Isotopic ratios and concentrations for mineral-associated and particulate organic fractions of sediment core Wilson_Lake samples

The flux of sediment and organic carbon from continents to the coastal ocean is an important factor governing organic burial in coastal sediments, and these systems preserve important records of environmental and biogeochemical conditions during past global change events. Burial of organic materials in coastal systems can be promoted by chemical resilience or through protection by association with mineral surfaces, but the role and influence of these processes on organic records from ancient sediments is poorly known. We studied sediment and organic matter burial as particulate organic matter (POM) and mineral-bound organic matter (MOM) in near-shore marine sediments from the Wilson Lake core (New Jersey, USA) that span the Paleocene-Eocene thermal maximum (PETM), a climatic perturbation 55.9 Myr ago. Our results show that distinct POM and MOM fractions can be isolated from sediments. Both fractions appear to be dominated by terrestrial material, but POM consisted primarily of recently synthesized material whereas MOM included a significant fraction of pre-aged organic matter from soils or ancient sediments. Variation in organic burial through the PETM is associated with changes in inorganic nitrogen burial, clay mineralogy, and clastic grain size that we associate with enhanced continental weathering, erosion and redeposition of ancient kaolinites, and eustatic sea level variation, respectively. These results provide a new perspective on factors governing carbon burial and carbon isotope records in ancient marine margin settings and offer information on rate and phasing of late Paleocene/early Eocene Earth system changes that may constrain interpretations of the cause of the PETM climate change event.

Hydraulic conductivity and experiments of sediment beds

In marine environments, sediments from different sources are stirred and dispersed, generating beds that are composed of mixed and layered sediments of differing grain sizes. Traditional engineering formulations used to predict erosion thresholds are however, generally for unimodal sediment distributions, and so may be inadequate for commonly occurring coastal sediments. We tested the transport behavior of deposited and mixed sediment beds consisting of a simplified two-grain fraction (silt (D50 = 55 µm) and sand (D50 = 300 µm)) in a laboratory-based annular flume with the objective of investigating the parameters controlling the stability of a sediment bed. To mimic recent deposition of particles following large storm events and the longer-term result of the incorporation of fines in coarse sediment, we designed two suites of experiments: (1) "the layering experiment": in which a sandy bed was covered by a thin layer of silt of varying thickness (0.2 - 3 mm; 0.5 - 3.7 wt %, dry weight in a layer 10 cm deep); and (2) "the mixing experiment" where the bed was composed of sand homogeneously mixed with small amounts of silt (0.07 - 0.7 wt %, dry weight). To initiate erosion and to detect a possible stabilizing effect in both settings, we increased the flow speeds in increments up to 0.30 m/s. Results showed that the sediment bed (or the underlying sand bed in the case of the layering experiment) stabilized with increasing silt composition. The increasing sediment stability was defined by a shift of the initial threshold conditions towards higher flow speeds, combined with, in the case of the mixed bed, decreasing erosion rates. Our results show that even extremely low concentrations of silt play a stabilizing role (1.4% silt (wt %) on a layered sediment bed of 10 cm thickness). In the case of a mixed sediment bed, 0.18% silt (wt %, in a sample of 10 cm depth) stabilized the bed. Both cases show that the depositional history of the sediment fractions can change the erosion characteristics of the seabed. These observations are summarized in a conceptual model that suggests that, in addition to the effect on surface roughness, silt stabilizes the sand bed by pore-space plugging and reducing the inflow in the bed, and hence increases the bed stability. Measurements of hydraulic conductivity on similar bed assemblages qualitatively supported this conclusion by showing that silt could decrease the permeability by up to 22% in the case of a layered bed and by up to 70% in the case of a mixed bed.

Pore water and solid-phase data from site Scharendijke (Lake Grevelingen, NL)

Will be submitted by the author

Data compilation on the biological response to ocean acidification: environmental and experimental context of data sets and related literature

The exponential growth of studies on the biological response to ocean acidification over the last few decades has generated a large amount of data. To facilitate data comparison, a data compilation hosted at the data publisher PANGAEA was initiated in 2008 and is updated on a regular basis (doi:10.1594/PANGAEA.149999). By January 2015, a total of 581 data sets (over 4 000 000 data points) from 539 papers had been archived. Here we present the developments of this data compilation five years since its first description by Nisumaa et al. (2010). Most of study sites from which data archived are still in the Northern Hemisphere and the number of archived data from studies from the Southern Hemisphere and polar oceans are still relatively low. Data from 60 studies that investigated the response of a mix of organisms or natural communities were all added after 2010, indicating a welcomed shift from the study of individual organisms to communities and ecosystems. The initial imbalance of considerably more data archived on calcification and primary production than on other processes has improved. There is also a clear tendency towards more data archived from multifactorial studies after 2010. For easier and more effective access to ocean acidification data, the ocean acidification community is strongly encouraged to contribute to the data archiving effort, and help develop standard vocabularies describing the variables and define best practices for archiving ocean acidification data.

Total mercury and total methylmercury during the POLARSTERN cruise ARK-XXVI/3 (TransArc)

Methylmercury (MeHg) is a neurotoxic compound that threatens wildlife and human health across the Arctic region. Though much is known about the source and dynamics of its inorganic mercury (Hg) precursor, the exact origin of the high MeHg concentrations in Arctic biota remains uncertain. Arctic coastal sediments, coastal marine waters and surface snow are known sites for MeHg production. Observations on marine Hg dynamics, however, have been restricted to the Canadian Archipelago and the Beaufort Sea (<79°N). Here we present the first central Arctic Ocean (79-90°N) profiles for total mercury (tHg) and MeHg. We find elevated tHg and MeHg concentrations in the marginal sea ice zone (81-85°N). Similar to other open ocean basins, Arctic MeHg concentration maxima also occur in the pycnocline waters, but at much shallower depths (150-200 m). The shallow MeHg maxima just below the productive surface layer possibly result in enhanced biological uptake at the base of the Arctic marine food web and may explain the elevated MeHg concentrations in Arctic biota. We suggest that Arctic warming, through thinning sea ice, extension of the seasonal sea ice zone, intensified surface ocean stratification and shifts in plankton ecodynamics, will likely lead to higher marine MeHg production.

(Table T1) Abundance of radiolarian skeletons in scrape samples of ODP Hole 178-1098B

Palmer Deep is a series of three glacially overdeepened basins on the Antarctic Peninsula shelf, ~20 km southwest of Anvers Island. Site 1098 (64°51.72'S, 64°12.48'W) was drilled in the shallowest basin, Basin I, at 1012 m water depth. The sediment recovered was primarily laminated, siliceous, biogenic, pelagic muds alternating with siliciclastic hemipelagic sediments (Barker, Camerlenghi, Acton, et al., 1999). Sedimentation rates of 0.1725 cm/yr in the upper 25 m and 0.7-0.80 cm/yr in the lower 25 m of the core have been estimated from 14C (Domack et al., 2001). The oldest datable sediments have an age of ~13 ka and were underlain by diamicton sediments of the last glacial maximum (Domack et al., 2001). The large-scale water-mass distribution and circulation in the vicinity of Palmer Deep is dominated by Circumpolar Deep Water (CDW) below 200 m (Hofmann et al., 1996). Palmer Deep is too far from the coast to be influenced by glacial meltwater and cold-tongue generation associated with it (Domack and Williams, 1990; Dixon and Domack, 1991). Circulation patterns in the Palmer Deep area are not well understood, but evidence suggests southward flow across Palmer Deep from Anvers Island to Renaud Island (Kock and Stein, 1978). The water south of Anvers Island is nearly open with loose pack ice from February through May. The area is covered with sea ice beginning in June (Gloersen et al., 1992; Leventer et al., 1996). Micropaleontologic data from the work of Leventer et al. (1996) on a 9-m piston core has revealed circulation and climate patterns for the past 3700 yr in the Palmer Deep. The benthic foraminifer assemblage is dominated by two taxa, Bulimina aculeata and Bolivina pseudopunctata, which are inversely related. High relative abundances of B. aculeata occur cyclically over a period of ~230 yr. The assemblage associated with high abundance of B. aculeata in Palmer Deep resembles that from the Bellingshausen shelf, which is associated with CDW. In addition to the faunal evidence, hydrographic data indicate incursions of CDW into Palmer Deep (Leventer et al., 1996). A distinctive diatom assemblage dominated by a single genus was associated with peaks in B. aculeata, whereas a few different assemblages were associated with lows in B. aculeata. Leventer et al. (1996) interpreted the variability in diatom assemblages as an indication of changes in productivity associated with changes in water column stability. Abelmann and Gowing (1997) studied the horizontal and vertical distributions of radiolarians in the Atlantic sector of the Southern Ocean. They show that the spatial distribution of radiolarian assemblages reflects hydrographic boundaries. In a transect from the subtropical Atlantic to polar Antarctic zones, radiolarians in the upper 1000 m of the water column occurred in distinct surface and deep-living assemblages related to water depth, temperature, salinity, and nutrient content. Living assemblages resembled those preserved in underlying surface sediments (Abelmann and Gowing, 1997). Circumantarctic coastal sediments from neritic environments contained a distinctive assemblage dominated by the Phormacantha hystrix/Plectacantha oikiskos group and Rhizoplegma boreale (Nishimura et al., 1997). Low diversity and species compositions distinguished the coastal sediments from the typical pelagic Antarctic assemblages. Factors that controlled the assemblages were water depth, proximity to the coast, occurrence of sea ice, and steepness of topography, rather than temperature and salinity. Nishimura et al. (1997) found a gradient of sorts from deep-water sites containing diverse assemblages typical of pelagic environments to coastal sites with low diversity assemblages dominated by P. hystrix/P. oikiskos group and R. boreale. In general, sites between these two extremes had increased proportions of the coastal assemblage with decreasing water depth (Nishimura et al., 1997). At a site near Hole 1098 (GC905), they showed that the relative abundance of the coastal assemblage increased downcore (Nishimura et al., 1997). The purpose of the research presented here was to make a cursory investigation into the radiolarian assemblages as possible paleoenvironmental indicators.

Texture Mineralogy and Geochemistry Of Sediments From The Coastal Plains Between Kodungallur And Chellanam Central Kerala India

The present study addresses to understand the sedimentological properties of the coasts of kodungallur and chellanam, central Kerala to bring out the relationship between the textural, mineralogical and geochemical characters with that of the respective environment. The grain size study of the beach ridge sediments from different pits has been investigated at close intervals, which enables to understand the grain size variations with depth. The sediment samples from various pits of the beach ridges indicate that the sediments range primarily from medium to very fine sand, well to moderately sorted, fine to coarse skewed and leptokurtic to platykurtic. The study area is considered as a prograding coast. Variations in grain size down the pit give three phases of beach building activities i.e.; a coarsening upward sequence in the bottom layers, a fining upward in the middle and coarsening upward in the top. Beach ridges are formed by swash built sediments with cross bedding and setting lag type sediments with seaward dipping/horizontal units. Geochemical signatures in the study area have been brought out through the analysis of major and trace elements. Iron is significantly enriched and its control over many trace elements is evident. Copper, chromium, cobalt, lithium, lead and zinc show decreasing trend with depth, while sodium, potassium,strontium,nickel and organic carbon increases. The association of many trace elements with organic carbon has also been established. Dissolution of trace elements in anoxic environment, at depth and reprecipitation in the oxic layers, at near or subsurface, are the major mechanism that brought out the variation of certain environmentally sensitive elements

Sedimentology and Geochemistry of core sediments from the Ashtamudi estuary and the adjoining coastal plain,central Kerala,India

The evolution of coast through geological time scale is dependent on the transgression-regression event subsequent to the rise or fall of sea level. This event is accounted by investigation of the vertical sediment deposition patterns and their interrelationship for paleo-enviornmental reconstruction. Different methods like sedimentological (grain size and micro-morphological) and geochemical (elemental relationship) analyses as well as radiocarbon dating are generally used to decipher the sea level changes and paleoclimatic conditions of the Quaternary sediment sequence. For the Indian coast with a coastline length of about 7500 km, studies on geological and geomorphological signatures of sea level changes during the Quaternary were reported in general by researchers during the last two decades. However, for the southwest coast of India particularily Kerala which is famous for its coastal landforms comprising of estuaries, lagoons, backwaters, coastal plains, cliffs and barrier beaches, studies pertaining to the marine transgression-regression events in the southern region are limited. The Neendakara-Kayamkulam coastal stretch in central Kerala where the coast is manifested with shore parallel Kayamkulam Lagoon on one side and shore perpendicular Ashtamudi Estuary on the other side indicating existence of an uplifted prograded coastal margin followed by barrier beaches, backwater channels, ridge and runnel topography is an ideal site for studying such events. Hence the present study has been taken up in this context to address the gap area. The location for collection of core samples representing coastal plain, estuarylagoon and offshore regions have been identified based on published literature and available sedimentary records. The objectives of the research work are:  To study the lithological variations and depositional environments of sediment cores along the coastal plain, estuary-lagoon and offshore regions between Kollam and Kayamkulam in the central Kerala coast  To study the transportation and diagenetic history of sediments in the area  To investigate the geochemical characterization of sediments and to elucidate the source-sink relationship  To understand the marine transgression-regression events and to propose a conceptual model for the region The thesis comprises of 8 chapters. The first chapter embodies the preamble for the selection and significance of this research work. The study area is introduced with details on its physiographical, geological, geomorphological, rainfall and climate information. A review of literature, compiling the research on different aspects such as physico-chemical, geomorphological, tectonics, transgression-regression events are presented in the second chapter and they are broadly classified into three viz:- International, National and Kerala. The field data collection and laboratory analyses adopted in the research work are discussed in the third chapter. For collection of sediment core samples from the coastal plains, rotary drilling method was employed whereas for the estuary-lagoon and offshore locations the gravity/piston corer method was adopted. The collected subsurficial samples were analysed for texture, surface micro-texture, elemental analysis, XRD and radiocarbon dating techniques for age determination. The fourth chapter deals with the textural analysis of the core samples collected from various predefined locations of the study area. The result reveals that the Ashtamudi Estuary is composed of silty clay to clayey type of sediments whereas offshore cores are carpeted with silty clay to relict sand. Investigation of the source of sediments deposited in the coastal plain located on either side of the estuary indicates the dominance of terrigenous to marine origin in the southern region whereas it is predominantly of marine origin towards the north. Further the hydrodynamic conditions as well as the depositional enviornment of the sediment cores are elucidated based on statistical parameters that decipher the deposition pattern at various locations viz., coastal plain (open to closed basin), Ashtamudi Estuary (partially open to restricted estuary to closed basin) and offshore (open channel). The intensity of clay minerals is also discussed. From the results of radiocarbon dating the sediment depositional environments were deciphered.The results of the microtextural study of sediment samples (quartz grains) using Scanning Electron Microscope (SEM) are presented in the fifth chapter. These results throw light on the processes of transport and diagenetic history of the detrital sediments. Based on the lithological variations, selected quartz grains of different environments were also analysed. The study indicates that the southern coastal plain sediments were transported and deposited mechanically under fluvial environment followed by diagenesis under prolonged marine incursion. But in the case of the northern coastal plain, the sediments were transported and deposited under littoral environment indicating the dominance of marine incursion through mechanical as well as chemical processes. The quartz grains of the Ashtamudi Estuary indicate fluvial origin. The surface texture features of the offshore sediments suggest that the quartz grains are of littoral origin and represent the relict beach deposits. The geochemical characterisation of sediment cores based on geochemical classification, sediment maturity, palaeo-weathering and provenance in different environments are discussed in the sixth chapter. In the seventh chapter the integration of multiproxies data along with radiocarbon dates are presented and finally evolution and depositional history based on transgression–regression events is deciphered. The eighth chapter summarizes the major findings and conclusions of the study with recommendation for future work.

Lipid biomarkers in surface sediments from an unusual coastal upwelling area from the SW Atlantic Ocean

The coastal upwelling off Cabo Frio (SE Brazilian coast, SEBC) represents an exception to the world`s oceans since the majority of the upwelling areas are located in eastern boundary current systems. Cabo Frio represents an interesting area for investigation due to its tight physical-biological interaction and the importance of the region as a major fishery area in the SEBC. We analyzed a suite of lipid biomarkers to apportion the main sources of organic matter in surface sediments of the continental shelf off Cabo Frio, comparing the area to non-upwelling regions off the SEBC (shelf break off Cabo Frio and continental shelf off Ubatuba). During spring and summer (the upwelling period), diatoms are probably the major sources of polyunsaturated fatty acids (PUFAs) and C-28 sterols in surface sediments from Cabo Frio continental shelf. Sediments sampled in winter showed, in contrast, lower relative abundance of PUFAs and higher stanol/stenol ratio values. In deeper regions off Cabo Frio, elevated concentrations of alkenones, 24-methylcholest-5,22E-dien-3 beta-ol and 24-ethylcholest-5-en-3 beta-ol during the spring may be produced by prymnesiophytes or cryptophytes and cyanobacteria, respectively. In Ubatuba, the C-27 and C-28 sterols are likely derived from omnivorous salps and nanoflagellates. At non-upwelling areas, despite the increase in biomarker concentrations during spring and summer, lower concentrations of PUFAs, phytol and algal sterols than in shelf areas off Cabo Frio suggest the importance of the upwelling system to the rapid transfer of organic carbon to surface sediments. Our results suggest that spatial and temporal variability in organic matter production and deposition merits consideration for constraining the carbon budgets in the coastal region off Cabo Frio. (C) 2008 Elsevier Ltd. All rights reserved.

Distribution and stable isotopic compositions of hydrogen and carbon of plant-wax derived n-C29 and -C31 alkanes in terrestrial, coastal and offshore surface sediments

Reconstructing terrestrial water budgets is of prime importance for understanding past climate and environment. To shed more light on how plant-wax derived n-alkanes may be used for this purpose we investigated the distribution and stable isotopic compositions of hydrogen (dD) and carbon (d13C) of plant-wax derived n-C29 and -C31 alkanes in terrestrial, coastal and offshore surface sediments in relation to hydrology along a NW-SE transect east of the Italian Apennines from the Po River to the Eastern Gulf of Taranto. The plant wax average chain length increases southward and may relate to increasing temperature and/or aridity. The plant wax dD of the terrestrial and coastal samples also increases southward and mainly reflects changes in the dD of precipitation. The d13C of plant waxes is primarily interpreted in terms of C3 vegetation changes rather than varying contributions by C4 plants. The plant wax d13C-dD composition of the Po River and Apennine rivers differs considerably from that in southern Italy, and suggests a mainly southern source for plant waxes in marine sediments of the Gulf of Taranto. This calibration provides a basis for the reconstruction of past changes in the Italian water balance and n-alkane source areas.

Diatom distribution in sediments of the Peruvian coastal upwelling

Two shelf and upper-slope sites (681 and 686) near present cores of active coastal upwelling on the Peruvian margin were sampled continuously at 7.5 cm intervals down to approximately 25 meters below the seafloor (mbsf). Sedimentary structures were subdivided into homogeneous/bioturbated, laminated, and laminated-varved intervals. Diatom analysis and statistical treatment of data revealed almost persistent upwelling over the last 400,000 yr, with slightly increased upwelling during oxygen-isotope Stages 3, 5, 7, and 8 that resulted in anoxic bottom-water conditions and deposition of laminated/undisturbed primary sedimentary structures.