Alternativas de ultimação de resíduo plástico termofixo

In the present work it was developed originals alternatives of enveronmentally safe and economically viable destination of thermoset plastic residue from a button factory, which at presnte stores such residue tempor and in a way that is inconvenient to the atmosphere, a waiting safe solutions. As the residue is not recycleab and its burning leberates strongly aggressive gases, safe alternatives were researched. Inicially, ghe residue in incineration was performed in cement ovens with precise control ofe emission of gases, but it was proved inviable due to its low calorific power, as well as the liberation of free lead in the ashes. An original and feasible option was the residue confinemente in soil-ciment blocks, lohich resulted in blocks highly resistant to simple compression with structural block, and also a significant increase in thermal resistence. Was got up other options of original and important composites as: making of blocks for pré-moulded flagstone, internal coating of walls with plaster being obtained good texture results, replenish of ceramic blocks and blocks with cement, also implying in increase of thermal resistance. Besides these original and scientific contributions, the it was technologically contribution of defreadation with suggestions of the material using torch of thermal plasm; for this was projected, built, characterized and tested a torch to it shapes it being obtained exciting results for the development of this technology come back for ending destruction from all the types of inconvenient garbage to the atmosphere

Aproveitamento de resíduo de beneficiamento do caulim na produção de porcelanato cerâmico

Nowadays, industries from all sectors have great concerns over the disposition of the residues generated along the productive process. This is not different in the mineral sector, as this generates great volumes of residues. It was verified that the kaolin improvement industry generates great volumes of residue basically constituted of kaolinite, muscovite mica and quartz, which are basic constitution elements to formularisations of ceramics masses to the production of covering of stoneware tiles type. This happens because the methodology applied to the improvement process is still very rudimentary, what causes a very low yield, only ¼ from all the material volume that enters the improvement process, in the end, is marketable. The disposal of this residue, in a general way, causes a very big negative environmental impact, what has justified the researches efforts aiming to find a rational solution to this problem. In this way, the intention of this present work is the utilization of this residue in the manufacture of products to high quality ceramics covering, stoneware tiles in an industrial scale. For this purpose, the influence of the addition of the residue to a standard ceramics mass used by a ceramics sector company, already established in the market, with the intention of verifying the possibility of use of this residue as the mass complementary raw material and even the possible partial or total substitution of one of the components of the mass for the raw material in evidence will be studied. To the accomplishment of this work, the kaolin improvement residue generated by an industry of exploitation and improvement of kaolin, located in the region of Equador-RN, in the levels 1,2,4,8, 16 and 32% will be added to the standard mass already used for the production of stoneware tiles. The raw materials used, kaolin residue and the standard mass, were characterized through DRX, FRX, DTA, TGA and dilatometry. After the sintering of the bodies of test, tests of water absorption, apparent porosity, post burning linear retraction, apparent specific mass and flexural strength (3 point bending) were realized to determinate the technological properties of these materials. The results show the studied residue can be considered raw material of great potential to the industry of floor and ceramics covering of the stoneware tiles type

Sinterização de matrizes cerâmicas à base de alumina reforçadas por carbetos a partir de precursores poliméricos

Ceramic composites produced with polymerics precursors have been studied for many years, due to the facility of obtaining a complex shape, at low temperature and reduces cost. The main objective of this work is to study the process of sintering of composites of ceramic base consisting of Al2O3 and silicates, reinforced for NbC, through the technique of processing AFCOP, as well as the influence of the addition of LZSA, ICZ and Al as materials infiltration in the physical and mechanical properties of the ceramic composite. Were produced ceramic matrix composites based SiCxOy e Al2O3 reinforced with NbC, by hidrosilylation reaction between D4Vi and D1107 mixtured with Al2O3 as inert filler, Nb and Al as reactive filler. The specimens produced were pyrolised at 1200, 1250 and 1400°C and infiltred with Al, ICZ and LZSA, respectively. Density, porosity, flexural mechanical strength and fracture surface by scanning electron microscopy were evaluated. The microstructure of the composites was investigated by X-ray diffraction to identify the presence of crystalline phases. The composites presented apparent porosity varying of 31 up to 49% and mechanical flexural strength of 14 up to 34 MPa. The infiltration process improviment of the densification and reduction of the porosity, as well as increased the values of mechanical flexural strength. The obtained phases had been identified as being Al3Nb, NbSi2, Nb5S3, Nb3Si and NbC. The samples that were submitted the infiltration process presented a layer next surface with reduced pores number in relation to the total volume

Implementación del método de aprendizaje basado en Proyectos en asignaturas de Ingeniería de Fabricación de los Grados de la Universidad de Málaga

El presente trabajo de innovación educativa pretende desarrollar las capacidades y competencias de los alumnos mediante la aplicación de un Proyecto que potencia el aprendizaje cooperativo. El alumno verá enriquecido su dominio de la disciplina a través de una coherente aplicación de los conocimientos adquiridos en una primera parte teórica de la asignatura. La interacción directa con otros alumnos, la exigibilidad individual, la reflexión sobre el funcionamiento del grupo y el desarrollo de las habilidades interpersonales son la base del aprendizaje cooperativo y la implementación del presente proyecto posibilita reducir las carencias que en estos aspectos muestra el alumnado universitario. El Proyecto puede ser denominado por el siguiente titular: ¿CÓMO SE FABRICA Y CÓMO FUNCIONA? En cada curso académico el Área de Ingeniería de Procesos de Fabricación (IPF) adquirirá un conjunto mecánico de complejidad media (p. e. cortasetos) que esté compuesto de un número adecuado de piezas fabricadas con distintos materiales (metal, polímeros, cerámicos, compuestos) y mediante diferentes procesos de fabricación (fundición, mecanizado, soldadura, deformación plástica, etc.). El proyecto partirá de una inicial descomposición por explosion de la totalidad de las piezas que forman el conjunto. Un posterior análisis establecerá las relaciones funcionales de los diferentes componentes y la naturaleza del material de cada uno de ellos, así como de las posibles alternativas a emplear en su fabricación.

[Texto del convenio de colaboración suscrito entre Artesanías de Colombia S. A. y la asociación de productores de mimbre de Ibagué – ASPROMI].

32 documentos : ilustraciones, fotografías.

Technological characterization of molded islamic pottery from Iberian Peninsula

The thesis examines the technical aspects of unglazed molded ceramics from Mértola, in the context of Islamic archaeology of the Iberian Peninsula (Almohad period, end of 12th and the beginning of 13th century). Ceramics of the time period under discussion (12th – 13th century) are understudied, including in what concern to shaping and firing of ceramic vessels, the origin of raw materials used in ceramics and glazes, and decoration methods such as slip painting and/or colored glazes. Moreover, the use of archaeometry tools is rare. Along with providing a general picture of molded ceramic production in Mértola, this work provides a new dimension to the discipline of Islamic ceramic studies by the analytical tool used and demonstrating the importance of archaeological ceramics of the western peripheries to the understanding the production of ceramics and the transmission of knowledge and cultural traditions within the Islamic caliphate. The chemical and mineralogical characterization of 12th/13th century Almohad unglazed molded ware from Mértola was accomplished through multi – analytical approach combining SEM, Powder/uXRD and LA-ICP-MS methods. In this paper unglazed and glazed samples were analyzed but the attention was given to unglazed specimens, while the glazed samples were used for the comparison with the previous group in order to determine possible similarities or dissimilarities, thus providing enough data to discuss about technical aspects and potential provenance; Resumo: A tese debruça-se sobre os aspetos técnicos de cerâmica de molde não-vidrada de Mértola, no contexto da arqueologia islâmica da Península Ibérica (período Almóada, final de XII e início do século XIII). A cerâmica do período em discussão (séculos XII-XIII) é pouco estudada inclusive no que concerne ao fabrico e à cozedura, à de fonte de matérias-primas, na pasta ou nos esmaltes e aos métodos de decoração, como pintura, presença de engobes ou esmaltes. Além disso, o uso de ferramentas de Arqueometria é raro. Para fornecer uma visão geral da produção de cerâmica moldada em Mértola, este trabalho oferece uma nova dimensão para a disciplina de cerâmica islâmicas pelas ferramentas analíticas utilizadas. Demonstrando a importância da cerâmica arqueológica da periferia ocidental para a compreensão da produção cerâmica e a transmissão de conhecimentos e tradições culturais no califado islâmico. A caracterização mineralógica e química das cerâmicas de molde e não-vidrada, Almóada, dos séculos XII-XIII de Mértola foi realizada através de uma abordagem multi-analítica que combina métodos de SEM-EDS, uXRD e LA-ICP-MS. Neste trabalho, as cerâmicas vidradas e não-vidradas foram analisadas conjuntamente, dando mais atenção aos espécimes não vidrados. As amostras de cerâmicas vidradas foram utilizados para a comparação com o grupo anterior, a fim de determinar as possíveis semelhanças ou diferenças, proporcionando, assim, dados suficientes para discutir os aspetos técnicos e o potencial de proveniência das cerâmicas não vidradas