Piano Crafts Department

Students are shown working on pianos in various states of construction in the Piano Crafts Department at the New York Trade School. Black and white photograph.

Students working in Piano Crafts Department

Three students are shown working in the Piano Crafts Department at the New York Trade School. The two students in the foreground appear to be working on the construction of a piano. Black and white photograph.

Professor and Student in Piano Crafts Department

Here a professor in the Piano Crafts Department at the New York Trade School is shown helping a student. Black and white photograph.

Learning from history : social movements, arts and crafts and anti-consumption

Contemplating the lCAR Agenda, I wondered what value was to be found in history and is historical research an appropriate methodology for this contemporary discussion? I reviewed articles from social sciences and marketing literature that discuss history as a research methodology and present some of the criticisms and benefits. Social movements like the Arts and Crafts contain themes and agendas that resonate today, including protest and boycott, sustainable solutions, and technophobia that can be found in contemporary crafts movements like Stitch'nBitch. Researchers, heeding some cautions, can use history to build agendas that contribute directly to the study of anti consumption

Crafts and successful aging: the Découpage Guild Australia

Facile fabrication of polyolefin/carbon nanotube composites via in situ friedel-crafts polyalkylation : structure and properties

Despite major advances in addressing the dispersion of carbon nanotubes (CNTs) in polymers and their interfacial interactions, exploring a facile approach for massively creating them is still fascinating. We interestingly find that the CNT dispersion is considerably improved in polypropylene (PP), and ?19.1 wt % of PP chains were in situ chemically grafted onto CNT surfaces only using a trace of AlCl3 via a one-step melt-blending. Compared with the PP/CNT composite, adding 0.2 wt % of AlCl3 enables an increase in tensile strength and Young's modulus of 30% and 25%, respectively. Moreover, the elongation at break is almost maintained, while adding CNTs alone causes significant decreases. Additionally, 0.2 wt % AlCl3 makes the thermal degradation temperature further improved. These remarkable improvements in properties are mainly attributed to better dispersion of CNTs and enhanced interfacial compatibility. This work opens up an innovative approach for scalable preparation of polyolefin/CNT composites applying to industrial production.

Sintesi enantioselettiva di atropisomeri non-biarilici via organocatalisi: alchilazione di Friedel-Crafts asimmetrica tra indenoni 4-sostituiti e β-naftoli

La reazione di Friedel-Crafts (F-C) rappresenta una delle più importanti e potenti vie per generare un nuovo legame C-C tra un sistema aromatico elettron-ricco e un appropriato elettrofilo. Durante gli ultimi anni l’organocatalisi si è dimostrata essere un’appropriata strategia per realizzare questa importante trasformazione in maniera enantioselettiva. Per quanto riguarda l’amminocatalisi, la reazione di F-C è stata insistentemente studiata su aldeidi α,β-insature utilizzando ammine secondarie chirali, ma ammine primarie basate sulla struttura degli alcaloidi della cincona sono catalizzatori privilegiati per l’attivazione di chetoni. In questa tesi, viene descritto lo sviluppo di un’alchilazione di F-C asimmetrica di appropriati indenoni attraverso la strategia per ione imminio. Opportuni naftoli sono stati utilizzati come nucleofili per ottenere con buone rese e stereocontrollo composti con possibili attività biologiche.

An approach to an intramolecular organocatalysed asymmetric Friedel-Crafts reaction

An intramolecular and asymmetric Friedel-Crafts alkylation of chalcones, exploiting mostly organocatalysts, in order to simultaneously obtain a new chiral center and a chiral axis.