984 resultados para Jennings, Al, b. 1863.


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vol. 7, pt. 1 has special t.p. only: Sharḥ majāni al-adab.

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The effects of boron and strontium interactions on the eutectic silicon in hypoeutectic Al-Si alloys have been studied. Samples were prepared from an AI-I 0 mass%Si base alloy with different Al-B additions, alone and in combination with strontium. In alloys containing no strontium, boron additions do not cause modification of the eutectic silicon, while in strontium containing alloys, boron additions reduce the level of modification of the eutectic silicon. Thermal analysis parameters and eutectic silicon microstructures were investigated with respect to the Sr to B ratio. In order to modify the eutectic silicon, a Sr/B ratio exceeding 0.4 is required.

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In the distributed storage setting introduced by Dimakis et al., B units of data are stored across n nodes in the network in such a way that the data can be recovered by connecting to any k nodes. Additionally one can repair a failed node by connecting to any d nodes while downloading at most beta units of data from each node. In this paper, we introduce a flexible framework in which the data can be recovered by connecting to any number of nodes as long as the total amount of data downloaded is at least B. Similarly, regeneration of a failed node is possible if the new node connects to the network using links whose individual capacity is bounded above by beta(max) and whose sum capacity equals or exceeds a predetermined parameter gamma. In this flexible setting, we obtain the cut-set lower bound on the repair bandwidth along with a constructive proof for the existence of codes meeting this bound for all values of the parameters. An explicit code construction is provided which is optimal in certain parameter regimes.

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Part I of this thesis deals with 3 topics concerning the luminescence from bound multi-exciton complexes in Si. Part II presents a model for the decay of electron-hole droplets in pure and doped Ge.

Part I.

We present high resolution photoluminescence data for Si doped With Al, Ga, and In. We observe emission lines due to recombination of electron-hole pairs in bound excitons and satellite lines which have been interpreted in terms of complexes of several excitons bound to an impurity. The bound exciton luminescence in Si:Ga and Si:Al consists of three emission lines due to transitions from the ground state and two low lying excited states. In Si:Ga, we observe a second triplet of emission lines which precisely mirror the triplet due to the bound exciton. This second triplet is interpreted as due to decay of a two exciton complex into the bound exciton. The observation of the second complete triplet in Si:Ga conclusively demonstrates that more than one exciton will bind to an impurity. Similar results are found for Si:Al. The energy of the lines show that the second exciton is less tightly bound than the first in Si:Ga. Other lines are observed at lower energies. The assumption of ground state to ground-state transitions for the lower energy lines is shown to produce a complicated dependence of binding energy of the last exciton on the number of excitons in a complex. No line attributable to the decay of a two exciton complex is observed in Si:In.

We present measurements of the bound exciton lifetimes for the four common acceptors in Si and for the first two bound multi-exciton complexes in Si:Ga and Si:Al. These results are shown to be in agreement with a calculation by Osbourn and Smith of Auger transition rates for acceptor bound excitons in Si. Kinetics determine the relative populations of complexes of various sizes and work functions, at temperatures which do not allow them to thermalize with respect to one another. It is shown that kinetic limitations may make it impossible to form two-exciton complexes in Si:In from a gas of free excitons.

We present direct thermodynamic measurements of the work functions of bound multi-exciton complexes in Al, B, P and Li doped Si. We find that in general the work functions are smaller than previously believed. These data remove one obstacle to the bound multi-exciton complex picture which has been the need to explain the very large apparent work functions for the larger complexes obtained by assuming that some of the observed lines are ground-state to ground-state transitions. None of the measured work functions exceed that of the electron-hole liquid.

Part II.

A new model for the decay of electron-hole-droplets in Ge is presented. The model is based on the existence of a cloud of droplets within the crystal and incorporates exciton flow among the drops in the cloud and the diffusion of excitons away from the cloud. It is able to fit the experimental luminescence decays for pure Ge at different temperatures and pump powers while retaining physically reasonable parameters for the drops. It predicts the shrinkage of the cloud at higher temperatures which has been verified by spatially and temporally resolved infrared absorption experiments. The model also accounts for the nearly exponential decay of electron-hole-droplets in lightly doped Ge at higher temperatures.

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The Yellowfin tuna was caught more than all other species in the southern waters of Iran (24000 tons in 1998). In order to come up with the responsible fishing pattern, there was a need to identify some of the biological characteristics and population dynamic parameters. This thesis was the first which covered the whole Yellowfin tuna distribution in the Oman Sea, included the fishing grounds of Berris, Ramin, Chabahar, Pozm and Jask. The data during 1998-99 from different fishing grounds were polled. Based on the exponential relationship between length and weight in the size range 38-173 Cm, the relationship (W=aL^ b) was calculated as W=0.000012L ^ 3.0831). The mean fork length,head length,girth and weight were calculated respectively 84.15 Cm, 23 Cm, 53 Cm, and 11828 g. Length infinity was estimated 189 Cm with growth parameters of 0.42 per year. Growth performance index was 4.18 which was in agreement with the findngs of the other studies in the Indian and Pacific Oceans. The mortality parameters and exploitation rate were estimated as below: Z = 1.75-1.85 M=0.6 F=1.25 E=0.68 Occurence of empty stomach was high (60%) in the speciemens obtained from the Oman Sea. Purpleback flying squid (Sthenoteuthis oualaniensis) was the most dominant prey species observed in the study (57% in females and 60% in males), occurrence of teleost fishes were found to be the second (38% in males and 42% in females). Crabs also were identified in the specimens(1-2%). The study on sex ratio indicated that males were predominant at all sizes above 120 Cm fork length. 50.82% of specimens were males and 49.18% females. The monthly gonadosomatic index was deriven higher values during January to June which could be indicated as spawning period.

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在运用一元数学公式:W=al~b(或W=aL~b)来描述鱼类的重量与身体维数关系时存在许多缺陷。作者从确立一条模式鱼的边界曲线方程出发,应用求旋转体体积的方法建立了鱼类重量与长度、体高的多元数学公式: W=al~(b_1)H~(b_2)(或W=aL~(b_1)H~(b_2)),并推演出鱼类重量与长度、体高、体周长之间的另外两种关系式: W=al~(b_1)S~(b_3)(或W=aL~(b_1)S~(b_3)) 和W=al~(b_1)H~(b_2)S~(b_3)(或W=aL~(b_1)H~(b_2)S~(b

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Three different inorganic-organic hetero-junctions (A : ITO/SiO2/Alq(3)/Al, B: ITO/Alq3/SiO2/Al and C: ITO/SiO2/Alq(3)/ SiO2/Al) were fabricated. The emission can be observed only under positive bias in devices A and B, but under both biases in device C according to their brightness waveforms. With increasing voltage, the increase in blue emission in devices B and C is faster than that in green emission. This is because that the recombination of hot electrons and holes, i.e., electron-hole pairs, produced blue emission in devices B and C, and the recombination of electrons injected from Al with the accumulated holes, which are excited by hot electrons, produced green emission in device A. Hence, the emissions of the devices are attributed to not only the recombination of electrons and accumulated holes, but also the cathodoluminescence-like (CL-like) emission.

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Al-doped and B, Al co-doped SiO2 xerogels with Eu2+ ions were prepared only by sol-gel reaction in air without reducing heat-treatment or post-doping. The luminescence characteristics and mechanism of europium doping SiO2 xerogels were studied as a function of the concentration of Al, B, the europium concentration and the host composition. The emission spectra of the Al-doped and B, Al codoped samples all show an efficient emission broad band in the blue violet range. The blue emission of the Al-doped sample was centered at 437 nm, whereas the B, Al co-doped xerogel emission maximum shifted to 423 nm and the intensity became weaker. Concentration quenching effect occurred in both the Al-doped and B, Al co-doped samples, which probably is the result of the transfer of the excitation energy from Eu2+ ions to defects. The highest Eu2+ emission intensity was observed for samples with the Si(OC2H5)(4):C2H5OH:H2O molar ratio of 1:2:4. (c) 2006 Elsevier B.V. All rights reserved.

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原子吸收光谱法自五十年代提出以来发展十分迅速,迄今已是一种比较成熟的仪器分析方法。对大多数元素的研究已趋于完善,要提高分析灵敏度比较困难。本工作主要从基体改进剂的角度来研究石墨炉原子吸收光谱法(GFAAS)提高某些元素,尤其是高温元素的测定灵敏度的方法及其应用。GFAAS测硼的报道很少,硼的分析灵敏度低原因的于硼在低温时易以氧化物形式挥发损失,而高温时又生成难熔的B_4C。因此,必须寻找合适的基体改进剂。本工作通过对基体改进剂量的试验以及基体改进剂对硼的灰化和原子化温度影响的研究,得到3Ca, Sr, Ca/Mg、Ca/La和Sr/Mg均可作为测硼的基体改进剂的结果,其中混合基体改进剂Ca/Mg、Ca/La和Sr/Mg较Ca、Sr单独作基体改进剂性能要优越。本工作将x射线衍射分析与热力学计算相结合,综合已有的实验现象,提出了硼原子化过程的初步机理,同时也解释了基体改进剂Sr(NO_3)_2对硼吸收信号的增强作用,并推测了相应原子化过程。即气态硼原子的产生源自固态硼原子的升华,而固态硼原子的产生源自B_2O_3的碳还原。Sr(NO_3)_2的增感作用在于子化前SrB_6的生成,减少了B_2O_3的挥发损失,阻止了B_4C的生成。此外,本工作在基体改进剂研究的基础上,选用Ca/Mg和Sr/Mg混合基体改进剂分别测定了饮用水,标准参考物质桃叶以及高温镍基合金钢中的痕量硼,进行了灵敏度、线性范围和抗干扰能力试验。硼1%吸收时的特征量分别为2.5 * 10~(-10)g和2.0 * 10~(-10)g,线性范围均达1.6μg ml~(-1),回收率在98-105%之间,精密度为4.7-8.4%。饮用水的检出限为50ng ml~(-1) B(3σ)。本工作还比较了金属盐类注入和浸渍处理石墨管后,GFAAS测硼的灵敏度、精密度和石墨管的使用寿命。用扫描电镜分析了石墨管的表面结构,并作了相应解释。建立快速、准确和灵敏的方法检测环境试样中的痕量Be、Al、Sn和Ge,是环境分析的重要课题之一。GFAAS作为一种灵敏的分析方法已广泛地用于环境分析上,但测定某些试样中的Be、Al、Sn和Ge灵敏度尚低。为此,本工作以Ca(NO_3)_2为基体改进剂探讨了增强这四种元素灵敏度的方法。实验结果表明,最佳条件下对比测定,Ca(NO_3)_2能将Be、Al、Sn和Ge的分析灵敏度分别提高3.6,5.7,9和50倍。Ca(NO_3)_2不仅提高了Be、Al、Sn和Ge的分析灵敏度,而且也提高灰化温度,并降低原子化温度,也增强抗干扰能力。本工作还探讨了Ca(NO_3)_2对Be、Al、Sn和Ge的增感机理。实验结果表明,钙对Be和Ge的增感主要在于气相作用,钙对Al的增感主要是固相作用,而钙对Sn的增感不仅有气相作用,也有固相作用。同时利用钙的增感作用直接测定了地下水及水系沉积物标样中的痕量铍,其检出限为5.5 * 10~(-13)g Be(3σ),回收率在98-105%之间,精密度为2.8-4.4%。也利用钙的增感作用直接测定了河水及地下水中的痕量铝,其检出限为1.1ng ml~(-1) Al (3σ),回收率在95-106%之间,测定的精密度为2.7-6.8%。此外,本工作也研究了石墨炉原子吸收光谱法测铝时各种氯化物的干扰现象。结果发现,NaCl,KCl,FeCl_3和CuCl_2对铝产生负干扰,这种干扰来自气相中Cl和Al的结合;MgCl_2和CaCl_2对铝产生正干扰,这种干扰来自它们的氧化物对铝的增感作用;HCl不干扰铝的测定,而HClO_4对铝的干扰与石墨管的表面有关。本工作所建立的GFAAS测Al,BBe的方法,具有简单、快速,且灵敏度高的特点,适用于环境试样中痕量铝、硼、铍的测定。

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制备了3种结构的器件:A:ITO/SiO2/Alq3/Al,BITO/Alq3/SiO2/Al,C:ITO/SiO2/Alq3/SiO2/Al。对于器件A和B在正向偏压(ITO接正极)下才能观察到发光;而对于器件C,在正向和反向偏压下都可以观察到发光。随着电压升高,器件BC产生的蓝色发光相对绿光逐渐增强。这主要是由于SiO2中的加速电子碰撞激发Alq3发光层产生热电子,并与空穴形成电子空穴对,复合产生蓝光;而对于器件A,在反向偏压下被热电子碰撞激发出的空穴与正向偏压下从Al电极进入的电子复合形成激子,产生绿色发光。这些结构的器件发光不但可来源于电子与积累的空穴复合,而且也来自固态阴极射线发光。

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The change of Eu3+-surroundings with the Al/B ratio varying from 4.5 to 2 and Eu/(Al + B) = 0.02, was investigated through X-ray diffraction, infrared spectra, excitation and emission spectra, and phonon sideband. The results show coexistence of the crystal phase Al18B4O33 and the amorphous phase and Eu3+ ions of the samples with the Al/B ratio from 3 to 2 are incorporated into the amorphous phase. It was also found that electron-phonon coupling strength decreases with the Al/B ratio from 3 to 2, non-radiative decay rate decreases, resulting in an increase of the Eu3+-emission intensity. (C) 1999 Elsevier Science Ltd. All rights reserved.

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The system Al2O3-B2O3-Eu2O3, with Al/B ratio varying from 4.5 to 2 and Eu/(Al+B)=0.02, was synthesized by solid state reaction. The vibrational spectra of the system Al2O3-B2O3-Eu2O3 were investigated. It was found that no definite change in the regions of 1200 similar to 1000 cm(-1) due to the adsorption BO4 groups with decreasing Al/B ratio, indicating no Al3+ ion was substituted by Eu3+ ions and other changes revealed that there was an amorphous phase and Eu3+ ions may dope into the amorphous phase. The studies on the luminescent properties of the system Al2O3-B2O3 also show that Eu3+ ions dope into amorphous phase. The investigations on the phonon sideband of Eu3+ indicate that electron-phonon coupling strength decreases with Al/B ratio change from 3 to 2, leading to the non-radiative decay rate decreases and the Eu3+-emission intensity increase.

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采用高温固相反应法,合成了一系列不同组份的磷光体,测定了它们的振动光谱.结果表明,随着Al/B的减小,在1100~1000cm-1的区域内的振动光谱没有明显变化,铕离子不可能进入Al18B4O33的晶格中;振动光谱的背底升高,非晶相逐渐增加.研究了Al2O3-B2O3-Eu2O3中Eu3+离子的光谱特性,发现随着Al/B的减少,Eu3+离子的存在相由晶相逐渐向非晶相转化。在非晶相中,Eu3+离子的声子伴带表明电子与声子的耦合强度随着Al/B的减少而减小,Eu3+离子的发射强度相应的增加,这与多声子弛豫的理论一致.

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The system Al2O3-B2O3-Ce2O3, with Al/B ratio varying from 4.5 to 2 and Ce/(Al + B) = 0.02, has been prepared at the temperature from 1 200 to 1 400 degrees C. Relationship between luminescence and matrices in the system Al2O3-B2O3-Ce2O3 was investigated. It was found that some changes of the matrices occurred with Al/B ratio varying from 4.5 to 2. These results lead to a great change in luminescence properties, indicating variation of Ce-surroundings of crystal field. With the decrease of the ratio from 3 to 2, the excitation and emission peaks shift to shorter wavelengths. it was also found that a new type of rare earth luminescent materials was obtained with appropriate Al/B ratio.