado fundamentalmente a madera de coniferas por motivos económicos, siendo su uso más habitual en ambientes exteriores o de elevada humedad, como elementos de revestimiento no estructurales, carpinterías, mobiliario de jardín, etc. En la presente tesis se estudia la viabilidad de la madera termotratada de frondosas para uso estructural, en particular fresno (Fraxinus excelsior L) y haya (Fagus sylvatica L). Con este fin, y considerando que el termotratamiento modifica la estructura interna de la madera resultando en un nuevo material, se realizan estudios experimentales y numéricos para su caracterización. Estos trabajos se desarrollan bajo el enfoque de la Mecánica de Fractura debido a la pérdida de resistencia y aumento de fragilidad que presenta el material, especialmente a tracción perpendicular a las fibras. Así mismo, se lleva a cabo una recopilación de las bases, fundamentos y metodologías de esta teoría aplicados a madera sin tratar y otros materiales debido a la inexistencia de este tipo de estudios en madera termotratada. De igual manera se realiza un programa de caracterización mecánica del material para determinar sus propiedades elásticas considerando un modelo ortótropo, necesarios en la investigación del comportamiento a fractura. El trabajo derivó en el desarrollo de un nuevo método de ensayo para la determinación multiparamétrica a partir de un sólo espécimen, proporcionando resultados mucho más robustos que los obtenidos con la metodología convencional de ensayos. En base a los trabajos realizados, considerando las limitaciones de resistencia y fragilidad, así como la dudosa aplicabilidad de las normativas existentes en madera sin tratar, se aconseja no utilizar tratamientos térmicos intensos en elementos estructurales primarios. Se propone su aplicación en elementos secundarios, de manera que un posible colapso no implique una pérdida de fiabilidad global de la estructura. Se estudia la viabilidad de un panel sandwich innovador y ecológico para fachadas expuesto a cargas de viento, compuesto de madera termotratada en las caras y panel aislante de fibras de madera con función estructural en el alma. Esta investigación se desarrolló dentro del proyecto de investigación Europeo "Holiwood", Holistic implementation of European thermal treated hardwood (TMT) in the sector of construction industry and noise protection by sustainable, knowledge-based and value added products, perteneciente al sexto Programa Marco. ABSTRACT Hcat-trcatcd wood is modified wood by a thermal process at high temperatures which provides greater dimensional stability and durability without adding harmful chemicals to the environment. It has been mainly applied to softwoods due mainly to economical reasons, being its most common use outdoors or in high humidity environments, as non-structural elements, furniture, etc. The present Thesis studies the feasibility of heat-treated hardwoods for structural uses, particularly ash (Fraxinus excelsior L) and beech (Fagus sylvatica L). To this end, and considering that heat treatment modifies the internal structure of the wood resulting in a new material, experimental and numerical studies are performed for its characterization. This investigation is developed under the approach of Fracture Mechanics due to the loss of strength and the increase in brittlcncss of the material, especially in tension perpendicular to the grain. Likewise, it holds a collection of the bases, foundations and methodologies of this theory applied to untreated wood and other materials due to the lack of such studies in heat-treated wood. In addition, studies for the mechanical characterization of the material are performed in order to determine the elastic properties considering an orthotropic model. This work is necessary in the investigation of the fracture behavior. It led to the development of a new test method for multiparameter determination by using just a single specimen, providing much more robust results than those obtained with conventional test methodology. Based on this investigation, and considering the limitations of strength and brittleness, and the questionable applicability of existing standards for untreated wood, it is advised not to use intense heat treatments in primary structural elements. It is proposed the application to secondary elements, so that a possible collapse does not involve a loss of overall reliability of the structure. It is studied the feasibility of an innovative and ecological sandwich panel for facades exposed to wind loads, composed by heat-treated wood faces and insulating wood fiberboard with structural function in the core. This investigación was developed within the European research project "Holiwood", Holistic implementation of European thermal treated hardwood (TMT) in the sector of construction industry and noise protection by sustainable, knowledge-based and value added products, of the Sixth Framework Program.
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Para la supervivencia de cualquier industria en un mercado cada vez más competitivo resulta esencial mejorar la calidad del producto y reducir costos. Como parte de esa tendencia, el proceso de diseño, tanto de bienes como de procesos de manufactura, debe ser confiable e insumir el menor tiempo posible para permitir agilidad y eficacia en los cambios y las innovaciones que requiere el mercado. Es necesario abandonar los procesos de desarrollo basados en largas y costosas secuencias de prueba y error y reemplazarlos por procedimientos más cortos y eficientes. Las herramientas informáticas y los modelos computacionales han contribuido en gran medida a lograr dicho objetivo. Estos métodos son cada vez más utilizados en industrias tan importantes como la automotriz o la de maquinaria y equipamiento agrícola, ambas de relevante importancia en la actividad económica de nuestra provincia. En las mencionadas industrias, con la intención de mejorar las prestaciones del producto, de reducir costos de mantenimiento para igual prestación y, sobre todo, con el objetivo de disminuir el peso total del vehículo, factor importante en relación con el ahorro de combustible, es habitual la sustitución de algunos materiales tradicionalmente utilizados por otros con mejor relación prestación/costo y prestación/peso. Dentro de este grupo de nuevos materiales que se emplean en la industria automotriz se encuentran los compuestos, las aleaciones ligeras y la fundición dúctil, los cuales han estado substituyendo al acero o a la fundición gris en algunas piezas. La meta de esta investigación es generar modelos computacionales multiescala de: a) el proceso de tratamiento térmico de austemperizado de la fundición dúctil, b) el comportamiento mecánico de elementos de fundición dúctil y c) el comportamiento mecánico de material compuesto de matriz epoxi y fibra de vidrio con daño higrotérmico. Se usarán simulaciones acopladas de meso y macromecánica. El principal postulado es que la representación de la mesomecánica del material acoplada a la macromecánica conduce a resultados que mejoran las predicciones con respecto a modelos planteados sólo a nivel macroscópico. El dominio macroscópico se representará con elementos finitos y en ese nivel se resolverán problemas térmicos y mecánicos. En la mesoescala se emplearán leyes fenomenológicas para el aspecto metalúrgico del austemperizado y elementos finitos para el análisis del comportamiento micromecánico de la fundición dúctil y del material compuesto. Los productos resultantes de la investigación serán software y metodologías que puedan ser utilizadas en la mejora del diseño de piezas de fundición dúctil y de materiales compuestos y en el ajuste del tratamiento de austemperizado de la fundición dúctil que permita obtener la microestructura requerida. Desde un punto de vista académico y en relación con la temática planteada en el proyecto, tres integrantes llevarán a cabo sus estudios doctorales y se publicarán resultados en revistas internacionales
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The electrical ceramic insulators industry, uses noble raw materials such as siliceous and aluminous clays of white burning, in order to provide plasticity of the mass and contribute to electrical and mechanical properties required of the product, and feldspar with the flux function In literature references the composition of the masses indicates that the clay participates in percentage between 20 and 32, and feldspar 8 to 35, these materials have significant cost. In this research was performed the total replacement of commercial clay, for white burning clay from Santa Luzia region in southern Bahia and partial replacement of feldspar by ash residue of husk conilon coffee burning, from extreme south of Bahia. The objective of replacement these raw materials is to aver its technical feasibility and call attention for the embryo pole of ceramic industry for the existing in the south and extreme south of Bahia, which has significant reserves of noble raw materials such as clay white burning, kaolin, quartz and feldspar, and generates significant volume of gray husk conilon coffee as alternate flux. Clay Santa Luzia is prima noble material whose current commercial application is the production of white roofing. The residue of coffee husk ash is discarded near of production sites and is harmful to the environment. Phase diagrams and statistic design of experiments, were used for optimization and cost savings in research. The results confirmed the expectations of obtaining electrical ceramic insulators, with white burning clay of Santa Luzia and partial replacement up to 35.4% of feldspar, by treaty residue of conilon ash coffee husk burning. The statistic design that showed best results was for formulation with percentages of: clay 26.4 to 30.4%; kaolin 14.85 to 17.1%; feldspar 12.92 to 16.96%; R2 residue 7.08 to 9.2% and Quartz 32.5 to 38.75%, relative to the total mass of the mixture. The best results indicated; 0.2 to 1.4% apparent porosity , water absorption 0.1 to 0.7%, flexural strength 35 to 45MPa , dielectric strength 35-41 kV/cm , the transverse resistivity 8x109 2.5x1010 Ω.cm and for the dielectric constant ε/ε0 7 to 10.4, specification parameters for manufacturing ceramic electrical insulators of low and medium voltage.
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O principal objetivo deste trabalho é preparar um cermeto do tipo Al2O3/Ti(C,N) com propriedades mecânicas adequadas à sua utilização na maquinação de materiais do tipo DIN ISO 513:K01-K10 e ISO H01-H10. De forma a incrementar a sinterabilidade do cermeto investigou-se o efeito da adição de dopantes metálicos, nomeadamente alumínio metálico (Al) e hidreto de titânio (TiH2) e o efeito da substituição da moagem convencional por moagem de alta energia. As variáveis das etapas principais de processamento, i.e., da moagem, prensagem e sinterização, foram selecionadas com trabalho realizado quer na Universidade de Aveiro quer na empresa Palbit. Foram preparadas três composições do cermeto Al2O3/Ti(C,N) com adições de 5%TiH2, 1%Al e 5%TiH21%Al através da moagem de alta energia. Os parâmetros de moagem, i.e. a velocidade de rotação, o rácio bolas/pó e o tempo de moagem foram otimizados para os seguintes valores: 350 rpm, 10:1 e 5 h, respetivamente. A utilização da moagem de alta energia permitiu uma redução do tamanho de partícula dos pós até aproximadamente 100 nm e a obtenção de uma boa uniformidade da distribuição das fases (Al2O3+Ti(C,N)). A etapa de conformação foi efetuada por prensagem uniaxial seguida de prensagem isostática. A avaliação da reatividade dos cermetos através de dilatometria em atmosfera de vácuo revelou que a densificação é maioritariamente realizada em estado sólido. A adição de apenas 1%Al é a menos efetiva para a densificação. Os cermetos foram sinterizados através de sinterização convencional em forno de vazio a 1650ºC e prensagem a quente (1650ºC com uma pressão uniaxial de 25 MPa). Os valores de densificação obtidos, aproximadamente 80% e 100%, respetivamente, indicam que a aplicação de pressão durante a sinterização é efetiva para atingir densificações elevadas nos compactos, compatíveis com as suas aplicações tecnológicas. As propriedades mecânicas de dureza e de tenacidade avaliadas nos três cermetos apresentaram valores aproximados de 1800-1900 HV50 para a dureza e entre 5.4 e 7.7 MPa.m1/2 para a tenacidade à fratura.
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Piauí state is a major producer of traditional red ceramic burning as bricks, tiles and ceramic tiles, with its main production center located in the city of Teresina. The state has large reserves of raw materials that can be used in the ceramic coating as clays, quartz, talc and carbonates. However, in the preparation of ceramic bodies using only a mixture of clays with different characteristics. The study aims to evaluate the effect of adding two types of carbonates in the ceramic semiporous mass coating produced in Piauí and then to verify the potential use of these carbonates as supplementary raw material product manufactured or the feasibility of obtaining a ceramic plate that meets the specifications for the porous coating. For this, were characterized the ceramic Piauí coating mass, a calcitic carbonate and a dolomitic, were made in the levels of 2, 4, 8, 16, and 32%. The masses were formed by pressing and burneds in two environments: a laboratory furnace (1080°C, 1120°C, 1140°C, and 1160°C) and an industrial furnace (1140°C). Then, following tests of linear shrinkage water absorption, apparent porosity, bulk density and flexural strength. Furthermore, the fired specimens were tested for their macrostructure and microstructure. The results showed the possibility of using the carbonate in ceramic mass flooring produced in Piauí, as added in small proportions improved dimensional stability and increased mechanical strength of ceramics pieces. It also proved itself possible to produce porous coating when added in higher levels
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Nickel alloys are frequently used in applications that require resistance at high temperatures associated with resistance to corrosion. Alloys of Ni-Si-C can be obtained by means of powder metallurgy in which powder mixtures are made of metallic nickel powders with additions of various alloying carriers for such were used in this study SiC, Si3N4 or Si metal with graphite. Carbonyl Ni powder with mean particle size of 11 mM were mixed with 3 wt% of SiC powders with an average particle size of 15, 30 and 50 μm and further samples were obtained containing 4 to 5% by mass of SiC with average particle size of 15 μm. Samples were also obtained by varying the carrier alloy, these being Si3N4 powder with graphite, with average particle size of 1.5 and 5 μm, respectively. As a metallic Si graphite with average particle size of 12.5 and 5 μm, respectively. The reference material used was nickel carbonyl sintered without adding carriers. Microstructural characterization of the alloys was made by optical microscopy and scanning electron microscopy with semi-quantitative chemical analysis. We determined the densities of the samples and measurement of microhardness. We studied the dissociation of carriers alloy after sintering at 1200 ° C for 60 minutes. Was evaluated also in the same sintering conditions, the influence of the variation of average particle size of the SiC carrier to the proportion of 3% by mass. Finally, we studied the influence of variation of the temperatures of sintering at 950, 1080 and 1200 ° C without landing and also with heights of 30, 60, 120 and 240 minutes for sintering where the temperature was 950 °C. Dilatometry curves showed that the SiC sintered Ni favors more effectively than other carriers alloy analyzed. SiC with average particle size of 15 μm active sintering the alloy more effectively than other SiC used. However, with the chemical and morphological analyzes for all leagues, it was observed that there was dissociation of SiC and Si3N4, as well as diffusion of Si in Ni matrix and carbon cluster and dispersed in the matrix, which also occurred for the alloys with Si carriers and metallic graphite. So the league that was presented better results containing Si Ni with graphite metallic alloy as carriers, since this had dispersed graphite best in the league, reaching the microstructural model proposed, which is necessary for material characteristic of solid lubricant, so how we got the best results when the density and hardness of the alloy