Production and characterization of poly-(3-hydroxybutyrate) from recombinant Escherichia coli grown on cheap renewable carbon substrates

Although the biopolymer poly-(3-hydroxybutyrate), P[3HB], presents physicochemical properties that make it an alternative material to conventional plastics, its biotechnological production is quite expensive. As carbon substrates contribute greatly to P[3HB] production cost, the utilization of a cheaper carbon substrate and less demanding micro-organisms should decrease its cost. In the present study a 23 factorial experimental design was applied, aiming to evaluate the effects of using hydrolysed corn starch (HCS) and soybean oil (SBO) as carbon substrates, and cheese whey (CW) supplementation in the mineral medium (MM) on the responses, cell dried weigh (DCW), percentage P[3HB] and mass P[3HB] by recombinant Escherichia coli strains JM101 and DH10B, containing the P[3HB] synthase genes from Cupriavidus necator (ex-Ralstonia eutropha). The analysis of effects indicated that the substrates and the supplement and their interactions had positive effect on CDW. Statistically generated equations showed that, at the highest concentrations of HCS, SO and CW, theoretically it should be possible to produce about 2 g L(1) DCW, accumulating 50% P[3HB], in both strains. To complement this study, the strain that presented the best results was cultivated in MM added to HCS, SBO and CW ( in best composition observed) and complex medium (CM) to compare the obtained P[3HB] in terms of physicochemical parameters. The obtained results showed that the P[3HB] production in MM (1.29 g L(-1)) was approximately 20% lower than in CM (1.63 g L(-1)); however, this difference can be compensated by the lower cost of the MM achieved by the use of cheap renewable carbon sources. Moreover, using differential scanning calorimetry and thermogravimetry analyses, it was observed that the polymer produced in MM was the one which presented physicochemical properties (Tg and Tf) that were more similar to those found in the literature for P[3HB].

Performance estimation for concretes made with recycled aggregates of construction and demolition waste of some Brazilian cities

The aim of this paper is to verify the influence of composition variability of recycled aggregates (RA) of construction and demolition wastes (CDW) on the performance of concretes. Performance was evaluated building mathematical models for compressive strength, modulus of elasticity and drying shrinkage. To obtain such models, an experimental program comprising 50 concrete mixtures was carried out. Specimens were casted, tested and results for compressive strength, modulus of elasticity and drying shrinkage were statistically analyzed. Models inputs are CDW composition observed at seven Brazilian cities. Results confirm that using RA from CDW for concrete building is quite feasible, independently of its composition, once compressive strength and modulus of elasticity still reached considerable values. We concluded the variability presented by recycled aggregates of CDW does not compromise their use for concrete building. However, this information must be used with caution, and experimental tests should always be performed to certify concrete properties.

Recycling of end of life concrete fines (0 - 4 mm) into silica and cement

The purpose of this work is to find a methodology in order to make possible the recycling of fines (0 - 4 mm) in the Construction and Demolition Waste (CDW) process. At the moment this fraction is a not desired by-product: it has high contaminant content, it has to be separated from the coarse fraction, because of its high water absorption which can affect the properties of the concrete. In fact, in some countries the use of fines recycled aggregates is highly restricted or even banned. This work is placed inside the European project C2CA (from Concrete to Cement and Clean Aggregates) and it has been held in the Faculty of Civil Engineering and Geosciences of the Technical University of Delft, in particular, in the laboratory of Resources And Recycling. This research proposes some procedures in order to close the loop of the entire recycling process. After the classification done by ADR (Advanced Dry Recovery) the two fractions "airknife" and "rotor" (that together constitute the fraction 0 - 4 mm) are inserted in a new machine that works at high temperatures. The temperatures analysed in this research are 600 °C and 750 °C, cause at that temperature it is supposed that the cement bounds become very weak. The final goal is "to clean" the coarse fraction (0,250 - 4 mm) from the cement still attached to the sand and try to concentrate the cement paste in the fraction 0 - 0,250 mm. This new set-up is able to dry the material in very few seconds, divide it into two fractions (the coarse one and the fine one) thanks to the air and increase the amount of fines (0 - 0,250 mm) promoting the attrition between the particles through a vibration device. The coarse fraction is then processed in a ball mill in order to improve the result and reach the final goal. Thanks to the high temperature it is possible to markedly reduce the milling time. The sand 0 - 2 mm, after being heated and milled is used to replace 100% of norm sand in mortar production. The results are very promising: the mortar made with recycled sand reaches an early strength, in fact the increment with respect to the mortar made with norm sand is 20% after three days and 7% after seven days. With this research it has been demonstrated that once the temperature is increased it is possible to obtain a clean coarse fraction (0,250 - 4 mm), free from cement paste that is concentrated in the fine fraction 0 - 0,250 mm. The milling time and the drying time can be largely reduced. The recycled sand shows better performance in terms of mechanical properties with respect to the natural one.

Seawater Cd reconstruction for the western subtropical South Atlantic

Benthic foraminiferal Cd/Ca from an intermediate depth, western South Atlantic core documents the history of southward penetration of North Atlantic Intermediate Water (NAIW). Cd seawater estimates (CdW) for the last glacial are consistent with the production of NAIW and its export into the South Atlantic. At ~14.5 ka concurrently with the onset of the Bølling-Allerød to Younger Dryas cooling, the NAIW contribution to the South Atlantic began to decrease, marking the transition from a glacial circulation pattern to a Younger Dryas circulation. High CdW in both the deep North Atlantic and the intermediate South Atlantic imply reduced export of deep and intermediate water during the Younger Dryas and a significant decrease in northward oceanic heat transport. A modern circulation was achieved at ~9 ka, concurrently with the establishment of Holocene warmth in the North Atlantic region, further supporting a close linkage between deepwater variability and North Atlantic climate.

Proportion of bryozoa, isopoda and ostracoda, and bryozoan species richness on the Antarctic continental shelf, slope and abyss

The Antarctic continental slope spans the depths from the shelf break (usually between 500 and 1000 m) to ~3000 m, is very steep, overlain by 'warm' (2-2.5 °C) Circumpolar Deep Water (CDW), and life there is poorly studied. This study investigates whether life on Antarctica's continental slope is essentially an extension of the shelf or the abyssal fauna, a transition zone between these or clearly distinct in its own right. Using data from several cruises to the Weddell Sea and Scotia Sea, including the ANDEEP (ANtarctic benthic DEEP-sea biodiversity, colonisation history and recent community patterns) I-III, BIOPEARL (Biodiversity, Phylogeny, Evolution and Adaptive Radiation of Life in Antarctica) 1 and EASIZ (Ecology of the Antarctic Sea Ice Zone) II cruises as well as current databases (SOMBASE, SCAR-MarBIN), four different taxa were selected (i.e. cheilostome bryozoans, isopod and ostracod crustaceans and echinoid echinoderms) and two areas, the Weddell Sea and the Scotia Sea, to examine faunal composition, richness and affinities. The answer has important ramifications to the link between physical oceanography and ecology, and the potential of the slope to act as a refuge and resupply zone to the shelf during glaciations. Benthic samples were collected using Agassiz trawl, epibenthic sledge and Rauschert sled. By bathymetric definition, these data suggest that despite eurybathy in some of the groups examined and apparent similarity of physical conditions in the Antarctic, the shelf, slope and abyssal faunas were clearly separated in the Weddell Sea. However, no such separation of faunas was apparent in the Scotia Sea (except in echinoids). Using a geomorphological definition of the slope, shelf-slope-abyss similarity only changed significantly in the bryozoans. Our results did not support the presence of a homogenous and unique Antarctic slope fauna despite a high number of species being restricted to the slope. However, it remains the case that there may be a unique Antarctic slope fauna, but the paucity of our samples could not demonstrate this in the Scotia Sea. It is very likely that various ecological and evolutionary factors (such as topography, water-mass and sediment characteristics, input of particulate organic carbon (POC) and glaciological history) drive slope distinctness. Isopods showed greatest species richness at slope depths, whereas bryozoans and ostracods were more speciose at shelf depths; however, significance varied across Weddell Sea and Scotia Sea and depending on bathymetric vs. geomorphological definitions. Whilst the slope may harbour some source populations for localised shelf recolonisation, the absence of many shelf species, genera and even families (in a poorly dispersing taxon) from the continental slope indicate that it was not a universal refuge for Antarctic shelf fauna.

Sea surface temperature reconstruction for ODP Hole 178-1098B

The disintegration of ice shelves, reduced sea-ice and glacier extent, and shifting ecological zones observed around Antarctica (Cook et al., 2005, doi:10.1126/science.1104235; Stammerjohn et al., 2008, doi:10.1016/j.dsr2.2008.04.026) highlight the impact of recent atmospheric (Steig et al., 2009, doi:10.1038/nature07669) and oceanic warming (Gille, 2002, doi:10.1126/science.1065863) on the cryosphere. Observations (Cook et al., 2005, doi:10.1126/science.1104235; Stammerjohn et al., 2008, doi:10.1016/j.dsr2.2008.04.026) and models (Pollard and DeConto, 2009, doi:10.1038/nature07809) suggest that oceanic and atmospheric temperature variations at Antarctica's margins affect global cryosphere stability, ocean circulation, sea levels and carbon cycling. In particular, recent climate changes on the Antarctic Peninsula have been dramatic, yet the Holocene climate variability of this region is largely unknown, limiting our ability to evaluate ongoing changes within the context of historical variability and underlying forcing mechanisms. Here we show that surface ocean temperatures at the continental margin of the western Antarctic Peninsula cooled by 3-4 °C over the past 12,000?years, tracking the Holocene decline of local (65° S) spring insolation. Our results, based on TEX86 sea surface temperature (SST) proxy evidence from a marine sediment core, indicate the importance of regional summer duration as a driver of Antarctic seasonal sea-ice fluctuations (Huybers and Denton, 2008, doi:10.1038/ngeo311). On millennial timescales, abrupt SST fluctuations of 2-4 °C coincide with globally recognized climate variability (Mayewski et al., 2004, doi:10.1016/j.yqres.2004.07.001). Similarities between our SSTs, Southern Hemisphere westerly wind reconstructions (Moreno et al., 2010, doi:10.1130/G30962.1) and El Niño/Southern Oscillation variability (Conroy et al., 2008, doi:10.1016/j.quascirev.2008.02.015) indicate that present climate teleconnections between the tropical Pacific Ocean and the western Antarctic Peninsula (Yuan et al., 2004, doi:10.1017/S0954102004002238) strengthened late in the Holocene epoch. We conclude that during the Holocene, Southern Ocean temperatures at the western Antarctic Peninsula margin were tied to changes in the position of the westerlies, which have a critical role in global carbon cycling (Moreno et al., 2010, doi:10.1130/G30962.1; Anderson et al., 2009, doi:10.1126/science.1167441).

(Table 1) Vertical turbulent eddy diffusivity of selected stations from the Nathaniel B. Palmer cruise NBP09-01

Dissolved iron (DFe) and total dissolvable Fe (TDFe) were measured in January-February 2009 in Pine Island Bay, as well as in the Pine Island and Amundsen polynyas (Amundsen Sea, Southern Ocean). Iron (Fe) has been shown to be a limiting nutrient for phytoplankton growth, even in the productive continental shelves surrounding the Antarctic continent. However, the polynyas of the Amundsen Sea harbor the highest concentrations of phytoplankton anywhere in Antarctica. Here we present data showing the likely sources of Fe that enable such a productive and long lasting phytoplankton bloom. Circumpolar Deep Water (CDW) flows over the bottom of the shelf into the Pine Island Bay where DFe and TDFe were observed to increase from 0.2 to 0.4 nM DFe and from 0.3-4.0 to 7-14 nM TDFe, respectively. At the southern end of Pine Island Bay, the CDW upwelled under the Pine Island Glacier, bringing nutrients (including Fe) to the surface and melting the base of the glacier. Concentrations of DFe in waters near the Pine Island Glacier and the more westward lying Crosson, Dotson, and Getz Ice Shelves varied between 0.40 and 1.31 nM, depending on the relative magnitude of upwelling, turbulent mixing, and melting. These values represent maximum concentrations since associated ligands (which increase the solubility of Fe in seawater) were saturated with Fe (Thuroczy et al., 2012, doi:10.1016/j.dsr2.2012.03.009). The TDFe concentrations were very high compared to what previously has been measured in the Southern Ocean, varying between 3 and 106 nM. In the Pine Island Polynya, macronutrients and DFe were consumed by the phytoplankton bloom and concentrations were very low. We calculate that atmospheric dust contributed < 1% of the Fe necessary to sustain the phytoplankton bloom, while vertical turbulent eddy diffusion from the sediment, sea ice melt, and upwelling contributed 1.0-3.8%, 0.7-2.9%, and 0.4-1.7%, respectively. The largest source was Fe input from the PIG, which could satisfy the total Fe demand by the phytoplankton bloom by lateral advection of Fe over a range of 150 km from the glacier. The role of TDFe as a phytoplankton nutrient remains unclear, perhaps representing an important indirect Fe source via dissolution and complexation by dissolved organic ligands (Gerringa et al., 2000, doi:10.1016/S0304-4203(99)00092-4; Borer et al., 2005, doi:10.1016/j.marchem.2004.08.006).

(Appendix table DR1) Foraminiferal distribution data for ODP Hole 178-1098B

Benthic foraminiferal data from Ocean Drilling Program Site 1098 indicate significant changes in deep-water conditions of the Palmer Deep, western Antarctic Peninsula margin, throughout the Holocene (13 ka to present). The earliest Holocene represents a period of transition from the Last Glacial Maximum (LGM). Cold bottom waters, similar to saline shelf water (SSW), dominated the middle Holocene. The late Holocene in the Palmer Deep has been characterized by alternating dominance of circumpolar deep water (CDW) and saline shelf water. These changes have global oceanographic and climatic implications. We suggest that the middle Holocene bottom-water record, in the absence of circumpolar deep water on the western Antarctic Peninsula shelf, indicates high saline shelf water production and/or weakened circumpolar deep water production during the middle Holocene climatic optimum. The late Holocene benthic foraminiferal record indicates rapidly fluctuating sea-ice conditions and may indicate a teleconnection between the South Pacific and Southern Ocean, thus having implications related to the Southern Oscillation Index.

Limiting properties in the characterisation of mixed recycled aggregates for use in the manufacture of concrete

El objetivo principal de este trabajo de investigación es estudiar las propiedades del árido reciclado mixto para la fabricación de hormigón reciclado en aplicaciones no estructurales. Se ha realizado la caracterización completa de 35 muestras de áridos reciclados mixtos gruesos de distinta calidad, procedentes de 13 plantas de tratamiento diferentes de la geografía española. Se han estudiado las correlaciones que existen entre las diferentes propiedades, en particular, con la absorción de agua, el contenido de sulfatos y la composición. Se propone una clasificación de los áridos reciclados y se limita de forma indicativa el contenido de yeso para que una muestra de árido reciclado mixto cumpla con la limitación del 0,8% de los sulfatos solubles en ácido de la Instrucción EHE-08. Recycling of construction and demolition waste (CDW) has become a widespread concern in Spain for the last years, as a way to preserve natural resources and achieve a better control of waste disposal sites.Specific applications which make use of mixed recycled aggregates are of great importance, as this types of aggregates constitute the majority of the total production. Structural and non-structural concrete is one of the possible applications, being this the main goal of our study. This paper presents a study on the physical and chemical characteristics of mixed recycled aggregates which have been obtained from different CDW treatment plants of Spain. Correlations between the different properties were investigated in order to find criterions of acceptance for recycled aggregates to be used in concrete. The comparison between the properties offers the possibility of pre-selecting a great quantity of mixed recycled aggregates, these being suitable for either structural and non-structural concrete. The determination of water absorption and the gypsum content are good indicators in order to evaluate the quality of the mixed recycled aggregates for its application in the production of concrete.

Sistema de gestión de residuos de construcción y demolición en obras de edificación residencial. Buenas prácticas en la ejecución de obra

En el sector de la edificación, las grandes constructoras comienzan a considerar aspectos medioambientales, no limitándose a lo establecido por la legislación vigente, y buscando la implementación de buenas prácticas. Si bien este hecho es una realidad para las grandes empresas constructoras, todavía falta que la gran mayoría de las empresas del sector (pequeñas y medianas) adopten ésta tendencia. En este sentido, las publicaciones y estadísticas consultadas revelan que el sector de la construcción sigue siendo el sector con menor número de Sistemas de Gestión Ambiental (SGA) certificados en comparación con otros sectores industriales, debido principalmente a las peculiaridades de su actividad. Por otra parte, el sector de la construcción genera grandes cantidades de residuos de construcción y demolición (RCD). Aunque, en los últimos años la actividad de la construcción ha disminuido, debido a la crisis económica del país, no hay que olvidar todos los problemas causados por este tipo de residuos, o mejor dicho, por su gestión. La gestión de los RCD actual está lejos de alcanzar la meta propuesta en la Directiva Marco de Residuos (DMR), la cual exige un objetivo global para el año 2020 en el que el 70% de todos los RCD generados deberán ser reciclados en los países de la UE. Pero, la realidad es que sólo el 50% de la RCD generados en la Unión Europea se recicla. Por este motivo, en los últimos años se ha producido una completa modificación del régimen jurídico aplicable a los RCD, incorporando importantes novedades a nuestro ordenamiento interno como son: la redacción de un Estudio de gestión de RCD (en fase de diseño) y un Plan de gestión de RCD (en fase de ejecución). Entre estas medidas destaca el poder conocer, con la antelación suficiente, la cantidad y el momento en que los RCD son generados, para así poder planificar la gestión más adecuada para cada categoría de RCD. Es por ello que el desarrollo de cualquier instrumento que determine la estimación de RCD así como iniciativas para su control debe ser considerado como una herramienta para dar respuestas reales en el campo de la sostenibilidad en la edificación. Por todo lo anterior, el principal objetivo de la Tesis Doctoral es mejorar la gestión actual de los RCD, a través de la elaboración e implementación en obra de un Sistema de gestión de RCD en fase de ejecución que podrá ser incluido en el Sistema de Gestión Ambiental de las empresas constructoras. Para ello, se ha identificado la actividad que más residuo genera, así como las diferentes categorías de RCD generadas durante su ejecución, a través del análisis de nueve obras de edificación de nueva planta. Posteriormente, se han determinado y evaluado, en función de su eficacia y viabilidad, veinte buenas prácticas encaminadas a reducir la generación de RCD. También, se han identificado y evaluado, en función de su coste económico, cinco alternativas de gestión para cada categoría de RCD generada. Por último, se ha desarrollado e implementado un Sistema de Gestión de RCD en una empresa de construcción real. En definitiva, el Sistema de Gestión de RCD propuesto contiene una herramienta de estimación de RCD y también proporciona una relación de buenas prácticas, según su viabilidad y eficacia, sobre los aspectos más significativos en cuanto a la gestión de RCD se refiere. El uso de este Sistema de gestión de RCD ayudará a los técnicos de la construcción en el desarrollo de los documentos "Estudio de gestión de RCD " y "Plan de gestión de RCD " - requeridos por ley -. Además, el Sistema promueve la gestión ambiental de la empresa, favoreciendo la cohesión del proceso constructivo, estableciendo responsabilidades en el ámbito de RCD y proporcionando un mayor control sobre el proceso. En conclusión, la implementación de un sistema de gestión de RCD en obra ayuda a conseguir una actividad de edificación, cuyo principal objetivo sea la generación de residuos cero. ABSTRACT Currently, in the building sector, the main construction companies are considering environmental issues, not being limited to the current legislation, and seeking the implementation of good practices. While this fact is a reality for large construction companies, still the vast majority of construction companies (small and medium enterprises) need to accept this trend. In this sense, official publications and statistics reveal that the construction sector remains with the lowest number of certified Environmental Management Systems (EMS) compared to other industrial sectors, mainly due to the peculiarities of its activity. Moreover, the construction industry in Spain generates large volumes of construction and demolition waste (CDW) achieving a low recycling rate compared to other European Union countries and to the target set for 2020. Despite the complete change in the legal regime for CDW in Spain, there are still several difficulties for their application at the construction works. Among these difficulties the following can be highlighted: onsite segregation, estimating CDW generation and managing different CDW categories. Despite these difficulties, the proper CDW management must be one of the main aspects considered by construction companies in the EMS. However, at present the EMS used in construction companies consider very superficially CDW management issues. Therefore, current EMS should go a step further and include not only procedures for managing CDW globally, but also specific procedures for each CDW category, taking into account best practices for prevention, minimization and proper CDW management in order to achieve building construction works with zero waste generation. The few scientific studies analysing EMS implementation in construction enterprises focus on studying the benefits and barriers of their implementation. Despite the drawbacks found, implementing an EMS would bring benefits such as improving the corporate image in relation to the environment, ensuring compliance with the law or reducing environmental risks. Also, the international scientific community has shown great interest in defining models to estimate in advance the CDW that will be generated during the building construction or rehabilitation works. These studies analyse the overall waste generation and its different CDW categories. However, despite the many studies found on CDW quantification, analysing its evolution throughout the construction activities is a factor that must be further studied and discussed in greater depth, as results would be of great significance when planning the CDW management. According to the scientific studies analysing the implementation of good environmental practices in construction sites, it seems that, in general, the CDW collection system is done in a decentralized manner by each subcontracted company. In addition, the corporate image generated when poor practices are done may adversely affect the company's reputation and can result in loss of contracts. Finally, although there are numerous guides and manuals of good practices for CDW management, no references have been found implementing these measures in the Environmental Management System of the construction companies. From all the above, this thesis aims to provide answers to reduce the environmental impact caused by CDW generation in building construction works, in order to get a building process with zero waste generation. In this sense, is essential to generate new knowledge in order to implement a system which can carry out comprehensive management of CDW generated onsite, at the design stage until the end of its life cycle, taking into account both technical and economic criteria. Therefore, the main objective of this thesis is to define and implement a CDW management system for residential building construction works, helping construction agents not only to manage the CDW in accordance with current legislation, but also minimizing their generation on site by applying best practices, resulting in achieving the goal of zero waste in building works.

Assessing construction and demolition waste on masonry works to avoid future generation

The difficulty of dealing with construction and demolition waste (CDW) on construction sites is not new and continues to be a significant environmental problem. Currently the CDW collection system in Spain is done in a decentralized manner by each sub-contracted company, being necessary to implement effective waste management measures ensuring a correct management and minimization. During the last years several measures have been launched in order to improve and encourage the reuse and recycling of CDW. A widespread solution for CDW recovery is using them as a landscaping aggregate or for road bases and sub-bases. However, measures encouraging onsite prevention still need to be enhanced. This paper studies the major work stage generating CDW and analyses the categories of CDW produced during its execution. For this, several real building sites have been analysed in order to quantify the estimation of CDW generated. Results of this study show that a significant contributor to the CDW generation on building construction sites in Spain are the masonry works. Finally, a Best Practices Manual (BPM) is proposed containing several strategies on masonry works aimed not only at CDW prevention, but also at improving their management and minimization. The use of this BPM together with the Study and Plan of CDW management --required by law--, promotes the environmental management of the company, favouring the cohesion of the construction process organization at all stages giving rise to establishing responsibilities in the field of waste and providing a greater control over the process. Keywords: construction and demolition waste, management, masonry works, good practice measures, prevention.

Los residuos de envases y embalajes en edificación residencial. Patrones de generación y estrategias de mejora de su gestión

Uno de los retos a los que se enfrenta la humanidad es la demanda de una sociedad con casi cero residuos: la búsqueda de una economía más eficiente en el uso de los recursos teniendo en cuenta el cambio climático y un abastecimiento sostenible de materias primas que permitan satisfacer las necesidades de una población mundial cada vez mayor, dentro de los límites sostenibles de los recursos naturales del planeta. Abordar este desafío implica la recuperación y reciclaje de materiales para reducir consumos de materias primas y, para ello, debe promoverse la innovación en la prevención y gestión de residuos, como estrategia hacia un desarrollo urbano sostenible. Los envases y embalajes forman parte de la cultura actual, relacionándose con el grado de desarrollo de países y regiones; el sector de la construcción no es ajeno a la problemática y genera un importante volumen de embalajes en las obras que no se gestionan de forma adecuada. El modelo de gestión de Residuos de Construcción Demolición (RCD) actual es poco eficaz, ya que los vertederos siguen recibiendo grandes cantidades de residuos valorizables. La normativa ha conseguido minimizar las prácticas ilegales, pero se comprueba que la gestión actual de los RCD en obra deja en manos de las plantas de tratamiento la misión de separar los residuos según su naturaleza y los datos aportados por las distintas plantas no permiten afirmar el grado de alcance de dicho objetivo, ni el destino de los mismos. Los envases y embalajes son un tipo de residuos que por su naturaleza suponen una fuente de recursos valorizables y por ello están presentes en directivas y leyes, dirigidas fundamentalmente al sector de la alimentación. En el ámbito de la construcción, hasta la fecha, no se habían tratado de forma específica, motivo que justifica este trabajo. Esta Tesis Doctoral tiene como objetivo principal mejorar la gestión de residuos de embalajes procedentes de materiales de construcción. Para ello se estudia un importante conjunto de obras de edificación residencial colectiva de 1173 viviendas, análisis que llevará a conocer los patrones de producción de los Residuos de Envases y Embalajes en Construcción (REEC) e identificar los productos o materiales responsables de su generación. La monitorización realizada, permitirá diseñar estrategias específicas que minimicen la generación de estos residuos y optimicen su valorización. Se ha podido comprobar que el tratamiento particularizado de los REEC puede mejorar los resultados de la gestión del conjunto de RCD, debido a que, al no mezclarse, se elimina un importante agente contaminador de los residuos inertes. Las obras analizadas alcanzan un nivel de segregación in situ muy bajo, y los capítulos de cerramientos e instalaciones suman más del 50% del global de REEC. Particularizando en cada tipo de material, el cartón predomina en los trabajos de electricidad, el plástico en las particiones y la madera en fachadas. Se evalúa la opción del eco-­‐rediseño para uno de los embalajes predominantes, y se identifican estrategias para minimizar su impacto. Se comprueba que el ahorro en la gestión de RCD en caso de impulsar la segregación in situ no es muy significativo en las obras estudiadas, si bien se demuestra que la viabilidad económica es el factor más importante para motivar a las empresas constructoras. Las Administraciones Públicas deberían incentivar la gestión responsable, estableciendo medidas de control en las plantas de tratamiento e implementando en sus obras medidas de gestión de RCD ejemplares para el mercado. Una adecuada planificación de la obra, y formación específica para el personal son medidas que facilitan la segregación in situ y mejoran los resultados. Los promotores, mediante su relación contractual con el resto de agentes, tienen la capacidad de establecer objetivos de reducción, planificación y gestión sostenible de los REEC. Por último, se propone un sistema de gestión de REEC, integrable dentro del Sistema de Gestión de la empresa constructora, que permite evitar que residuos valorizables tales como los envases y embalajes se envíen a vertedero, guiando al sector hacia un futuro más respetuoso, alineado con el desarrollo sostenible. ABSTRACT One of the challenges humanity faces is the demand of an almost zero waste society: the search for a more efficient economy in the use of resources, taking into account climate change and a sustainable supply of raw materials, that meet the needs of an increasing world population within the sustainable limits of the planet's natural resources. Addressing this challenge involves the recovery and recycling of materials to reduce consumption of raw materials, so innovation must therefore be promoted in the prevention and management of waste, as a strategy towards a sustainable urban development. Packaging is part of our current culture and is related to the degree of development of countries and regions; the construction sector is no stranger to this problem and generates a significant amount of packaging waste in the site works, which nowadays is not managed properly. The current Construction Demolition Waste (CDW) management model is ineffective, since landfills continue to receive large amounts of recoverable waste. The legislation has managed to minimize illegal practices, but it has been observed that the current management of CDW in the analysed works leaves the mission of separating waste according to their nature to the plants, and data provided by the latter does not allow for checking the scope of this objective, nor the destiny of the waste. Packaging is a type of waste which, by its nature, represents a source of recoverable resources and is therefore present in directives and laws, focused primarily on the food industry. It has not been specifically treated to date in the construction field, hence the reason that justifies this work. This Thesis aims to improve the management of packaging waste from construction materials. An important set of residential building works with 1173 dwellings is analysed, which leads to knowledge on the production patterns of packaging waste (PW) in the construction industry, and the identification of the products responsible for its generation. The monitorization also allows for the design of specific strategies which minimise the generation of waste and optimize recovery. It has been found that the individualized treatment of PW can improve the results of the management of the whole CDW since, when not mixed, a major pollutant of inert waste is removed. The analysed works reached a very low segregation level and the façades and building services phases account for more than 50% of the overall PW. Focusing on each type of material, cardboard predominates electricity works, plastic on partitions and wood on façades. Eco-­‐redesign is evaluated for one of the predominant packages, and strategies are identified to minimise their impact are . There is evidence that the savings in the CDW management in case of promoting segregation on site are not very significant at the studied works, although economic feasibility is the most important factor to motivate the construction companies. Public Administrations should encourage responsible management, establishing control measures in treatment plants and implementing CDW management exemplary measures on their work sites for the market. A proper planning of the works and specific training for the personnel are measures that facilitate in situ segregation and improve outcomes. The developers, through their contractual relationship with the other agents, have the ability to set reduction targets, planning and sustainable management of PW. Finally, a management system for PW is proposed, integrated within the Management System of the construction company, which aims to avoid that recoverable waste such as packaging is sent to landfill, leading the industry towards a more environmentally friendly future, aligned with sustainable development.

Caracterización físico-mecánica del yeso de construcción con adición de residuos de poliestireno extruído y residuos cerámicos

Este trabajo estudia el comportamiento de una matriz de yeso de construcción a la que se le han añadido residuos de construcción y demolición (RCD), residuos de poliestireno extruido (XPS) y residuos cerámicos respectivamente, combinados y en diferentes porcentajes en función del peso del yeso. Los residuos de XPS son producto de una obra en Madrid donde el material fue utilizado como aislamiento térmico y los residuos cerámicos corresponden a trozos de ladrillos toscos encontrados en una obra paralizada en la ciudad de Ávila. Se confeccionaron probetas con porcentajes hasta 3% de XPS y hasta 50% de cerámicos en función del peso del yeso utilizado, como referencia se confeccionaron probetas sin adición de RCD. Fueron ensayadas en laboratorio y se determinaron las características físicas y mecánicas de las mismas. Tras un análisis comparativo se evidencian que la adición de residuos de XPS y residuos cerámicos en conjunto disminuye la densidad seca del material y la absorción de agua por capilaridad, en algunos casos disminuye la conductividad térmica y aumenta la dureza superficial. ABSTRACT: This paper studies the behavior of a building gypsum matrix to which have been added Construction and Demolition waste (CDW), residues of extruded polystyrene (XPS) and ceramic waste respectively, and combined in different percentages depending on the weight of gypsum. XPS waste are the product of a work in Madrid where the material was used as thermal insulation and ceramic waste correspond to pieces of rough bricks found in a paralyzed work in the city of Avila. Specimens were prepared with percentages up to 3% of XPS and up to 50% depending on the weight ceramic gypsum used as reference samples were prepared without addition of CDW. They were tested in laboratory and determined the physical and mechanical characteristics thereof. After a comparative analysis they show that the addition of ceramic waste and waste XPS decreases together dry material density and water absorption by capillary action, in some cases the thermal conductivity decreases and increases surface hardness.

Tratamento superficial dos agregados reciclados de RCD com hidrofugantes.

A proposta busca reduzir a absorção de água dos agregados reciclados de Resíduos de Construção e Demolição (RCD), através do tratamento de sua superfície com hidrofugante, de maneira que estes não aumentem o consumo de água tampouco reduzam a resistência mecânica. Os agregados reciclados de RCD foram caracterizados quanto à granulometria, morfologia, porosidade, ângulo de contato aparente, absorção de água, análise de imagem e rugosidade superficial. Em seguida, os mesmos foram tratados superficialmente com dois tipos de hidrofugante: solução de silano e parafina. Todos os tratamentos permitiram reduzir a absorção de água dos agregados reciclados de RCD. O tratamento por imersão foi aquele que permitiu obter os melhores resultados e a menor variabilidade entre as técnicas. Os tratamentos hidrofugam a superfície, apesar da parafina apresentar maior molhabilidade. O tratamento com parafina apresentou, em termos de absorção de água, resultados inferiores e menos variáveis que o silano. Os parâmetros de rugosidade constataram que, ambos os materiais perdem seu perfil topográfico original quando tratados com parafina. Os diferentes agregados reciclados com cada hidrofugante foram aplicados em materiais cimentícios analisados no estado fresco e no estado endurecido. Os tratamentos reduziram a absorção e o consumo de água de mistura, porém afetaram negativamente as propriedades mecânicas, devido nova interface gerada (no caso específica de parafina) e falta de molhabilidade nas superfícies.