Total organic carbon, delta13C, biomarker, diatom distributions in sediment core JM11-FI-19PC

In the light of rapidly diminishing sea ice cover in the Arctic during the present atmospheric warming, it is imperative to study the distribution of sea ice in the past in relation to rapid climate change. Here we focus on glacial millennial scale climatic events (Dansgaard/Oeschger events) using the new sea ice proxy IP25 in combination with phytoplankton proxy data and quantification of diatom species in a record from the SE Norwegian Sea. We demonstrate that expansion and retreat of sea ice varied consistently in pace with the rapid climate changes 90 ka to present, and with this present the first IP25 sea ice proxy record resolving the D/O cyclicity going back in time into Marine Isotope Stage 5a. Sea ice retreated abruptly at the start of warm interstadials, but spread rapidly during the cooling phase of the interstadials and became near-perennial and perennial during cold stadials and Heinrich events, respectively. Low salinity surface water and the sea ice edge spread to the Greenland-Scotland Ridge, and during the largest Heinrich events, probably far into the Atlantic Ocean.

Sedimentology, organic geochemistry, and stable isotopes of core PS2138-1

We studied variations in terrigenous (TOM) and marine organic matter (MOM) input in a sediment core on the northern Barents Sea margin over the last 30 ka. Using a multiproxy approach, we reconstructed processes controlling organic carbon deposition and investigated their paleoceanographic significance in the North Atlantic-Arctic Gateways. Variations in paleo-surface-water productivity are not documented in amount and composition of organic carbon. The highest level of MOM was deposited during 25-23 ka as a result of scavenging on fine-grained, reworked, and TOM-rich material released by the retreating Svalbard/Barents Sea ice sheet during the late Weichselian. A second peak of MOM is preserved because of sorptive protection by detrital and terrigenous organic matter, higher surface-water productivity due to permanent intrusion of Atlantic water, and high suspension load release by melting sea ice during 15.9-11.2 ka.

Age determinations, biomarker analyses, and accumulation rates of three sediment cores from the Fram Strait

A reconstruction of Holocene sea ice conditions in the Fram Strait provides insight into the palaeoenvironmental and palaeoceanographic development of this climate sensitive area during the past 8,500 years BP. Organic geochemical analyses of sediment cores from eastern and western Fram Strait enable the identification of variations in the ice coverage that can be linked to changes in the oceanic (and atmospheric) circulation system. By means of the sea ice proxy IP25, phytoplankton derived biomarkers and ice rafted detritus (IRD) increasing sea ice occurrences are traced along the western continental margin of Spitsbergen throughout the Holocene, which supports previous palaeoenvironmental reconstructions that document a general cooling. A further significant ice advance during the Neoglacial is accompanied by distinct sea ice fluctuations, which point to short-term perturbations in either the Atlantic Water advection or Arctic Water outflow at this site. At the continental shelf of East Greenland, the general Holocene cooling, however, seems to be less pronounced and sea ice conditions remained rather stable. Here, a major Neoglacial increase in sea ice coverage did not occur before 1,000 years BP. Phytoplankton-IP25 indices ("PIP25-Index") are used for more explicit sea ice estimates and display a Mid Holocene shift from a minor sea ice coverage to stable ice margin conditions in eastern Fram Strait, while the inner East Greenland shelf experienced less severe to marginal sea ice occurrences throughout the entire Holocene.

Age determination of sediment cores off western Spitsbergen

The Late Weichselian glacial history of the continental shelf off western Spitsbergen is discussed, based on acoustic sub-bottom records and sediment cores. The outer part of Isfjorden and the inner shelf to the west of this fjord are characterized by a thin veneer (10-20 m) of glacigenic sediments and absence of ice-marginal features. Towards the outer shelf the sediment thickness increases significantly, and exceeds 500 m at the shelf edge. Possible moraine complexes were identified in this outer part. Sediment cores from the inner shelf sampled a firm diamicton, interpreted as till, beneath soft glaciomarine sediments. Radiocarbon dates on shells from the clay resting directly on the till, suggest an age of around 12,500 yrs B.P. for the base of the marine sequence. We argue that grounded ice covered the sites shortly before. In contrast to suggestions that the fjords and coast were partly ice free during the Late Weischselian, we conclude that the ice must have reached out onto the continental shelf.

Age determination of sediment cores from the western Svalbard margin

The deglaciation of the continental shelf to the west of Spitsbergen and the main fjord, Isfjorden, is discussed based on sub-bottom seismic records and sediment cores. The sea floor on the shelf to the west of Isfjorden is underlain by less than 2 m of glaciomarine sediments over a firm diamicton interpreted as till. In central Isfjorden up to 10 m of deglaciation sediments were recorded, whereas in cores from the innermost tributary, Billefjorden, less than a meter of ice proximal sediments was recognized between the till and the 'normal' Holocene marine sediments. We conclude that the Barents Sea Ice Sheet terminated along the shelf break during the Late Weichselian glacial maximum. Radiocarbon dates from the glaciomarine sediments above the till indicate a stepwise deglaciation. Apparently the ice front retreated from the outermost shelf around 14.8 ka. A dramatic increase in the flux of line-grained glaciomarine sediments around 13 ka is assumed to reflect increased melting and/or current activity due to a climatic warming. This second stage of deglaciation was interrupted by a glacial readvance culminating on the mid-shelf area shortly after 12.4 ka. The glacial readvance, which is correlated with a simultaneous readvance of the Fennoscandian ice sheet along the western coast of Norway, is attributed to the so-called 'Older Dryas' cooling event in the North Atlantic region. Following this glacial readvance the outer part of Isfjorden became rapidly deglaciated around 12.3 ka. During the Younger Dryas the inner fjord branches were occupied by large outlet glaciers and possibly the ice front terminated far out in the main fjord. The remnants of the Barents Sea Ice Sheet melted quickly away as a response to the Holocene warming around 10 ka.

Biomarker distributions and calculated sea surface temperatures from the North Pacific Ocean

In order to study the modern sea surface characteristics of the sub-polar North Pacific and the Bering Sea, i.e. sea surface temperature (SST) and sea ice cover, surface sediments recovered during the RV Sonne Expedition 202 in 2009 were analysed. To distinguish between marine and terrestrial organic carbon, hydrogen index values, long chain n-alkanes and specific sterols have been determined. The results show that in the Bering Sea, especially on the sea slope, the organic carbon source is mainly caused by high primary production. In the North Pacific, on the other hand, the organic material originates predominantly from terrestrial higher plants, probably related to dust input from Asia. SST has been reconstructed using the modified alkenone unsaturation index. Calibration from Müller et al. (1998, doi:10.1016/S0016-7037(98)00097-0) offers the most reliable estimate of mean annual temperature in the central North Pacific but does not correlate with mean annual temperature throughout the study area. In the eastern North Pacific and the Bering Sea, the Sikes et al. (1997, doi:10.1016/S0016-7037(97)00017-3) calibration seems to be more accurate and matches summer SST. The distribution of the novel sea ice proxy IP25 (highly branched C25 isoprenoid alkene) in surface sediments is in accord with the modern spring sea ice edge and shows the potential of this proxy to track past variation in sea ice cover in the study area.