Optimizing the Curie temperature of pseudo-binary RxR2-x ' Fe-17 (R, R ' = rare earth) for magnetic refrigeration

Several pseudo-binary RxR2-x'Fe-17 alloys (with R = Y, Ce, Pr, Gd and Dy) were synthesized with rhombohedral Th2Zn17-type crystal structure determined from x-ray and neutron powder diffraction. The choice of compositions was done with the aim of tuning the Curie temperature (T-C) in the 270 +/- 20 K temperature range, in order to obtain the maximum magneto-caloric effect around room temperature. The investigated compounds exhibit broad isothermal magnetic entropy changes, Delta S-M(T), with moderate values of the refrigerant capacity, even though the values of Delta S-M(Peak) are relatively low compared with those of the R2Fe17 compounds with R = Pr or Nd. The reduction on the Delta S-M(Peak) is explained in terms of the diminution in the saturation magnetization value. Furthermore, the Delta S-M(T) curves exhibit a similar caret-like behavior, suggesting that the magneto-caloric effect is mainly governed by the Fe-sublattice. A single master curve for Delta S-M/Delta S-M(Peak)(T) under different values of the magnetic field change are obtained for each compound by rescaling of the temperature axis.

Seasonal dynamics in the occurrence and abundance of Pseudo-nitzschia species in the Maheshkhali channel of the Bay of Bengal, Bangladesh

Occurrence and abundance of Pseudo-nitzschia spp. at the mouth of the Maheshkhali channel of the Bay of Bengal, Bangladesh were studied. Plankton and water samples were collected monthly from the sub-surface water during high tide at daytime from June 2000 to May 2001. Four species of Pseudo-nitzschia, namely P. pungens, P. pseudodelicatissima, P. delicatissima and P. australis were identified and among them the first three were most commonly encountered and they varied seasonally. Pseudo-nitzschia delicatissima was the dominant species during the autumn and winter months, whereas P. pungens was dominant during the summer and spring months. Pseudo-nitzschia pseudodelicatissima exhibited its highest abundance level during the summer. Surface water temperature, salinity, nitrate-nitrogen (N03-N) and phosphate-phosphorus (P04-P) were recorded and their relationship with the occurrence and abundance of Pseudo-nitzschia species were studied. At the mouth of the Maheshkhali channel, Pseudo-nitzschia cell density was highest in late autumn (November) when highest salinity (35 o/oo) and P04-P (3.2 mg/l) concentrations and low temperature (23 °C) were recorded.

The synthesis of phenyl-capped trianiline and teraaniline by a modified-pseudo-high dilution technique and their UV-Vis spectral studies

Phenyl-capped trianiline and tetraaniline in the leucoemeraldine oxidation state were synthesized through a modified-pseudo-high-dilution technique. The chemical oxidation process of these compounds were studied by UV-Vis spectra. It was found that phenyl-capped trianiline in the leucoemeraldine oxidation state was oxidized to its EB form and then decomposed, Phenyl-capped tetraaniline was oxidized to its EB form and then to the pernigraniline oxidation state.

Comments On The Pseudo-Microfossil Linotolypen

Hollow, black reticulate ‘microfossils’ of unknown affinity found in Ordovician to late Cretaceous sediments from North America, Europe and Australia were given the name Linotolypa by Eisenack in 1962. In 1978, he recognised that they were pseudo-microfossils consisting of asphalt, and noted that their structure resembled that of soap bubbles formed in agitated suspensions. These objects are well known as a component of the particles caught from the air by pollen and spore traps at the present day. They are correctly termed ‘cenospheres’ and are formed from coal and possibly pitch and fuel oil by incomplete combustion. If their presence were to be confirmed in Palaeozoic sediments, this would provide important new evidence for the occurrence of fire in the geological record and of the history of levels of O2 in the atmosphere.

Validation of the detection of Pseudo-nitzschia spp. using specific RNA probes tested in a microarray format: Calibration of signal based on variability of RNA content with environmental conditions.

Harmful algal blooms (HAB) occur worldwide and cause health problems and economic damage to fisheries and tourism. Monitoring for toxic algae is therefore essential but is based primarily on light microscopy, which is time consuming and can be limited by insufficient morphological characters such that more time is needed to examine critical features with electron microscopy. Monitoring with molecular tools is done in only a few places world-wide. EU FP7 MIDTAL (Microarray Detection of Toxic Algae) used SSU and LSU rRNA genes as targets on microarrays to identify toxic species. In order to comply with current monitoring requirements to report cell numbers as the relevant threshold measurement to trigger closure of fisheries, it was necessary to calibrate our microarray to convert the hybridisation signal obtained to cell numbers. Calibration curves for two species of Pseudo-nitzschia for use with the MIDTAL microarray are presented to obtain cell numbers following hybridisation. It complements work presented by Barra et al. (2012b. Environ. Sci. Pollut. Res. doi: 10.1007/s11356-012-1330-1v) for two other Pseudo-nitzschia spp., Dittami and Edvardsen (2012a. J. Phycol. 48, 1050) for Pseudochatonella, Blanco et al. (2013. Harmful Algae 24, 80) for Heterosigma, McCoy et al. (2013. FEMS. doi: 10.1111/1574-6941.12277) for Prymnesium spp., Karlodinium veneficum, and cf. Chatonella spp. and Taylor et al. (2014. Harmful Algae, in press) for Alexandrium.