961 resultados para Last deglaciation
A broad deglacial delta C-13 minimum event in planktonic foraminiferal records in the Okinawa Trough
Resumo:
The equatorial Pacific upwelling zone has been suspected of playing an important role in the global atmospheric CO2 changes associated with glacial-interglacial cycles. In order to assess the influencing scope of the surface water deglacial delta(13)C minimum in the tropical low-latitude Pacific, the core DGKS9603, collected from the middle Okinawa Trough, was examined for 4513 C records of planktonic foraminifera N. dutertrei and G. ruber. The planktonic foraminiferal delta(13)C records show a clear decreasing event from 20 to 6 cal. kaBP., which is characterized by long duration of about 14 ka and amplitude shift of 0.4 x 10(-3). Its minimum value occurred at 15.7 cal kaBP. The event shows fairly synchrony with the surface water deglacial delta(13)C minimum identified in the tropical Pacific and its marginal seas. Because there is no evidence in planktonic foraminiferal fauna and 45180 records for upwelling and river runoff enhancement, the broad deglacial delta(13)C minimum event in planktonic foraminiferal records revealed in core DGKS9603 might have been the direct influencing result of the deglacial surface water of the tropical Pacific. The identification for the event in the Okinawa Trough provides new evidence that the water evolution in the tropical low-latitude Pacific plays a key role in large regional, even global carbon cycle.
Resumo:
Planktonic foraminiferal faunas, oxygen isotope and modern analog technique sea surface temperature records were obtained in piston core DGKS9603 (28degrees08.869'N, 127degrees16.238'E, water depth 1100 in) collected from the middle Okinawa Trough. During the last glaciation, four cold events were identified and correlate Heinrich events (HE) H2-5 of the last 45 ka. During the last deglaciation, core DGKS9603 has begun to be influenced by the Kuroshio since about 16 cal ka BP. Three weakenings of this warm current occurred at about 2.8-5.3, 11.4 and 15.5 cal ka BP respectively. Among the three fluctuations, the oldest one is synchronous with HE1 and could be a response to the strong cooling observed in the North Atlantic Ocean. The fluctuation occurring at about 11.4 cal ka ago corresponds to the Younger Dryas within the age error bars. Our observations provide new evidence that the HEs documented from Greenland and the northern North Atlantic had a global climatic impact. Changes in the intensity of the East Asian monsoon could be the main mechanism responsible for the paleoccanographic variations observed in the Okinawa Trough. (C) 2001 Elsevier Science B.V. All rights reserved.
Resumo:
本论文通过对冲绳海槽南部的MD05-2908孔、北黄海的B-U35、B-U41、B-L44孔和北黄海的299份表层样中的孢粉组成、堆积速率、有机碳氮同位素的综合研究,分析了北黄海的孢粉来源、传播动力和途径,并与其它古气候记录对比,重建了末次冰消期以来东亚季风的演化。 MD05-2908孔孢粉组合特征显示6800-3800a BP间气候温暖干燥,其间存在着两次明显的温度降低、湿度增加阶段,即6800-6600a BP和5800-4850a BP;3800a BP以后,气候变得比较寒冷湿润,中世纪暖期和小冰期分别位于990-480a BP和480-230a BP。 北黄海表层孢粉百分含量等值线图显示北黄海不同海域孢粉来源不同,北黄 海东部海域(123.5°E以东的陆架区域)孢粉主要来源于鸭绿江;北黄海中部海域(123.5°E-122.6°E的陆架区域)孢粉来源比较复杂,既有来自辽东半岛、沿海岛屿、山东半岛,还有由黄海暖流携带而来的;北黄海西部海域(122.6°E以西的陆架区域)孢粉以黄海沿岸流携带而来的黄河来源的为主。 北黄海表层孢粉百分含量等值线图还显示,北黄海东部海域孢粉分布主要受 鸭绿江冲淡水影响,波浪和潮汐的作用较弱;北黄海中部海域孢粉分布受黄海暖流和辽东沿岸流的分支共同影响;黄海暖流与黄海沿岸流在山东半岛东北部相遇,形成一逆时针方向的涡旋,该涡旋控制着北黄海西部海域孢粉的分布。 B-U35孔、B-U41和B-L44孔孢粉组合特征显示,12830-12350a BP时气候 寒冷干燥,植被以旱生草本植物为主,时间上可能对应YD事件;12350-10100a BP时植被以针叶林为主,林下生长着大量蕨类植物,气候寒冷湿润,可能对应着YD事件;10100-6600a BP时植被以落叶阔叶林为主,伴生大量旱生草本植物,气候温暖干燥;6600-5000a BP时植被以针叶-落叶阔叶混交林为主,旱生草本植物含量下降,相对上一阶段温度有所降低,但气候更湿润,可能对应全新世最佳期;5000-4000a BP时针叶林所占比例扩大,温度再次降低,湿度变化不明显;4000-500a BP旱生草本植物含量增加,气候寒冷干燥;500a BP-至今,受人类活动影响,植被遭到严重破坏。 B-U35孔和B-U41孔淡水水生植物花粉百分含量曲线显示11750a BP以来黄河河口地区沼泽湿地面积几经变化。10100-6600a BP时沼泽湿地范围在上一阶段的基础上进一步扩大;6600-2850a BP间沼泽湿地大面积缩小,水生植物属种式微;2850a BP之后黄河河口地区沼泽湿地面积再次扩大,水生植物重新繁盛。 MD05-2908孔蕨类孢子百分含量被用来作为中国东南部季风演化的代用指标。结果显示6800-3800a BP时夏季风较强,其间有两次夏季风减弱阶段,分别位于6800-6600a BP和5800-4850a BP,3800a BP以来,夏季风明显减弱,此期的夏季风减弱除受太阳辐射量的减少影响外,可能还与El Nino的频繁爆发有关。 B-U35孔和B-U41孔蒿属、藜科、麻黄科百分含量被用来作为中国中北部夏季风演化的代用指标。研究表明,11750a BP以来东亚夏季风强度在10100-6600a BP时,显著加强,6600a BP左右,夏季风开始减弱,4000a BP以后夏季风显著减弱。 将MD05-2908孔、B-U35孔和B-U41孔夏季风代用指标进行对比发现,中晚全新世以来中国南-北湿度变化特征正好相反,东亚夏季风强度变化以及由此引起的雨锋的南进北撤可能是导致中国不同区域中晚全新世以来降雨量不同的主要原因。
Resumo:
Longgang maar area in Northern China is a sensitive region to the change of Asian summer monsoon, and also an important area to understand the dynamic mechanism of global paleoclimate and paleoenvironment changes. The grain-size and major element analyses have been carried out on the samples of the core from Erlongwan maar for reconstruction of high –resolution paleoenvironment change in Northeast China. Subsampling was done by 1cm interval for the upper 19.39m. Connecting multi-proxies (including,dry density, total organic carbon, etc.), we have acquired the following conclusions: 1、 the coarse fraction in grain size reflects the intensity of surface flow, and thus the intensity of monsoon rainfall in the region. 2、 the 19.39-m-long sediment covering the past 33ka, can be divided into 3 periods: The last glacial stage (33-18.5ka B.P.):summer monsoon rainfall was low, temperature was minimum and climatic deteriorated. The last deglaciation (18.5-10 ka B.P.): temperature rose and surface water inflow increased. But it experienced a period, a Younger Dryas-like climatic deterioration. Holocene(10-0 ka B.P.):summer monsoon rainfall reached maxima and varied at century scale and major millennial scale. 3、 the climatic variability in the whole Holocene is positively correlated with Atlantic ice-rafting events and there is an influence of sunspot activity in the late Holocene
Resumo:
Stable isotope compositions of land snail shells have a great potential as an indicator of paleoclimatic and paleoenvironmental changes. However, some key issues, such as the relationship of carbon isotope between snail food and local vegetation, and the uncertainty of the dominant factors about snail body fluid changes in oxygen isotope composition, remain less well known, strongly limiting shell isotopic application. In this study, we measure the stable isotope compositions on the shells of both live snails and fossils collected from the Chinese Loess Plateau and a loess sequence at Mangshan, Xingyang, respectively. Based on the analyses, the association of the stable isotope compositions of land snail shells with their growing seasons is investigated. In addition, the climatic and environmental significances of isotopic differences among several snail species are discussed. The main results and conclusions are presented as follows: 1. δ18O values for the shell lip samples of Bradybaena ravida redfieldi range from -6.79‰ to -1.92‰, and parallels to the monthly changes of local rain water δ18O, temperature and humidity. The compatibility of shell lip δ18O with monthly modeled shell δ18O indicates that the shell lip δ18O changes are mainly resulted from the 18O variations of rain-water. The shells of a land snail growing in spring could be enriched in 18O, and those growing in summer depleted in 18O. 2. Carbon isotope compositions of snail shells are controlled by their diet, which is affected by the relative proportion of C3 to C4. There are some differences in carbon isotopic compositions among different snail species, especially between P. orphana and V. tenera or P. aeoli. Shell δ13C for P. orphana is the most positive with an average of -5.88 ± 2.54 ‰. The C4 plant fraction of the food for “cold-aridiphilous” taxa, P. aeoli and V. tenera, is distinctly lower than that for “thermo-humidiphilous” taxa, P. orphana, indicating that summer is likely to be the main active season of P. orphana and spring of P. aeoli and V. tenera. Therefore, some discrepancy of carbon isotopic compositions among different species may be related to snail active season. 3. δ13C values among different species have a certain degree of positive correlation, which may be influenced by local vegetation ecosystem. δ13C value of the snail shells (especially P. orphana) shows an eastward increasing trend and consists with the variations of C4 plants biomass in Loess Plateau. The result shows that the carbon isotope in local vegetation ecosystem is one of the main factors influencing δ13C values of snail food. Therefore, both carbon isotopes of local vegetation ecosystem and snail active season contribute to the carbon isotopic differences among different snail species and in different areas. 4. δ13C values of living snail shells and soil organic matter have a positive correlation with each other, which further supports the view that carbon isotope in local vegetation ecosystem is one of the main factors influencing δ13C values of snail food. However, the range of δ13C values of snail food for various species in response to carbon isotope in local vegetation ecosystem is different. It is suggested that 13C enrichment of snail shells relative to local vegetation ecosystem has a potential to indicate snail active season and the degree of climate temperature and humidity. 5. There is a significant negative correlation between carbon and oxygen isotopic compositions of living snail shells in Loess Plateau. This result further supports that snail active season can be inferred based on the shell carbon and oxygen isotopic compositions. Moreover, there are some positive correlations between mean annual temperature and differences of shell δ13C values ( 13CV. tenera-P. orphana) and that of δ18O values ( 18OV. tenera-P. orphana) for P. orphana, a typical “thermo-humidiphilous” taxa, and V. tenera, a typical “cold-aridiphilous” taxa, respectively. It shows that 13CV. tenera-P. orphana and 18OV. tenera-P. orphana may have a potential to indicate mean annual temperature or the length of biological growing season. 6. Stable isotopes of land snail shell in the Mangshan loess sequence show that the shell δ18O value of “cold-aridiphilous” taxa V. tenera is more positive than “thermo-humidiphilous” taxa P. orphana and δ13C value of the former is more negative than the latter. In addition, the shell δ18O value of V. tenera varies significantly in different period. During the last glacial maximum, its δ18O value with an average of -7.89 ‰ is more negative than that (-5.88 ‰) from the last deglaciation to the early Holocene. This phenomenon indicates that its growing season during different period is significantly different. It tends to grow in summer in last glacial maximum. With climate warming, it prefers growing in spring with relatively low temperature. While the shell δ18O value of P. orphana varies in a little range, which shows that its activity season is shorter and mainly in summer. These results further support that the change of the snail growing season is one of the main factors of differences of carbon isotopic compositions among different snail species and varies with time. Furthermore, it is consistent that changes in magnetic susceptibility and trend of differences of shell δ18O values and δ13C values respectively between the two snail fossils. It is further testified that 13CV. tenera-P. orphana and 18OV. tenera-P. orphana may have a potential to indicate mean annual temperature or the length of biological growing season.
Resumo:
In this study, 172 mollusk assemblages from the Weinan loess section in the southeast of Loess Plateau, China, were identified quantitatively at relative high resolution. The results show: 1) the history and processes of paleoclimatic and paleoenvironmental changes in Weinan since the last 70 ka; 2) the characteristics of climatic changes during the period of the last glacial maximum (LGM); 3) the spatial pattern of paleoclimate variations at the south and middle parts of the Loess Plateau during the LGM period; 4) the timing of the last deglaciation and the return event of rapid climate change during the last deglaciation. The main conclusions are as follows: 1) 172 mollusk samples taken from the uppermost 9 m deposits cover the past 70 ka, which were sampled at the internals of 5 cm for S_0, 3 cm for L_(1-1) and L_(1-2), and 10 cm for L_(1-3), L_(1-4) and L_(1-5). Author analyzed quantitatively all individuals including broken pieces of snail shells, percentages of 15 species identified from 172 samples. Three main groups were determined according to the ecological requirement of each taxon. Based on the variations of three ecological groups and typical ecological species, The author intended to reconstruct the history of and processes of climate and environment since the last 70 ka in the Weinan region. The climate and environment in this region experienced the following changes: relative warm and humid stage from 67.5-20.3 cal. ka B.P., a period of forest-steppe or steppe developed; cold and arid stage from 20.3-15.5 cal. ka B.P., a dry steppe period, later wetter and colder; cold and humid period once time from 15.5 to 12.3 cal. ka B.P., a typical steppe or forest-steppe stage; cold and humid again from 12.3 cal. ka B.P. to 8.2 cal. ka B.P., a tropical steppe stage; warm and humid climate, a forest-steppe developed. 2) The climate during the period of the last glacial maximum (LGM) in Weinan was characterized by a general cold-humid condition, represented by occurrence of a number of the cool-humidiphilous mollusk species such as Gastocopta amigerella and Vallonia cf. pulchella in the section. 3) Comparison of the variations in abundance of Puncture orphana at Weinan with those at Luochuan and Changwu sections suggests that the summer monsoon intensity influenced differently at the three regions during the LGM period. The Weinan was weaker summer monsoon impact during all the period, the Luochuan was influenced occasionally, and Changwu was only a very short time affected, which indicated it might be located at the western margin of the summer monsoon influence during that period. 4) The ratio of thermo-humidiphilous mollusk group to cold-aridiphilous one shows an increase tendency at about 15 cal. ka B.P., reflecting the climate warming after the deglaciation in Weinan, which is approximately corresponding to the timing of warming period of the last deglaciation, found in the East Atlantic Ocean, the South China Sea and the Loess Plateau (indicated by the phytolith study). 5) A remarkable decrease in the number of thermo-humidiphilous and cool-humidiphilous mollusk species from 12.7 - 11.6 cal. ka B.P. indicates a cooling in climate and might be the reflection of the Younger Dryas event in Weinan. 6) Variations in the ratios of thermo-humidiphilous mollusk species to cold-aridiphilous ones reflect the climate instability in Holocene. There were four warm-humid periods (10-8.1 cal. ka B.P., 6.9-6.1 cal. ka B.P., 5.2-2.6cal. ka B.P., 1.6cal. ka B.P. to the present ) and three relative cold-arid periods (8.1-6.9 cal. ka B.P., 6.1-5.2 cal. ka B.P., 2.6-1.6 cal. ka B.P.), showing about a 1,000 year climatic oscillation.
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Climate change during the last deglaciation was strongly influenced by the „bipolar seesaw‟, producing antiphase climate responses between the North and South Atlantic. However, mounting evidence demands refinements of this model, with the occurrence of abrupt events in southern low to mid latitudes occurring in-phase with North Atlantic climate. Improved constraints on the north-south phasing and spatial extent of these events are therefore critical to
understanding the mechanisms that propagate abrupt events within the climate system. We present a 19,400 year multi-proxy record of climate change obtained from a rock hyrax midden in southernmost Africa. Arid anomalies in phase with the Younger Dryas and 8.2 ka events are apparent, indicating a clear shift in the influence of the bipolar seesaw, which diminished as the Earth warmed, and was succeeded after ~14.6 ka by the emergence of a dominant interhemispheric atmospheric teleconnection.
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Studies of marine sediments, cave speleothemes, annually laminated corals, and tree rings from Asian monsoon regions have added knowledge to our understanding of the factors that control inter-annual to millennial monsoon variability in the past and have provided important constraints for climate modeling scenarios. In contrast, the spatial and temporal pattern of sub-millennial scale monsoon variability and its impact on land cover in SE Asia are still unresolved. This shortcoming stems from the fact that temporally well-resolved paleo-environmental studies are missing from large parts of SE Asia, especially from Thailand. Given that global and regional climate models are increasingly using terrestrial paleo- data to test their performance, past changes in land cover are therefore important variables to better understand feedbacks between different Earth systems. We obtained sediments from Lake Nong Thale Pron, in southern Thailand (8º 10`N, 99 º23`E; 380 m.asl). The aim of our study is to reconstruct lake status changes and to evaluate whether the extent of these changes are linked to known shifts in monsoon intensity and variability. Preliminary results show that lake infilling started more than 15,000 years ago and that the sediments cover the last deglaciation and the Holocene. Current analyses include Itrax XRF core scanning, loss-on-ignition (LOI at 950 and 550ºC), CN elemental and isotopic composition. We expect that our results will be able to give a picture of how the lake's status has changed over time and whether the extent of these changes is linked to known shifts in monsoon intensity and variability.
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We report evidence for a major ice stream that operated over the northwestern Canadian Shield in the Keewatin Sector of the Laurentide Ice Sheet during the last deglaciation 9000-8200 (uncalibrated) yr BP. It is reconstructed at 450 km in length, 140 km in width, and had an estimated catchment area of 190000 km. Mapping from satellite imagery reveals a suite of bedforms ('flow-set') characterized by a highly convergent onset zone, abrupt lateral margins, and where flow was presumed to have been fastest, a remarkably coherent pattern of mega-scale glacial lineations with lengths approaching 13 km and elongation ratios in excess of 40:1. Spatial variations in bedform elongation within the flow-set match the expected velocity field of a terrestrial ice stream. The flow pattern does not appear to be steered by topography and its location on the hard bedrock of the Canadian Shield is surprising. A soft sedimentary basin may have influenced ice-stream activity by lubricating the bed over the downstream crystalline bedrock, but it is unlikely that it operated over a pervasively deforming till layer. The location of the ice stream challenges the view that they only arise in deep bedrock troughs or over thick deposits of 'soft' fine-grained sediments. We speculate that fast ice flow may have been triggered when a steep ice sheet surface gradient with high driving stresses contacted a proglacial lake. An increase in velocity through calving could have propagated fast ice flow upstream (in the vicinity of the Keewatin Ice Divide) through a series of thermomechanical feedback mechanisms. It exerted a considerable impact on the Laurentide Ice Sheet, forcing the demise of one of the last major ice centres.
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Stable isotope analysis of leaf waxes in a sediment core from Laguna La Gaiba, a shallow lake located at the Bolivian margin of the Pantanal wetlands, provides new perspective on vegetation and climate change in the lowland interior tropics of South America over the past 40,000 years. The carbon isotopic compositions (δ13C) of long-chain n-alkanes reveal large shifts between C3-and C4-dominated vegetation communities since the last glacial period, consistent with landscape reconstructions generated with pollen data from the same sediment core. Leaf wax δ13C values during the last glacial period reflect an open landscape composed of C4grasses and C3herbs from 41–20ka. A peak in C4abundance during the Last Glacial Maximum (LGM, ∼21ka) suggests drier or more seasonal conditions relative to the earlier glacial period, while the development of a C3-dominated forest community after 20 ka points to increased humidity during the last deglaciation. Within the Holocene, large changes in the abundance of C4 vegetation indicate a transition from drier or more seasonal conditions during the early/mid-Holocene to wetter conditions in the late Holocene coincident with increasing austral summer insolation. Strong negative correlations between leaf wax δ13C and δD values over the entire record indicate that the majority of variability in leaf wax δD at this site can be explained by variability in the magnitude of biosynthetic fractionation by different vegetation types rather than changes in meteoric water δD signatures. However, positive δD deviations from the observed δ13C–δD trends are consistent with more enriched source water and drier or more seasonal conditions during the early/mid-Holocene and LGM. Overall, our record adds to evidence of varying influence of glacial boundary conditions and orbital forcing on South American Summer Monsoon precipitation in different regions of the South American tropics. Moreover, the relationships between leaf wax stable isotopes and pollen data observed at this site underscore the complementary nature of pollen and leaf wax δ13C data for reconstructing past vegetation changes and the potentially large effects of such changes on leaf wax δD signatures.
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A new deep ice core drilling program, TALDICE, has been successfully handled by a European team at Talos Dome, in the Ross Sea sector of East Antarctica, down to 1620 m depth. Using stratigraphic markers and a new inverse method, we produce the first official chronology of the ice core, called TALDICE-1. We show that it notably improves an a priori chronology resulting from a one-dimensional ice flow model. It is in agreement with a posteriori controls of the resulting accumulation rate and thinning function along the core. An absolute uncertainty of only 300 yr is obtained over the course of the last deglaciation. This uncertainty remains lower than 600 yr over Marine Isotope Stage 3, back to 50 kyr BP. The phasing of the TALDICE ice core climate record with respect to the central East Antarctic plateau and Greenland records can thus be determined with a precision allowing for a discussion of the mechanisms at work at sub-millennial time scales.
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Gas is trapped in polar ice sheets at ~50–120 m below the surface and is therefore younger than the surrounding ice. Firn densification models are used to evaluate this ice age-gas age difference (Δage) in the past. However, such models need to be validated by data, in particular for periods colder than present day on the East Antarctic plateau. Here we bring new constraints to test a firn densification model applied to the EPICA Dome C (EDC) site for the last 50 kyr, by linking the EDC ice core to the EPICA Dronning Maud Land (EDML) ice core, both in the ice phase (using volcanic horizons) and in the gas phase (using rapid methane variations). We also use the structured 10Be peak, occurring 41 kyr before present (BP) and due to the low geomagnetic field associated with the Laschamp event, to experimentally estimate the Δage during this event. Our results seem to reveal an overestimate of the Δage by the firn densification model during the last glacial period at EDC. Tests with different accumulation rates and temperature scenarios do not entirely resolve this discrepancy. Although the exact reasons for the Δage overestimate at the two EPICA sites remain unknown at this stage, we conclude that current densification model simulations have deficits under glacial climatic conditions. Whatever the cause of the Δage overestimate, our finding suggests that the phase relationship between CO2 and EDC temperature previously inferred for the start of the last deglaciation (lag of CO2 by 800±600 yr) seems to be overestimated.
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Here we present a detailed multi-proxy record of the climate and environmental evolution at Lake El'gygytgyn, Far East Russian Arctic during the period 430–395 ka covering the marine isotope stage (MIS) 12/11 transition and the thermal maximum of super interglacial MIS 11c. The MIS 12/11 transition at Lake El'gygytgyn is characterized by initial warming followed by a cold reversal implying similarities to the last deglaciation. The thermal maximum of MIS 11c is characterized by full and remarkably stable interglacial conditions with mean temperatures of the warmest month (MTWM) ranging between ca. 10–15 °C; annual precipitation (PANN) ranging between ca. 300–600 mm; strong in-lake productivity coinciding with dark coniferous forests in the catchment; annual disintegration of the lake ice cover; and full mixis of the water column. Such conditions persisted, according to our age model, for ca. 27 ± 8 kyr between ca. 425–398 ka. The Lake El'gygytgyn record closely resembles the climate pattern recorded in Lake Baikal (SE Siberia) sediments and Antarctic ice cores, implying interhemispheric climate connectivity during MIS 11c.
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Correct estimation of the firn lock-in depth is essential for correctly linking gas and ice chronologies in ice core studies. Here, two approaches to constrain the firn depth evolution in Antarctica are presented over the last deglaciation: outputs of a firn densification model, and measurements of δ15N of N2 in air trapped in ice core, assuming that δ15N is only affected by gravitational fractionation in the firn column. Since the firn densification process is largely governed by surface temperature and accumulation rate, we have investigated four ice cores drilled in coastal (Berkner Island, BI, and James Ross Island, JRI) and semi-coastal (TALDICE and EPICA Dronning Maud Land, EDML) Antarctic regions. Combined with available ice core air-δ15N measurements from the EPICA Dome C (EDC) site, the studied regions encompass a large range of surface accumulation rates and temperature conditions. Our δ15N profiles reveal a heterogeneous response of the firn structure to glacial–interglacial climatic changes. While firn densification simulations correctly predict TALDICE δ15N variations, they systematically fail to capture the large millennial-scale δ15N variations measured at BI and the δ15N glacial levels measured at JRI and EDML – a mismatch previously reported for central East Antarctic ice cores. New constraints of the EDML gas–ice depth offset during the Laschamp event (~41 ka) and the last deglaciation do not favour the hypothesis of a large convective zone within the firn as the explanation of the glacial firn model–δ15N data mismatch for this site. While we could not conduct an in-depth study of the influence of impurities in snow for firnification from the existing datasets, our detailed comparison between the δ15N profiles and firn model simulations under different temperature and accumulation rate scenarios suggests that the role of accumulation rate may have been underestimated in the current description of firnification models.