Ordinary and duplicate analysis from major and trace elements of ODP Holes 146-888B and 168-1027B

Oceanic sediments deposited at high rate close to continents are dominated by terrigenous material. Aside from dilution by biogenic components, their chemical compositions reflect those of nearby continental masses. This study focuses on oceanic sediments coming from the juvenile Canadian Cordillera and highlights systematic differences between detritus deriving from juvenile crust and detritus from old and mature crust. We report major and trace element concentrations for 68 sediments from the northernmost part of the Cascade forearc, drilled at ODP Sites 888 and 1027. The calculated weighted averages for each site can then be used in the future to quantify the contribution of subducted sediments to Cascades volcanism. The two sites have similar compositions but Site 888, located closer to the continent, has higher sandy turbidite contents and displays higher bulk SiO2/Al2O3 with lower bulk Nb/Zr, attributed to the presence of zircons in the coarse sands. Comparison with published data for other oceanic sedimentary piles demonstrates the existence of systematic differences between modern sediments deriving from juvenile terranes (juvenile sediments) and modern sediments derived from mature continental areas (cratonic sediments). The most striking systematic difference is for Th/Nb, Th/U, Nb/U and Th/Rb ratios: juvenile sediments have much lower ratios than cratonic sediments. The small enrichment of Th over Nb in cratonic sediments may be explained by intracrustal magmatic and metamorphic differentiation processes. In contrast, their elevated Th/U and Nb/U ratios (average values of 6.87 and 7.95, respectively) in comparison to juvenile sediments (Th/U ~ 3.09, Nb/U ~ 5.15) suggest extensive U and Rb losses on old cratons. Uranium and Rb losses are attributed to long-term leaching by rain and river water during exposure of the continental crust at the surface. Over geological times, the weathering effects create a slow but systematic increase of Th/U with exposure time.

Chemical composition of basalts and andesites from the Sea of Japan

An investigation of uranium and thorium contents in extrusive rocks from underwater rises in the Sea of Japan demonstrates that concentrations of these radioactive elements can be used as indicators of geodynamic conditions. It is concluded that basalt volcanism of the Sea of Japan is of continental type.

Composition of Carnian to Norian sandstones from the Wombat Plateau (Table 1)

The Carnian to Norian sediments, as much as 600 m in total thickness, recovered from ODP Sites 759 and 760 on the Wombat Plateau, are generally represented by fluvial-dominated deltaic successions. In general, the Carnian to Norian sandstones are quartzose. The average ratio of monocrystalline quartz grains, total feldspar grains, and total lithic fragments (i.e., Qm:F:Lt ratio) is 71:22:7. This indicates that they were derived mainly from the transitional continental and cratonic interior provenance terranes, such as the Pilbara Precambrian block to the south of the Wombat Plateau. The upper Carnian sediments, however, are characterized by more feldspathic sandstone petrofacies. They typically contain some volcanic rock fragments with trachytic texture and indicate the onset of the incipient rift-related tectonic movement, such as uplift and subsequent abrupt basin subsidence, together with volcanism in the Gondwana continental block. Mixed siliciclastic and carbonate cycles are typically intercalated in the prodelta to delta front deposits that developed mainly in a lagoon-like, restricted marine environment. The restricted marine environment developed during transgressions as the outflow of shallow water was restricted by depositional barriers. Around the barriers and/or delta lobes, carbonate shoals/banks were probably developed and the allochemical components of the neritic limestones may have been transported into the restricted marine environment by overwash processes and/or storm waves. Siliciclastic detritus, on the other hand, was mainly derived accompanied by delta progradation dominated by fluvial processes in the restricted marine environment. Therefore, we interpret the mixed siliciclastic and carbonate cycles in the deltaic successions to be a result of transgression-regression cycles in a deltaic system during the Late Triassic.

Geochemistry of ODP Sites 128-798 and 128-799 sediments

Nineteen trace elements, including seven rare earth elements (REE's), and 10 major and minor elements in 76 sediment samples from Sites 798 (Oki Ridge) and 799 (Yamato Trough) were determined by means of instrumental neutron activation analysis and X-ray fluorescence spectrometry. Most REE patterns (chondrite-normalized) of the sediments from both sites were nearly identical to the patterns of terrigenous materials. The cerium anomaly (slightly positive) frequently appeared in REE patterns of the sediments (200-750 mbsf) from Site 799. Cerium may be selectively incorporated into the sediments with hydrogenous manganese precipitation. However, the degree of the anomaly was not well correlated with manganese content, suggesting that cerium may behave as a trivalent REE (like the other REE's) during diagenesis while manganese is transported in the sediment column accompanied by reduction to a lower oxidation state. The Th/Sc ratio of the sediments from Sites 798 and 799 tended to decrease with penetration depth. Such a depth profile may indicate a decrease in basic volcanism activities from the Pliocene (Site 798) and Miocene (Site 799). The La/Yb ratio and degree of europium anomaly also varied with depth, which may imply that two or more components with different REE patterns were supplied throughout sedimentation at sites in the Japan Sea.

Chemical and isotopic compositions of lavas from the Broken Ridge and Southern Kerguelen Plateau

Lavas from several major bathymetric highs in the eastern Indian Ocean that are likely to have formed as Early to Middle Cretaceous manifestations of the Kerguelen hotspot are predominantly tholeiitic; so too are glass shards from Eocene to Paleocene volcanic ash layers on Broken Ridge, which are believed to have come from eruptions on the Ninetyeast Ridge. The early dominance of tholeiitic compositions contrasts with the more recent intraplate, alkalic volcanism of the Kerguelen Archipelago. Isotopic and incompatible-element ratios of the plateau lavas are distinct from those of Indian mid-ocean ridge basalts; their Nd, Sr, 207Pb/204Pb and 2078b/204Pb isotopic ratios overlap with but cover a much wider range than measured for more recent oceanic products of the Kerguelen hotspot (including the Ninetyeast Ridge) or, indeed, oceanic lavas from any other hotspot in the world. Samples from the Naturaliste Plateau and ODP Site 738 on the southern tip of the Kerguelen Plateau are particularly noteworthy, with e-Nd(T) = -13 to -7, (87Sr/86Sr)T=0.7090 to 0.7130 and high 207Pb/204Pb relative to 206Pb/204Pb. In addition, the low-e-Nd(T) Naturaliste Plateau samples are elevated in SiO2 (>54 wt%). In contrast to "DUPAL" oceanic islands such as the Kerguelen Archipelago, Pitcairn and Tristan da Cunha, the plateau lavas with extreme isotopic characteristics also have relative depletions in Nb and Ta (e.g., Th/Ta, La Nb > primitive mantle values); the lowest e-Nd(T) and highest Th/Ta and La Nb values occur at sites located closest to rifted continental margins. Accepting a Kerguelen plume origin for the plateau lavas, these characteristics probably reflect the shallow-level incorporation of continental lithosphere in either the head of the early Kerguelen plume or in plume-derived magmas, and suggest that the influence of such material diminished after the period of plateau construction. Contamination of asthenosphere with the type of material affecting Naturaliste Plateau and Site 738 magmatism appears unlikely to be the cause of low-206Pb/204Pb Indian mid-ocean ridge basalts. Finally, because isotopic data for the plateaus do not cluster or form converging arrays in isotope-ratio plots, they provide no evidence for either a quickly evolving, positive ?Nd, relatively high-206Pb/204Pb plume composition, or a plume source dominated by mantle with e-Nd of -3 to ~0.

Neptunian dikes and their fillings in carbonates of the Warstein area (northeastern Rhenish massif)

Neptunian dikes and cavities as weil as their fillings are described from Middle to Upper Devonian carbonates of the Warstein area. The genesis of the pre-Upper Carboniferous dikes is due to pre-orogenic synsedimentary tensional movements. Lifting, subsidence and tilting caused joints and cracks, which are enlarged to dikes and cavities on submarine conditions. The post-Upper Carboniferous dikes are based on the orogenesis during Upper Carboniferous time, causing numerous tectonical divisional planes in the sediments. Along these planes a far-reaching karstification took place since mesozoic time. According to their size the cavities are subdivided into macro-, mega- and microdikes. With the exception of one macrodike all the others are limited to the massive limestone. Megadikes especially occur in Upper Devonian cephalopod limestone and in the Erdbach limestone, microdikes can be found in all carbonatic rocks. The dikes follow pre-orogenic, tectonical and sedimentary divisional planes and are orientated to ac-, bc- as well as bedding planes and diagonal directions. The fillings happened down from above either in a solitary event or repeatedly in long-lived dikes during a span of several ten millions of years. More seldom the fillings took place laterally or upside from beneath. The dikes contain - without regard to autochthonous conodont faunas - older and/or younger mixed faunas, too. Occasionally they were used as life district by a trilobite fauna adapted to the dikes. The dikes represent sedimentary pitfalls and conserve sediments eroded in other places. Therefore, by aid of the fillings, it can be demonstrated, that stratigraphic gaps are not absolutely due to primary interruptions of sedimentation, but were caused by reworking. Some dikes contain the distal offsets of slides and suspension streams. Relations between condensation and development of dikes could not be derived in the Warstein area. However, an increase of the frequency of dikes towards east to the eastern margin of the Warstein carbonate platform could be pointed out. This margin is a slope, persisting more than 10 millions of years, between a block and a basin. Evidently cracks and dikes, which were caused by settlements, slides and earth quakes, occured there frequently. The Warstein dikes and cavities, caused by karstification, are filled with terrestrial Lower Cretaceous, marine Upper Cretaceous and terrestrial Pleistocene to Holocene sediments. Tertiary sediments could not be detected.

Chemical composition of bottom sediments at DSDP Sites 91-595 and 91-596 and ODP Sites 114-701 and 129-801

Subducted sediments play an important role in arc magmatism and crust-mantle recycling. Models of continental growth, continental composition, convergent margin magmatism and mantle heterogeneity all require a better understanding of the mass and chemical fluxes associated with subducting sediments. We have evaluated subducting sediments on a global basis in order to better define their chemical systematics and to determine both regional and global average compositions. We then use these compositions to assess the importance of sediments to arc volcanism and crust-mantle recycling, and to re-evaluate the chemical composition of the continental crust. The large variations in the chemical composition of marine sediments are for the most part linked to the main lithological constituents. The alkali elements (K, Rb and Cs) and high field strength elements (Ti, Nb, Hf, Zr) are closely linked to the detrital phase in marine sediments; Th is largely detrital but may be enriched in the hydrogenous Fe-Mn component of sediments; REE patterns are largely continental, but abundances are closely linked to fish debris phosphate; U is mostly detrital, but also dependent on the supply and burial rate of organic matter; Ba is linked to both biogenic barite and hydrothermal components; Sr is linked to carbonate phases. Thus, the important geochemical tracers follow the lithology of the sediments. Sediment lithologies are controlled in turn by a small number of factors: proximity of detrital sources (volcanic and continental); biological productivity and preservation of carbonate and opal; and sedimentation rate. Because of the link with lithology and the wealth of lithological data routinely collected for ODP and DSDP drill cores, bulk geochemical averages can be calculated to better than 30% for most elements from fewer than ten chemical analyses for a typical drill core (100-1000 m). Combining the geochemical systematics with convergence rate and other parameters permits calculation of regional compositional fluxes for subducting sediment. These regional fluxes can be compared to the compositions of arc volcanics to asses the importance of sediment subduction to arc volcanism. For the 70% of the trenches worldwide where estimates can be made, the regional fluxes also provide the basis for a global subducting sediment (GLOSS) composition and flux. GLOSS is dominated by terrigenous material (76 wt% terrigenous, 7 wt% calcium carbonate, 10 wt% opal, 7 wt% mineral-bound H2O+), and therefore similar to upper continental crust (UCC) in composition. Exceptions include enrichment in Ba, Mn and the middle and heavy REE, and depletions in detrital elements diluted by biogenic material (alkalis, Th, Zr, Hf). Sr and Pb are identical in GLOSS and UCC as a result of a balance between dilution and enrichment by marine phases. GLOSS and the systematics of marine sediments provide an independent approach to the composition of the upper continental crust for detrital elements. Significant discrepancies of up to a factor of two exist between the marine sediment data and current upper crustal estimates for Cs, Nb, Ta and Ti. Suggested revisions to UCC include Cs (7.3 ppm), Nb (13.7 ppm), Ta (0.96 ppm) and TiO2 (0.76 wt%). These revisions affect recent bulk continental crust estimates for La/Nb and U/Nb, and lead to an even greater contrast between the continents and mantle for these important trace element ratios. GLOSS and the regional sediment data also provide new insights into the mantle sources of oceanic basalts. The classical geochemical distinction between 'pelagic' and 'terrigenous' sediment sources is not valid and needs to be replaced by a more comprehensive understanding of the compositional variations in complete sedimentary columns. In addition, isotopic arguments based on surface sediments alone can lead to erroneous conclusions. Specifically, the Nd/Hf ratio of GLOSS relaxes considerably the severe constraints on the amount of sediment recycling into the mantle based on earlier estimates from surface sediment compositions.

Paleomagnetic of basalts from ODP Site 145-883 on Detroit Seamount

Paleomagnetic data were measured from basaltic flows cored by the Ocean Drilling Program (ODP) at Site 883 on the summit of Detroit Seamount, located in the northernmost Emperor seamounts. These data are important because they reflect the paleolatitude of Hawaiian volcanism for the Late Cretaceous and bear upon geodynamic models of hotspot drift. A total of 143 samples were measured, from cores acquired at two ~20-30 m apart. Most samples gave apparently reliable magnetic directions that were analyzed in a tiered fashion to compute a composite inclination vs. depth curve. One hole gave 13 distinct inclination groups, the other 10, and the two were combined into nine groups thought to represent independent measurements of paleofield direction. These data indicate normal magnetic polarity and give a mean inclination of 61.5+10.6°/-6.4° and paleolatitude of 42.8+13.2°/-7.6° (95% confidence limits). This paleolatitude is 6.2° higher than results from another ODP site (884) drilled on the lower flank of the same seamount. The difference is thought to result partly from an age difference (1-3 Myr) and partly from incomplete averaging of paleosecular variation at both drill sites. Together, the data from the two sites reinforce the conclusion that the northern Emperor seamounts were formed far north of the present-day hotspot latitude (~19.5°N) and suggest prior estimates of the amount and rate of southward drift may have been low. This analysis also illustrates uncertainties in determining paleolatitude from a small number of lava flow units from a single drill site.

Tab. 1 Analyses of major phases in Vestgötabreen formation schists

The glaucophane schists of Oscar II Land, it has been suggested, originated in a compressive plate boundary subduction zone environment. An alternative hypothesis is presented here linking the metamorphism of these schists with that of the surrounding pre-Carboniferous rocks. It has been estimated from mineralogical and textural relationships that at the time of metamorphism these rocks exceeded 30 km in thickness. Similarly, an ambient geothermal gradient of 15° C/km has been calculated for the now exposed succession. Pressures of sufficient magnitude would be realised near the base of this geosynclinal pile to produce eclogite from rocks of basic composition. Subsequent synmetamorphic penetrative deformation would give rise to glaucophane and greenschist facies assemblages.