Ligações

Ilustração componente do jogo “Quimolécula (http://www.loa.sead.ufscar.br/quimolecula.html)” desenvolvido pela equipe do Laboratório de Objetos de Aprendizagem da Universidade Federal de São Carlos (LOA/UFSCar).

Ligações aéreas com a Madeira: constrangimentos e perspetivas de crescimento: o efeito do binómio tempo/distância e o mercado low cost

O transporte, neste caso o transporte aéreo para a Madeira, assume particular importância na atividade turística, para mais sendo esta uma região insular e ultraperiférica da Europa, em que a realidade socioeconómica tem como pedra basilar o Turismo que, por si só, representa 25% do PIB. Frequentemente são apontados como “culpados” pelas cíclicas crises no sector, a promoção (ou a falta dela) e as opções tomadas, a concorrência de destinos mais baratos, o peso das taxas aeroportuárias, os fenómenos climáticos, os incentivos às companhias aéreas e aos operadores, o estímulo à operação low cost, as unidades hoteleiras e as camas disponíveis, a distância (tempo de voo) deste destino em relação ao norte da Europa e ao outro lado do Atlântico, a existência ou não de ligações aéreas diretas, um sem número de “razões” em que, provavelmente, todas elas, em maior ou menor percentagem, darão o seu contributo. As infraestruturas aeroportuárias, outrora também “culpadas” por não permitirem operações de longo curso, estão hoje habilitadas para receber voos intercontinentais. A Madeira, não deixou de ser a “Pérola do Atlântico”, com um clima ameno e profilático, com as levadas e a floresta Laurissilva, com o Vinho Madeira; com a Festa do Fim do Ano, o Carnaval e a Festa da Flor, com as Paisagens únicas, o Mar e a Montanha, o Golf, o Rali da Madeira, atrativos que deveriam ser suficientes para ultrapassar os fatores “negativos” citados. Sê-lo-ão? Sem a presunção de encontrar soluções milagrosas para algo que vem sendo estudado por profissionais e consultores, pretende-se possibilitar um olhar sob uma outra perspetiva, deixando pistas para uma abordagem diversa, em que se investigam os efeitos dos voos não diretos, o peso das operações low cost e se desenha um benchmarking com o destino concorrencial das Canárias.

Não-extensividade em percolação por ligações de longo - alcance

A linear chain do not present phase transition at any finite temperature in a one dimensional system considering only first neighbors interaction. An example is the Ising ferromagnet in which his critical temperature lies at zero degree. Analogously, in percolation like disordered geometrical systems, the critical point is given by the critical probability equals to one. However, this situation can be drastically changed if we consider long-range bonds, replacing the probability distribution by a function like . In this kind of distribution the limit α → ∞ corresponds to the usual first neighbor bond case. In the other hand α = 0 corresponds to the well know "molecular field" situation. In this thesis we studied the behavior of Pc as a function of a to the bond percolation specially in d = 1. Our goal was to check a conjecture proposed by Tsallis in the context of his Generalized Statistics (a generalization to the Boltzmann-Gibbs statistics). By this conjecture, the scaling laws that depend with the size of the system N, vary in fact with the quantitie

Estudo do comportamento térmico e da luminescência de filmes de quitosana com os íons Eu3+ e Tb3+

Films of chitosan with trivalent lanthanides ions Eu3+ and Tb3+ were respectively prepared in the ratio of 3:1 m/m (chitosan: lanthanide) and 6:1 m/m (chitosan: lanthanide). There were no formations of films in a ratio of 1:1 m/m (chitosan: lanthanides). The films of chitosan with the Tb3+ ion have the same transparent appearance than the pure chitosan films. The film of chitosan with Eu3+ ion has a muddy appearance. These films present good resistance to tear. The appearance of the compounds prepared in ratio 1:1m/m is a white powder. The films and compounds of chitosan were characterized by Elementary Analysis (CHN), Thermal Analysis (TG/DTG) and Spectroscopy of Luminescence. The CHN analysis was made only for compounds prepared in ratio 1:1m/m, suggesting that these compounds possess the formula QUILn.6H2O, where QUI = Chitosan and Ln = Lanthanide. The results of the curves TG/DTG indicated that there are strong interactions between Eu3+ or Tb3+ and chitosan, causing a lesser lost of mass in the films. The luminescence analysis showed that the films of chitosan with the ions Eu3+ and Tb3+ present emissions in the region of the visible one, with bands of the chitosan and of the Eu3+ ion. The luminescence analysis of the compounds of chitosan with the Eu3+ and Tb3+ ions suggest that the chitosan does not transfer into energy to the ions lanthanides, however the chemical neighborhood around of the ion lanthanides breaks the selection rules and, conseqüently the 4f-4f transitions of the lanthanide ions are observed

Problemas de aprendizagem sobre ligações químicas para estudantes de graduação

This research aims at identifying the learning problems in newly undergraduate students at university, interpreting the nature and causes of these problems, offering subsidies to overcome these difficulties and enabling a meaningful learning through which students give meaning to their learning. As an object for this work was chosen the theme Chemical Bonds - where were studied the forces between atoms to form molecules, compound ions and ionic crystalline structures - and is characterized as one of the most important subjects of Chemistry. In research, it was used a questionnaire with five open questions, answered by 147 students from the early periods of degrees in Chemistry at Universidade Federal do f Rio Grande do Norte. The answers revealed uncertainty on the part of students, both conceptual and representation, with superficial justifications, always using the octet rule to describe models of chemical bonds. Results suggest that these students had inadequate training in high school and that the examinations for entrance into the ranks were made according to flexible criteria less demanding in terms of knowledge. These observations have led to the conclusion that for future changes, it is necessary for high schools and in the early periods in universities favoring the adoption of pedagogical approaches in context and applying strategies to overcome the teaching of superficial memorization on Chemical Bonds, which probably have applied to the teaching of other subjects of chemistry

Estudo da imobilização de proteases para a síntese de oligolisinas

Enzymatic synthesis of peptides using proteases has attracted a great deal of attention in recent years. One key challenge in peptide synthesis is to find supports for protease immobilization capable of working in aqueous medium at high performance, producing watersoluble oligopeptides. At present, few reports have been described using this strategy. Therefore, the aim of this thesis was to immobilize proteases applying different methods (Immobilization by covalent bound, entrapment onto polymeric gels of PVA and immobilization on glycidil metacrylate magnetic nanoparticles) in order to produce water-soluble oligopeptides derived from lysine. Three different proteases were used: trypsin, α-chymotrypsin and bromelain. According to immobilization strategies associated to the type of protease employed, trypsin-resin systems showed the best performance in terms of hydrolytic activity and oligopeptides synthesis. Hydrolytic activities of the free and immobilized enzymes were determined spectrophotometrically based on the absorbance change at 660 nm at 25 °C (Casein method). Calculations of oligolysine yield and average degree of polymerization (DPavg) were monitored by 1H-NMR analysis. Trypsin was covalently immobilized onto four different resins (Amberzyme, Eupergit C, Eupergit CM and Grace 192). Maximum yield of bound protein was 92 mg/g, 82 mg/g and 60 mg/g support for each resin respectively. The effectiveness of these systems (Trypsin-resins) was evaluated by hydrolysis of casein and synthesis of water-soluble oligolysine. Most systems were capable of catalyzing oligopeptide synthesis in aqueous medium, albeit at different efficiencies, namely: 40, 37 and 35% for Amberzyme, Eupergit C and Eupergit CM, respectively, in comparison with free enzyme. These systems produced oligomers in only 1 hour with DPavg higher than free enzyme. Among these systems, the Eupergit C-Trypsin system showed greater efficiency than others in terms of hydrolytic activity and thermal stability. However, this did not occur for oligolysine synthesis. Trypsin-Amberzyme proved to be more successful in oligopeptide synthesis, and exhibited excellent reusability, since it retained 90% of its initial hydrolytic and synthetic activity after 7 reuses. Trypsin hydrophobic interactions with Amberzyme support are responsible for protecting against strong enzyme conformational changes in the medium. In addition, the high concentration of oxirane groups on the surface promoted multi-covalent linking and, consequently, prevented the immobilized enzyme from leaching. The aforementioned results suggest that immobilized Trypsin on the supports evaluated can be efficiently used for oligopeptides synthesis in aqueous media

Estudos de confinamento quântico em ligações de hidrogênio

Pós-graduação em Biofísica Molecular - IBILCE

Estudo teórico e experimental das ligações diretas contra-fiadas entre paredes de blocos de concreto em escala real e reduzida 1:4

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estudo experimental de ligações entre paredes de alvenaria estrutural de blocos cerâmicos sujeitas a ações verticais

Pós-graduação em Engenharia Civil - FEIS

A Obra Lógica racional, geométrica e analítica (1744) de Manoel de Azevedo Fortes (1660-1749): um estudo das possíveis contribuições para o desenvolvimento educacional luso-brasileiro

Pós-graduação em Educação Matemática - IGCE

Ligações em estruturas metálicas com ênfase em perfís formados a frio

Pós-graduação em Engenharia Civil - FEIS

Estudo das ligações por conectores de chapas com dentes estampados em peças estruturais de madeira

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estudo das ligações entre pilares de concreto e alvenaria cerâmica de vedação

Pós-graduação em Engenharia Civil - FEIS

Abordagens bio-inspiradas aplicadas ao estudo da cognição: um encontro entre biologia, psicologia e filosofia

Pós-graduação em Filosofia - FFC

Síntese de filmes finos do sistema PMN-PT pelo método dos precursores óxidos

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)