Assessing the environmental fate of selected polybrominated diphenyl ethers in the region surrounding the Zhuoshui River of Taiwan based on an Equilibrium Constant fugacity model

Polybrominated diphenyl ethers (PBDEs) are a group of flame retardants that have been in use since the 1970s. They are included in the list of hazardous substances known as persistent organic pollutants (POPs) because they are extremely hazardous to the environment and human health. PBDEs have been extensively used in industry and manufacturing in Taiwan, thus its citizens are at high risk of exposure to these chemicals.
An assessment of the environmental fate of these compounds in the Zhuoshui river and Changhua County regions of western Taiwan, and also including the adjacent area of the Taiwan Strait, was conducted for three high risk congeners, BDE-47, -99 and -209, to obtain information regarding the partitioning, advection, transfer and long range transport potential of the PBDEs in order to identify the level of risk posed by the pollutants in this region.
The results indicate that large amounts of PBDEs presently reside in all model compartments – air, soil, water, and sediment – with particularly high levels found in air and especially in sediment. The high levels found in sediment, particularly for BDE-209, are significant, since there is the threat of these pollutants entering the food chain, either directly through benthic feeding, or through resuspension and subsequent feeding in the pelagic region of the water column which is a distinct possibility in the strong currents found within the Taiwan Strait. Another important result is that a substantial portion of emissions leave the model domain directly through advection, particularly for BDE-47 (58%) and BDE-209 (75%), thus posing a risk to adjacent communities.
Model results were generally in reasonable agreement with available measured concentrations. In air, model concentrations are in reasonably good agreement with available measured values. For both BDE-47 and -99, model concentrations are a factor of 2-3 higher and BDE-209 within the range of measured values. In soil, model results are somewhat less than measured values. In sediment, model results are at the high end of measured values.

Integração Energética da Unidade de Pré-destilação U-0100 da Fábrica de Aromáticos

A presente dissertação foi realizada no âmbito do Mestrado em Engenharia Química no ramo de Otimização Energética na Indústria Química, do Instituto Superior de Engenharia do Porto. O estudo energético foi desenvolvido na empresa Petrogal, S.A, na Refinaria de Matosinhos, avaliando a possível racionalização energética do processo existente na Fábrica de Aromáticos. Os objetivos propostos basearam-se na realização de uma integração energética à unidade de pré-destilação, denominada por U-0100, que se encontra instalada na Fábrica de Aromáticos. Pretende-se, de uma forma geral, o reaproveitamento máximo da energia do processo, diminuindo o recurso a utilidades externas. Para tal recorreu-se à metodologia da análise do ponto de estrangulamento, designada por tecnologia Pinch. Numa primeira fase da otimização foi necessário conhecer todo o processo em causa e os conceitos associados à tecnologia aplicada. Após contactar com o processo procedeu-se ao levantamento energético do mesmo, referente ao ano 2013. Nesta etapa foram recolhidos todos os dados considerados relevantes para a quantificação energética das correntes e das utilidades empregues. Depois da recolha efetuou-se a integração energética estabelecendo um ∆Tmin ótimo para o processo de 5°C, após uma prévia análise da influência deste parâmetro sobre os consumos. Constatou-se que atualmente o processo de separação opera com uma taxa de recuperação energética de 16,8% da energia total, sendo a restante energia introduzida por utilidades externas. Com a análise do ponto de estrangulamento concluiu-se que a unidade de pré - destilação U-0100 se encontra integrada energeticamente, não sendo essencial proceder a qualquer modificação à mesma. No entanto sugere-se como trabalho futuro um estudo técnico e económico da implementação de um pré-aquecedor de ar, necessário ao processo de combustão que se dá na fornalha H-0101. Isto tendo em vista o reaproveitamento máximo da corrente, gases de combustão, que é desperdiçada para o meio ambiente.

Communication and Economic Growth.

Overs the past millennium, each of the three centuries of most rapid demographic growth in the West Coincided with the diffusion of a new communications technology. This paper examines the hypothesis of Harold Innis (1894-1952) that there is two-way feeback between such innovations and economic growth.

Economic integration in North America: Formal, Informal and Spatial Aspects.

An exemination of a series of indicators of economic integration in the western hemisphere (Canada-USA-Latin America) indicates that it is proceeding under the influence of formal trade agreements and informal forces including technological change, multinational firm rationalization and location strategies, etc.

La mondialisation de l'economie et le role de l'Etat.

Cet article examine la nature, les cause et les effets de la globalisation, phenomene tres anciens et tres influence par le changement technologique.

Industrial Relations and "Humanware"

This is a preliminary paper. Please do not quote without the permission of the author. The research on which this paper is based has been conducted with the collaboration of John Paul MacDuffie, MIT. The researchers owe much to the warm cooperation of managers, employees, and union officials of Japanese auto companies and joint venture companies in the U.S. as well as American auto companies and the UAW. We would like to express our sincere appreciation for their assistance.

Death of the high street: identification, prevention, reinvention

Location is of paramount importance within the retail sector, yet defining locational obsolescence remains overlooked, despite significant concerns over the viability of parts of the complex sector. This paper reviews the existing literature and, through this, explores retail locational obsolescence, including the multi-spatial nature of the driving forces that range from the global economy, local markets and submarkets, to individual property-specific factors; and, crucially, the need to disentangle locational obsolescence from other important concepts such as depreciation and functional obsolescence that are often mistakenly used. Through this, a conceptual model, definition and diagnostic criteria are presented to guide future studies, policy development and the allocation of resources. Importantly, three stages are presented to enable the operationalization of the model, essential to future academic and industry studies as well as the ongoing development of policy in this economically important, complex and contentious area.

Acumulação de competências tecnológicas e suas implicações para performance operacional: análise comparativa de duas empresas do grupo Lupatec em Caxias do Sul - RS

This work focuses on the implications of accumulation of technological competences for improvement of operational performance indicators. This relationship is examined in two mechanical industry firms in Caxias do Sul-RS, in the period 1985-2000. Based on a comparative case study, this work finds its ground in both qualitative and quantitative empirical evidences, collected in different sources in the firms, which are being studied. The examination of accumulation of technological competences is done through a structure of analysis existing in literature, which is specifically adapted to the mechanical industry. The examination of performance improvement is based on a set of typical operational indicators pertaining to mechanical industry. Studies of this nature are already found, mainly in Latin American literature, since the eighties. But, the application of these analytic structures in industrializing firms in Brazil is found only in the nineties. This work shows that within a unique enterprise group there is a different accumulation of technological competences, and it demonstrates that this process is not automatic. Moreover, it contributes to explain not only the differences between both firms, in terms of operational performance at some points in time, but also, how both firms got to (or did not get to) improve their performance indicators along time. This conclusion is not different from that of previous studies, but it derives from a study made in a specific industry (mechanical), which has not yet been studied in the south of Brazil.

Acumulação de Competências Tecnológicas e suas Implicações para a Performance Corporativa: Um Estudo Comparativo entre Duas Empresas da Indústria Moveleira em Bento Gonçalves - RS

This dissertation focus the implication of differences in accumulation of technological competences among companies and its reflex on the improvement of indexes of operational, economical and financial performance. This connection has been investigated at D'Itália Móveis Industrial Ltda. and Pozza S.A Industrial Moveleira, both companies of the furniture market located in Bento Gonçalves - RS. Based on a comparative case study of these two companies, this dissertation is based on empiric evidences about how the company has accumulated its technological competences. Such evidences are qualitative and quantitative, and were collected from several sources in the studied companies. The examination of technological competences accumulation is done based on an analytical structure that exists in the literature, that has been adapted to the analysis of the furniture market. The examination of performance improvement is based on a set of indexes used in the furniture industry. Studies about this subject are found in the literature, but the application of these analytic structures in the furniture market is scarce, mainly in brazilian companies. It has been noticed that the company D'Itália has accumulated technological competences on all the three functions analysed, what suggests implications for the improvement of its performance. On the other side, the company Pozza has shown a paralysation on technological competences accumulation during a long time, what brought implications for the reduction of its corporative performance. In this way, the conclusion of this dissertation suggests that the accumulation of technological competences has contributed to explain the differences of performance between both companies. Besides, it explains how both companies have managed (or not) to accumulate their indexes of performance in the long run. Even though this conclusion is not different from other studies formerly done, this conclusion is derivated from a study applied to a kind of industry that still wasn¿t examined in the available literature.

Demand and supply: price elasticities and corporate performance in the UK

This paper investigates the relationship between consumer demand and corporate performance in several consumer industries in the UK, using two independent datasets. It uses data on consumer expenditures and the retail price index to estimate Almost Ideal Demand Systems on micro-data and compute timevarying price elasticities of demand for disaggregated commodity groups. Then, it matches the product definitions to the Standard Industry Classification and uses the estimated elasticities to investigate the impact of consumer behaviour on firm-level profitability equations. The time-varying household characteristics are ideal instruments for the demand effects in the firms' supply equation. The paper concludes that demand elasticities have a significant and tangible impact on the profitability of UK firms and that this impact can shed some light on the relationship between market structure and economic performance.

Feira livre e circuitos da economia urbana: um estudo da feira da Pedra, em São Bento (PB)

The Feira da Pedra is an extension of the open fair of São Bento in the State of Paraiba. It is a system of trade in textile goods produced by textile industry in manufacturing of hammocks and derivatives of this industry, present in some cities in the state of Paraiba and Rio Grande do Norte, as a survival strategy, inserted in the list of tertiary and retail of the urban economics of this city. It is thereby aimed to discuss about the urban economics, reflecting on the open fair system from the two circuits of urban economy, mainly in the context of the dynamics of the current period of geographic space, the technical-scientific-informational period, as the specific empirical object, the Feira da Pedra of São Bento (PB). For this, this research was carried out in two stages of operation: a) surveys of secondary data and b) primary data collection which were reported an operational triad: I) literature; II) documentary research, and III) research of field. The presence of the Feira da Pedra in São Bento has shown us one of the most important characteristics of this city, in order to present major economic, social and cultural benefits to the local population, and contribute to (re) production of sertanejo space, making lower part of the circuit of its urban economy. This activity has entailed several dynamics for urban space in this city, mainly because of attracting large numbers of people, carrying typical actions of its relationship with the urban space are são-bentense and built environment. Thus, its importance is not only a local and regional phenomenon, but also a cultural reference of a place in the geographical area of many paraibanos and norte-rio-grandenses subjects, as the case of this activity has brought to its weekly routine, this product resulting from the textile working of this area of Sertão Paraibano and Seridó Potiguar

Textile Dye Treated Photoelectrolytically and Monitored by Winogradsky Columns

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Especiarias como antioxidantes naturais: aplicações em alimentos e implicação na saúde

Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)