Next generation robotic counter IED technology : A step change in capability

Improvised Explosive Devices (IEDs) are reported as the number one cause of injury and death for allied troops in the current theater of operation. Deakin University’s Centre for Intelligent Systems Research (CISR) is working on next-generation technology to combat the threat. In 2006 CISR was awarded funding through the Capability and Technology Demonstrator (CTD) Program managed by the Australian Defence Force. The objective was to investigate the use of haptics or force feedback technology for Counter-IED (CIED) tasks. Over the past six years, engineers from CISR have worked alongside Defence stakeholders to develop a series of robotic platforms designed to immerse a soldier in the remote environment. Utilising a natural user interface, haptic force feedback and stereovision, the technology has undergone initial trials in Sydney, Canberra, Woomera and at the CISR testing facility in Geelong, Australia. The technology has proved popular among operators allowing them increased fidelity and manipulation speed while significantly reducing required training. CISR has a history of rapidly delivering technology to meet the needs of police and law enforcement in Australia. The OzBot™ series of robots developed in conjunction with the Victorian Police is currently in service and used extensively for hostage negotiation and first responder roles. The CISR robotics group works on technologies that reduce operator fatigue, minimise training liability and maintenance. Over 55 engineers develop simulation environments for increased training availability and continuous improvement to the current range of mobile platforms, including communications range, payload, manipulator reach and capability. This paper describes a number of the technologies, methods and systems developed by CISR for IED neutralisation, with the aim to increasing military awareness of Australian capability.

Improving peak shapes with counter gradients in two-dimensional high performance liquid chromatography

To achieve the greatest peak capacity in two-dimensional high performance liquid chromatography (2D-HPLC) a gradient should be operated in both separation dimensions. However, it is known that when an injection solvent that is stronger than the initial mobile phase composition is deleterious to peak performance, thus causing problems when cutting a portion from one gradient into another. This was overcome when coupling hydrophilic interaction with reversed phase chromatography by introducing a counter gradient that changed the solvent strength of the second dimension injection. It was found that an injection solvent composition of 20% acetonitrile in water gave acceptable results in one-dimensional simulations with an initial composition of 5% acetonitrile. When this was transferred to a 2D-HPLC separation of standards it was found that a marked improvement in peak shape was gained for the moderately retained analytes (phenol and dimethyl phthalate), some improvement for the weakly retained caffeine and very little change for the strongly retained n-propylbenzene and anthracene which already displayed good chromatographic profiles. This effect was transferred when applied to a 2D-HPLC separation of a coffee extract where the indecipherable retention profile was transformed to a successful application multidimensional chromatography with peaks occupying 71% of the separation space according to the geometric approach to factor analysis.

Advanced microwave-assisted production of hybrid electrodes for energy applications

Carbon nanotubes are one of the most prominent materials in research for creating electrodes for portable electronics. When coupled with metallic nanoparticles the performance of carbon nanotube electrodes can be dramatically improved. Microwave reduction is an extremely rapid method for producing carbon nanotube-metallic nanoparticle composites, however, this technique has so far been limited to carbon nanotube soot. An understanding of the microwave process and the interactions of metallic nanoparticles with carbon nanotubes have allowed us to extend this promising functionalisation route to pre-formed CNT electrode architectures. Nanoparticle reduction onto pre-formed architectures reduces metallic nanoparticle waste as particles are not formed where there is insufficient porosity for electrochemical processes. A two-fold increase in capacitive response, stable over 500 cycles, was observed for these composites, with a maximum capacitance of 300 F g−1 observed for a carbon Nanoweb electrode.

Nanostructured carbon electrodes

In its conducting form, carbon has proven to be a versatile, robust and high performing electrode material in areas such as energy conversion, energy storage and even medical bionics. In our laboratories we have been interested in the fabrication and utilization of nanostructured electrodes based on more recently discovered forms of carbon. These include carbon nanotubes and graphene.

Analyses and comparison of counter-movement jump performance and self-rated recovery in state under-18s Australian Rules Football players during a national championship

Recovery of team sport athletes during multiple competitive games is an important area for strength and conditioning coaches to monitor as it facilitates for athletes to be ready to perform (11,13). Utilising athletic performance data in conjunction with self-rated reporting measures can help determine if in fact a player or team has recovered sufficiently or shown a trend towards recovery prior to a competitive match (11). Positive improvement in recovery variables can provide confidence in the effectiveness of recovery methods used and assist in determining the training schedule in order to positively manipulate the fitness-fatigue relationship (3).

Various methods of analysing the recovery of athletes have been reported in the literature and are available to the strength and conditioning coach. These include subjective, self-rated scales and perceived level of recovery questionnaires (11,12,13). Athletic performance measures during exercises such as the counter movement jump (CMJ) have also been analysed, predominantly utilising force plates to obtain kinetic data. (5,13,14). However, such equipment can be difficult to transport, requires continual calibration and is costly to purchase. A linear transducer can provide important information on CMJ variables in the assessment of athletic movements and due to its size and portability could serve as a valuable tool to assist strength and conditioning coaches, (8,10), and potentially enable the monitoring of recovery.

Previous studies have investigated the fatigue effects of competitive games in various sports (11,13,14) including Australian Rules Football (AFL) at the senior elite league level (5, 6). To the authors’ knowledge, however, there is yet to be a study investigating the recovery response in AFL players, specifically in players 18 years and under competing in the National Under 18s Championships. Australian Rules football is an extremely physically demanding and fatiguing sport where players participate in games time exceeding 120 minutes duration, covering large distances (~12-18km, position dependent) with many high intensity efforts performed at random times throughout the game (2,6,16). Hence, it would seem pertinent to analyse the fatigue effects of competitive matches in an Australian Rules Under-18’s National Championship and the subsequent recovery from these games.

The aim of this study was to analyse and compare two self-rated subjective measures of recovery; they being muscle soreness (MS) of the lower body, overall perceived total recovery (TR), and the performance measure of peak velocity (PV) obtained from a CMJ analysed with a linear transducer. Data collection occurred between rounds four and five of the Australian Football League Under-18’s National Championship, representing a four-day recovery analysis period between matches.

Preparation of composite electrodes with carbon nanotubes for lithium-ion batteries by low-energy ball milling

Some of the prospective electrode materials for lithium-ion batteries are known to have electronic transport limitations preventing them from being used in the electrodes directly. In many cases, however, these materials may become practical if they are applied in the form of nanocomposites with a carbon component, e.g. via incorporating nanoparticles of the phase of interest into a conducting network of carbon nanotubes. A simple way to prepare oxide-carbon nanotube composites suitable for the electrodes of lithium-ion batteries is presented in this paper. The method is based on low-energy ball milling. An electrochemically active but insulating phase of LiFeTiO4 is used as a test material. It is demonstrated that the LiFeTiO4-carbon nanotube composite is not only capable of having significantly higher capacity (∼105-120 mA h g-1vs. the capacity of ∼65-70 mA h g -1 for the LiFeTiO4 nanoparticles) at a slow current rate but may also operate at reasonably high current rates. © the Partner Organisations 2014.

Performance enhancement of single-walled nanotube-microwave exfoliated graphene oxide composite electrodes using a stacked electrode configuration

We report the development of a stacked electrode supercapacitor cell using stainless steel meshes as the current collectors and optimised single walled nanotubes (SWNT)-microwave exfoliated graphene oxide (mw rGO) composites as the electrode material. The introduction of mw rGO into a SWNT matrix creates an intertwined porous structure that enhances the electroactive surface area and capacitive performance due to the 3-D hierarchical structure that is formed. The composite structure was optimised by varying the weight ratio of the SWNTs and mw rGO. The best performing ratio was the 90% SWNT-10% mw rGO electrode which achieved a specific capacitance of 306 F g-1 (3 electrode measurement calculated at 20 mV s-1). The 90% SWNT-10% mw rGO was then fabricated into a stacked electrode configuration (SEC) which significantly enhanced the electrode performance per volume (1.43 mW h cm-3, & 6.25 W cm-3). Device testing showed excellent switching capability up to 10 A g-1, and very good stability over 10000 cycles at 1.0 A g-1 with 93% capacity retention. © the Partner Organisations 2014.

The influence of graphene on the electrical communication through organic layers on graphite and gold electrodes

The influence of graphene on the electrical communication through organic layers fabricated on graphite and gold electrodes is investigated. These layers were prepared by in situ reductive adsorption of 4-aminobenzoic acid in the presence of NaNO2 and HCl to have surface bound carboxylic acid functionalities, followed by covalent attachment of 1-aminopyrene via an amide coupling reaction to have surface bound pyrene groups for graphene immobilization via noncovalent π-π stacking interaction. The coverage of the layers created via reductive adsorption on graphite electrodes was found to be much higher than that on gold electrodes. It was revealed that graphene significantly enhances the electrical communication through the layers on graphite electrodes but on gold electrodes the enhancement effect through the layers was only minor. However, when gold electrodes were modified with a self-assembled monolayer (SAM) of propanethiol the subsequent immobilization of graphene resulted in a significant enhancement of the electrical communication. It is also found that immobilization of graphene could affect the electron transfer between the redox probe, pyrene and the underlying electrodes. Atomic force microscopy (AFM) and scanning electron microscopy (SEM) were used to characterize the graphene sheets. Cyclic voltammetry, electrochemical impedance spectroscopy (EIS), and X-ray photoelectron spectroscopy (XPS) were also used to characterize the stepwise modified electrodes. © 2014 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

Electrochemistry of tris(2,2′-bipyridyl) cobalt(II) in ionic liquids and aprotic molecular solvents on glassy carbon and platinum electrodes

The tris(2,2′-bipyridyl) complexes of cobalt(II) and (III) ([Co(bpy)3]^2+/3+) produce a redox couple of great interest in thermoelectrochemical cells and dye sensitized solar cells including both types of devices based on ionic liquid electrolytes. We present a systematic study of the electrochemistry of [Co(bpy)3]²⁺ [NTf2]^-2 in two ionic liquids (ILs) based on the 1-ethyl-3-methylimidazolium (C2mim) cation and two ILs based on the 1-butyl-1-methylpyrrolidinium cation (C4mpyr), as well as three aprotic molecular solvents. Platinum (Pt) and glassy carbon (GC) working electrodes were compared. In all solvents better electrochemical responses were observed on GC, which yielded higher currents in the cyclic voltammograms and lower rate constants for the redox reaction. The [Co(bpy)3]^1+/2+ couple is also readily observed, but this redox reaction is chemically irreversible, possibly because the [Co(bpy)3]¹⁺ complex dissociates. However, the [Co(bpy)3]^1+/2+ reaction is chemically reversible in all of the solvents studied, except 3-methoxypropionitrile, if excess of 2,2′-bipyridyl is added to the solution.