80 resultados para Creutz


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Variantti A.

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Dedikaatio: Laurentius Crevtz, Elias Petri Holm., Johannes Banck.

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Invokaatio: Q.B.V.D.T.O.M.

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Variantti A.

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Invokaatio: Q.B.V.

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Invokaatio: Q.B.V.

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Variantti A.

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Invokaatio: Assistente Sacra Triade.

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Invokaatio: In nomine Jesu.

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Dedikaatio: Rabbe Gottlieb Wrede, [Eva Christina] Wrede née Creutz.

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Invokaatio: Divina clementer adfulgente gratia.

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Variantti A.

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Complexes of the type {[(pyS)Ru(NH3)(4)](2)-mu-L}(n), where pyS = 4-mercaptopyridine, L = 4,4'-dithiodipyridine (pySSpy), pyrazine (pz) and 1,4-dicyanobenzene (DCB), and n = +4 and +5 for fully reduced and mixed-valence complexes, respectively, were synthesized and characterized. Electrochemical data showed that there is electron communication between the metal centers with comproportionation constants of 33.2, 1.30 x 10(8) and 5.56 x 10(5) for L = pySSpy, pz and DCB, respectively. It was also observed that the electronic coupling between the metal centers is affected by the p-back-bonding interaction toward the pyS ligand. Raman spectroscopy showed a dependence of the intensity of the vibrational modes on the exciting radiations giving support to the assignments of the electronic transitions. The degree of electron communication between the metal centers through the bridging ligands suggests that these systems can be molecular wire materials.

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von Ludwig Philippson

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zur Kt. von A. Creutz hrsg. von P. E. Thode