Lithology and pollen record of 4 profiles from the Bavaria, southern Germany

Palynological investigations of sediments from northern Bavaria (Rhön, Grabfeld, Lange Berge) reveal the Late Glacial and Postglacial history of the regional vegetation. The older sedirnents were found in the Rhön (Schwarzes Moor) and date back into the Bölling Period. At the end of that period pine spread into the Grabfeld. In both areas Lacher Tuff has been found. A radiocarbon date of 10,300 BP was found for the Late Glacial - Postglacial transition and one of 9300 BP for the Preboreal - Boreal transition. Hazel reached its highest values in the Rhön around 7,400 BP. During the Atlanticum a deciduous mixed oak forest covered the Rhön and Grabfeld regions. Beech dominated since the Subatlanticum. In the Lange Berge region, however, a mixed forest with Fagus, Picea, Pinus and Abies developed. In the Rhön first anthropogenic influence was found during the Latene Period. The boundary between zone IX and X has been dated at 820 A.D., and the start of extensive forest clearances at 1000 A. D. A culmination of landuse was found for the Medieval Period. At the end of that period however the Rhön was deserted. New forest clearances started around 1500 A.D., but were interrupted by the 'Thirty Years War'. Afterwards the Rhön got its present appearance.

The past distribution of pinus nigra arnold in northern iberia. Contribution from its macroremains.

The presence of Pinus nigra in central Spain, where its natural populations are very rare, has led to different interpretations of the current vegetation dynamics. Complementary to the available palynological evidence, macroremains provide local information of high taxonomic resolution that helps to reconstruct the palaeobiogeography of a given species. Here we present new macrofossil data from Tubilla del Lago, a small palaeolake located at the eastern part of the northern Iberian Meseta. We identified 17 wood samples and 71 cones on the basis of their wood anatomy and morphology, respectively. S ome of the fossil samples were radiocarbon dated (~4.230-3210 years cal BP). The results demonstrate the Holocene presence of P. nigra in the study area, where it is currently extinct. This evidence, together with other published palaeobotanical studies, indicates that the forests dominated by P. nigra must have had a larger importance on the landscape prior to the anthropogenic influence on the northern Iberian Meseta.

Estudio del radón en viviendas mediante modelos de minería de datos basados en cubos OLAP

En esta tesis doctoral se estudian las variaciones de radón en el interior de dos viviendas similares de construcción nueva en Madrid, una de ellas ocupada y la otra no, que forman parte del mismo edificio residencial. La concentración de radón y los parámetros ambientales (presión, temperatura y humedad) se midieron durante ocho meses. La monitorización del gas radón se realizó mediante detectores de estado sólido. Simultáneamente, se adquirieron algunas variables atmosféricas de un modelo atmosférico. En el análisis de los datos, se utilizó principalmente el método de la Transformada Wavelet. Los resultados muestran que el nivel de radón es ligeramente más alto en la vivienda ocupada que en la otra. A partir del análisis desarrollado en este estudio, se encontró que había un patrón específico estacional en la concentración de radón interior. Además, se analizó también la influencia antropogénica. Se pudieron observar patrones periódicos muy similares en intervalos concretos sin importar si la vivienda está ocupada o no. Por otra parte, los datos se almacenaron en cubos OLAP. El análisis se realizó usando unos algoritmos de agrupamiento (clustering) y de asociación. El objetivo es descubrir las relaciones entre el radón y las condiciones externas como la presión, estabilidad, etc. Además, la metodología aplicada puede ser útil para estudios ambientales en donde se mida radón en espacios interiores. ABSTRACT The present thesis studies the indoor radon variations in two similar new dwellings, one of them occupied and the other unoccupied, from the same residential building in Madrid. Radon concentration and ambient parameters were measured during eight months. Solid state detectors were used for the radon monitoring. Simultaneously, several atmospheric variables were acquired from an atmospheric model. In the data analysis, the Wavelet Transform Method was mainly used. The results show that radon level is slightly higher in the unoccupied dwelling than in the other one. From the analysis developed in this study, it is found that a specific seasonal pattern exists in the indoor radon concentration. Besides, the anthropogenic influence is also analysed. Nearly periodical patterns could be observed in specific periods whether dwelling is occupied or not. Otherwise, data were stored in cubes OLAP. Analysis was carried out using clustering and association algorithms. The aim is to find out the relationships among radon and external conditions like pressure, stability, etc. Besides, the methodology could be useful to assess environmental studies, where indoor radon is measured.

Lipid biomarkers in the Enol Lake (Asturias, Northern Spain): coupled natural and human induced environmental history

The lipid content of three cores from Lake Enol (Picos de Europa National Park, Asturias, Northern Spain) was studied. The n-alkane profiles indicated a major input from terrigenous plants [predominance of high molecular weight (HMW) alkanes] since ca. 1695 AD to the water body, although the uppermost cm revealed a predominance of organic matter (OM) derived from algae, as the most abundant alkane was C17. Three units revealing different environmental conditions were defined. Unit A (ca. 1695–1860 AD) in the lowermost parts of ENO13-10 (< 12 cm) and ENO13-15 (< 28 cm) was identified and was characterized by higher OM input and evidence of minimal degradation (high CPI values, predominance of HMW n-alkanoic acids and good correspondence between the predominant n-alkane and n-alkanoic acid chains). These findings could be linked to the Little Ice Age, when cold and humid conditions may have favored an increase in total organic carbon (TOC) and n-alkane and n-alkanoic acid content (greater terrigenous OM in-wash), and may have also reduced bacterial activity. In Unit B (ca. 1860–1980 AD) the lack of correspondence between the n-alkane and n-alkanoic acid profiles of ENO13-10 (12–4 cm) and ENO13-15 (28–8 cm) suggested a certain preferential microbial synthesis of long chain saturated fatty acids from primary OM and/or bacterial activity, coinciding with a decrease in OM input, which could be linked to the global warming that started in the second half of the 19th century. In ENO13-7 the low OM input (low TOC) was accompanied by some bacterial degradation (predominance ofHMWn-alkanoic acids but with a bimodal distribution) in the lowermost 16–5 cm. Evidence of considerable phytoplankton productivity and microbial activity was especially significant in Unit C (ca. 1980–2013 AD) identified in the uppermost part of all three cores (5 cm in ENO13-7, 4 cm in ENO13-10 and 8 cm in ENO13-15), coinciding with higher concentrations of n-alkanes and n-alkanoic acids, which were considered to be linked to warmer and drier conditions, as well as to greater anthropogenic influence in modern times. Plant sterols, such as b-sitosterol, campesterol and stigmasterol, were significantly present in the cores. In addition, fecal stanols, such as 24-ethylcoprostanol from herbivores, were present, thereby indicating a continuous and significant pollution input derived from these animals since the 17th century, being more important in the last 20 years.

Os efeitos das queimadas na Amazônia em nível celular e molecular

The Amazon holds over half of the planet's remaining tropical forests and comprises the largest biodiversity in the world, accounting for approximately 60 % of the Brazilian territory. However, deforestation fires in the region causes serious problems to exposed human. The aim of this study was to evaluate the chemical compounds as well as the cellular and molecular effects after exposure to organic material extracted from particulate matter less than 10 µm (PM10) in the Amazon region. As for the chemical composition, n-alkanes analysis showed a prevalence of anthropogenic influence during the fires in the region. In addition, there was a predominance of monosaccharides from biomass burning markers. Also, the Polycyclic Aromatic Hydrocarbons (PAH) and their derivatives have also been identified in samples collected in the Amazon. By using the PAH concentrations was possible to calculate the BaP-equivalent and it was found that the dibenz(a) anthracene contributes with 83% to potential carcinogenic risk. As for the potential mutagenic risk, the benzo (a) pyrene is the HPA that has a major contribution in this analysis. It may be noted that the retene was the most abundant PAH. This compound was genotoxic and cause death by necrosis in the human lung cells. In biological tests, the data showed that organic PM10 is capable of causing genetic damage in both plant cells and in human lung cells. This damage cause an arrest in the G1 phase of the cell cycle exposed, increasing the expression of p53 and p21. Additionally, the PM10 caused cell death by apoptosis, increasing the foci of histone - H2AX. Given these results, it is important to emphasize the reduction and better control of biomass burning in the Amazon region thus improving the quality of health of the population being exposed. As clearly stated recently by the World Health Organization, the reduction of air pollution could save millions of lives annually.

Composition of bottom sediments and interstitial waters from the Gdansk Bay

Contents of mercury and zinc in reduced sediments and interstitial waters of the Gdansk Bay in the Baltic Sea were investigated. It was found that sediments contain 0.7 ppm Hg, of which 0.008 ppm.(0.4% of total) is dissolved in interstitial water, and 91 ppm Zn, of which 0.15 ppm (0.45% of total) is dissolved in interstitial water. Differences in contents in different layers (0-5 and 25-30 cm) can be attributed to anthropogenic influence. Aderage concentration of mercury in the upper sediment layer is 27% higher and one of zinc is 40% higher than those found in the lower sediment layer. In addition, distribution of zinc in grain size fractions of the sediments was investigated, and some data on cadmium content were obtained.

TABLE 1. - Taxa list at Bahi'a Ushuaia and Bahi'a Golondrina

This paper describes the composition and abundance of mesozooplankton of Bahi'a Ushuaia and Bahi'a Golondrina. These small bays are located in the northern Beagle Channel. Sampling was carried out from January 20 to 23, 2001 and samples were collected from the upper layer at nine stations. This study is the first research on mesozooplankton in this part of the Beagle Channel. Due to their dominance in the mesozooplankton community, we compared our Copepoda data with those reported by other authors from Antarctic coastal environments. By applying cluster analysis, we found two station groups in both bays: one in slightly polluted zones and the other in undisturbed external zones. Four assemblages in Bahi'a Ushuaia and two in Bahi'a Golondrina were determined by using non-metric multidimensional scaling (MDS) and cluster analysis. Mesozooplanktonic assemblages showed a certain resemblance in zones with and without anthropogenic influence. Most of the copepod species in our samples are typical of the sub-Antarctic region. Oithona similis (=0. helgolandica sensu Ramirez, 1966), Oncaea curvata, and Ctenocahmus citer show either similar or higher abundances at Antarctic coastal sites, including the upper layer in oceanic areas, in comparison with sub-Antarctic coastal localities. This suggests that, in agreement with other findings, the Polar Front is probably not a major geographic boundary for the distribution of these species.

Sedimentology and geochemistry of surface sediments from the Pagassitikos Gulf

Volos city and its port are situated in the northern part of Pagassitikos Gulf, a shallow, semi-enclosed marine area in central Greece. A wastewater treatment plant (WWTP) and pipeline operate in the same area. Muddy sediments with low carbonate contents cover most of the seabed, except for the Volos embayment and the western part of the gulf where sandy carbonates prevail. Bulk organic carbon contents and the organic carbon contents of the clay fractions are high in the vicinity of Volos embayment. High element (Pb, Cu, and Zn) contents and Igeo (geoaccumulation index) values were found for the clay fractions in the northern part of Pagassitikos Gulf. This enrichment is attributed to the discharge of raw domestic and industrial effluents of Volos city and port before the WWTP was installed. The dispersal of pollutants is essentially controlled by diffusion from point sources (city, port and WWTP) and is limited to Volos Bay. Relatively high Mn levels are ascribed to diagenetic formation of manganese carbonates (authigenic phase), whereas Cr and Ni are elevated due to weathering of ultrabasic formations on land.

Molecular hydrogen (H2) mixing ratio and stable isotopic composition (dD) at the Cabauw tall tower in the Netherlands (2008-2012)

Measurements of the stable isotopic composition (dD(H2) or dD) of atmospheric molecular hydrogen (H2) are a useful addition to mixing ratio (X(H2)) measurements for understanding the atmospheric H2 cycle. dD datasets published so far consist mostly of observations at background locations. We complement these with observations from the Cabauw tall tower at the CESAR site, situated in a densely populated region of the Netherlands. Our measurements show a large anthropogenic influence on the local H2 cycle, with frequently occurring pollution events that are characterized by X(H2) values that reach up to 1 ppm and low dD values. An isotopic source signature analysis yields an apparent source signature below -400 per mil, which is much more D-depleted than the fossil fuel combustion source signature commonly used in H2 budget studies. Two diurnal cycles that were sampled at a suburban site near London also show a more D-depleted source signature (-340 per mil), though not as extremely depleted as at Cabauw. The source signature of the Northwest European vehicle fleet may have shifted to somewhat lower values due to changes in vehicle technology and driving conditions. Even so, the surprisingly depleted apparent source signature at Cabauw requires additional explanation; microbial H2 production seems the most likely cause. The Cabauw tower site also allowed us to sample vertical profiles. We found no decrease in (H2) at lower sampling levels (20 and 60m) with respect to higher sampling levels (120 and 200m). There was a significant shift to lower median dD values at the lower levels. This confirms the limited role of soil uptake around Cabauw, and again points to microbial H2 production during an extended growing season, as well as to possible differences in average fossil fuel combustion source signature between the different footprint areas of the sampling levels. So, although knowledge of the background cycle of H2 has improved over the last decade, surprising features come to light when a non-background location is studied, revealing remaining gaps in our understanding.

Hidrocarbonetos policíclicos aromáticos em sedimentos de fundo do estuário do rio Potengi, região da grande Natal (RN): implicações ambientais

Estuaries are environments prone to the input of chemical pollutants of various kinds and origins, including polycyclic aromatic hydrocarbons (PAHs). Anthropogenic PAHs may have two possible sources: pyrolytic (with four or more aromatic rings and low degree of alkylation) and petrogenic (with two and three aromatic rings and high degree of alkylation). This study aimed to evaluate the levels, distribution and possible sources of polycyclic aromatic hydrocarbons in the estuary of the Potengi river, Natal, Brazil. Samples of bottom sediments were collected in the final 12 km of the estuary until its mouth to the sea, where the urbanization of the Great Natal is more concentrated. Sampling was performed on 12 cross sections, with three stations each, totaling 36 samples, identified as T1 to T36. The non alkylated and alkylated PAHs were analyzed by gas chromatography coupled to mass spectrometry (GC / MS). PAHs were detected in all 36 stations with total concentration on each varying 174-109407 ng g-1. These values are comparable to those of several estuarine regions worldwide with high anthropogenic influence, suggesting the record of diffuse contamination installed in the estuary. PAHs profiles were similar for most stations. In 32 of the 36 stations, low molecular weight PAHs (with 2 and 3 ring: naphthalene, phenanthrene and their alkylated homologues) prevailed, which ranged from 54% to 100% of the total PAH, indicating that leaks, spills and combustion fuels are the dominant source of PAH pollution in the estuary. The level of contamination by PAHs in most stations suggests that there is potential risk of occasional adverse biological effects, but in some stations adverse impacts on the biota may occur frequently. The diagnostic ratios could differentiate sources of PAHs in sediments of the estuary, which were divided into three groups: petrogenic, pyrolytic and mixing of sources. The urban concentration of the Great Natal and the various industrial activities associated with it can be blamed as potential sources of PAHs in bottom sediments of the estuary studied. The data presented highlight the need to control the causes of existing pollution in the estuary

Free Troposphere Ozone and Carbon Monoxide over the North Atlantic for 2001-2011

Carbon Monoxide (CO) and Ozone (O3) are considered to be one of the most important atmospheric pollutants in the troposphere with both having significant effects on human health. Both are included in the U.S. E.P.A list of criteria pollutants. CO is primarily emitted in the source region whereas O3 can be formed near the source, during transport of the pollution plumes containing O3 precursors or in a receptor region as the plumes subside. The long chemical lifetimes of both CO and O3 enable them to be transported over long distances. This transport is important on continental scales as well, commonly referred to as inter-continental transport and affects the concentrations of both CO and O3 in downwind receptor regions, thereby having significant implications for their air quality standards. Over the period 2001-2011, there have been decreases in the anthropogenic emissions of CO and NOx in North America and Europe whereas the emissions over Asia have increased. How these emission trends have affected concentrations at remote sites located downwind of these continents is an important question. The PICO-NARE observatory located on the Pico Mountain in Azores, Portugal is frequently impacted by North American pollution outflow (both anthropogenic and biomass burning) and is a unique site to investigate long range transport from North America. This study uses in-situ observations of CO and O3 for the period 2001-2011 at PICO-NARE coupled with output from the full chemistry (with normal and fixed anthropogenic emissions) and tagged CO simulations in GEOS-Chem, a global 3-D chemical transport model of atmospheric composition driven by meteorological input from the Goddard Earth Observing System (GEOS) of the NASA Global Modeling and Assimilation Office, to determine and interpret the trends in CO and O3 concentrations over the past decade. These trends would be useful in ascertaining the impacts emission reductions in the United States have had over Pico and in general over the North Atlantic. A regression model with sinusoidal functions and a linear trend term was fit to the in-situ observations and the GEOS-Chem output for CO and O3 at Pico respectively. The regression model yielded decreasing trends for CO and O3 with the observations (-0.314 ppbv/year & -0.208 ppbv/year respectively) and the full chemistry simulation with normal emissions (-0.343 ppbv/year & -0.526 ppbv/year respectively). Based on analysis of the results from the full chemistry simulation with fixed anthropogenic emissions and the tagged CO simulation it was concluded that the decreasing trends in CO were a consequence of the anthropogenic emission changes in regions such as USA and Asia. The emission reductions in USA are countered by Asian increases but the former have a greater impact resulting in decreasing trends for CO at PICO-NARE. For O3 however, it is the increase in water vapor content (which increases O3 destruction) along the pathways of transport from North America to PICO-NARE as well as around the site that has resulted in decreasing trends over this period. This decrease is offset by increase in O3 concentrations due to anthropogenic influence which could be due to increasing Asian emissions of O3 precursors as these emissions have decreased over the US. However, the anthropogenic influence does not change the final direction of the trend. It can thus be concluded that CO and O3 concentrations at PICO-NARE have decreased over 2001-2011.