Stable oxygen isotope ratios of diatoms and relative species abundances in ODP Site 145-882

Recent research has increasingly advocated a role for the North Pacific Ocean in modulating global climatic changes over both the last glacial cycle and further back into the geological record. Here a diatom d18O record is presented from Ocean Drilling Program Site 882 over the Pliocene/Quaternary boundary from 2.73 Ma to 2.52 Ma (MIS G6-MIS 99). Large changes in d18Odiatom of c. 4 per mil from 2.73 Ma onwards are documented to occur on a timeframe broadly coinciding with glacial-interglacial cycles. These changes are primarily attributed to large scale inputs of meltwater from glacials surrounding the North Pacific Basin and the Bering Sea. Despite these inputs and associated change in surface water salinity, on the basis of existing opal and UK37 temperature data and new modelled water column densities, no evidence exists to suggests a removal of the halocline stratification or a resumption of the high productivity system similar to that which prevailed prior to 2.73 Ma. The permanence of the halocline suggests that the region played a key role in driving global climatic changes over the early glacial-interglacial cycles that followed the onset of major Northern Hemisphere Glaciation by inhibiting deep water upwelling and ventilation of CO2 to the atmosphere.

Stable oxygen isotope record of coral core RUS-95 from the Red Sea

A 245-year coral oxygen isotope record from the northern Red Sea (Ras Umm Sidd/Egypt, ~28°N) in bimonthly resolution is presented. The mean annual coral delta18O signal apparently reflects varying proportions of both sea surface temperature and delta18Oseawater variability. In conjunction with instrumental observations of climate the coral record suggests for interannual and longer timescales that colder periods are accompanied by more arid conditions in the northern Red Sea but increased rainfall in the southeastern Mediterranean, whereas warmer periods are accompanied by decreased rainfall in the latter and less arid conditions in the northern Red Sea. A ~70-year oscillation of probably North Atlantic origin dominates the coral time series. Interannual to interdecadal variability is correlated with instrumental indices of the North Atlantic Oscillation (NAO), the El Niño-Southern Oscillation (ENSO), and North Pacific climate variability. The results suggest that these modes contributed consistently to Middle East climate variability since at least 1750, preferentially at a period of ~5.7 years.

Stable carbon and oxygen isotope ratios of benthic foraminifera from the East Atlantic Ocean

The glacial to interglacial delta13C records of the benthic foraminifera Cibicidoides wuellerstorfi and the Uvigerina peregrina group from deep-sea cores cannot be adjusted by a generally valid constant. The delta13C values of the U. peregrina group largely correlate with the accumulation rates of organic carbon, suggesting a local "habitat effect"; those of C. wuellerstorfi vary independently with respect to the carbon flux and record fluctuations in the delta13C of the ambient bottom water isotopic composition.

Mg/Ca and stable oxygen isotope ratios of Uvigerina spp. from the Southern Ocean

The sensitivity to temperature of Mg/Ca ratios in the shallow-infaunal benthic foraminifera Uvigerina spp. has been assessed. Core-top calibrations over ~1-20 °C show a range in sensitivity of 0.065-0.084 mmol/mol/°C but few data are available spanning the temperature range anticipated in deep-sea records over glacial-interglacial cycles. In contrast to epibenthic foraminiferal species, carbonate ion saturation appears not to affect Mg/Ca significantly. A method based on estimating the ratio of the temperature sensitivity of foraminiferal Mg/Ca to that of d18Ocalcite shows that sensitivity for Mg/Ca at the high end of the observed core-top range (~0.1 mmol/mol/°C) is required for consistency with LGM-Holocene differences in each property as constrained by independent proxy data. This is supported by a Mg/Ca record for Uvigerina spp. generated for the Southern Ocean over the past 440,000 years from Ocean Drilling Program Site 1123 (Chatham Rise, New Zealand). The record shows variability that correlates with climate oscillations. The LGM deep ocean temperature derived from the Mg/Ca record is -1.1 ± 0.3 °C. Transformation to temperature allows estimates to be made of changes in bottom water temperature and seawater d18O and comparison made with literature records. Analysis reveals a ~2.5-kyr lead in the record of temperature over calcite d18O and a longer lead over seawater d18O. This is a reflection of larger phase offsets at eccentricity periods; phase offsets at tilt and precession are within error zero.

Oxygen isotope ratios on calcite from the Piànico lake record

Stable oxygen isotope analyses at annual, 2-, 5-, 10- and 20-varve sample resolutions were carried out on two selected varve intervals from the interglacial sediment record of the Piànico palaeolake. These sediments are particularly suitable for ultra-high-resolution isotope analyses on lacustrine endogenic calcite because of the exceptionally well-preserved varve structure. A bias through detrital contamination can be excluded because microscopically controlled sampling enabled selecting detritus-free samples. The studied sediment intervals comprise 352 and 88 continuous varve series formed during periods of rapid climate change at the onset and end of a marked millennial-scale cool interval during the Piànico Interglacial. The most intriguing result is a pronounced short-term oscillation in the bi-annually resolved isotope record superimposed on the general decreasing and increasing d18O trends at the climatic transitions that is recorded at lower sample resolution. Spectral analyses of the bi-annual time series reveal periodicities indicating solar and NAO controls on the d18O record. Multiple d18O measurements from endogenic calcite of individual varves showed variations of up to 0.6 per mil, thus larger than the observed inter-annual variability and most likely explained by seasonal effects.

Carbon and oxygen isotope ratios of Selinde River, southeastern Siberian platform

Carbon isotopic data from the Selinde section in the southeastern part of the Siberian platform area are correlated with the reference isotopic profile from the Lower Cambrian stratotype sections of the Lena Aldan region, but also show additional d13C excursions unrecognized there. The chemostratigraphic correlation suggests that the geological and fossil record of the lower Pestrotsvet Formation in the Selinde section has a deeper history than the stratotype region. This conclusion is important for both constraining the age of the earliest Cambrian marine transgression on the Siberian platform and providing a clearer understanding of the pace and order of early Cambrian geochemical and biological events.

Stable oxygen isotope data and geophysical measurements from Red Sea of core M174/Kl11

To settle debate on the timing of sea level fluctuations during marine isotope stage (MIS) 3, we present records of d18O ruber (sea level proxy) and magnetic susceptibility from the same samples within the single sediment archive (i.e., "coregistered") of central Red Sea core GeoTü-KL11. Core-scanning X-ray fluorescence and environmental magnetic data establish the suitability of magnetic susceptibility as a proxy for eolian dust content in Red Sea sediments. The eolian dust data record similar variability as Greenland d18O ice during early to middle MIS 3, in agreement with previous observations that regional Arabian Sea climate fluctuated with a timing similar to that of Greenland climate variations. In contrast, the sea level record fluctuates with a timing similar to that of Antarctic-style climate variations. The coregistered nature of the two records in core KL11 unambiguously reveals a distinct offset in the phase relationship between sea level and eolian dust fluctuations. The results confirm that sea level rises, indicated by shifts in Red Sea d18O ruber to lighter values, occurred during cold episodes in Greenland during early to middle MIS 3. This indicates that the amplitudes of the reconstructed MIS 3 sea level fluctuations would not be reduced by inclusion of regional climate fluctuations in the Red Sea sea level method. Our analysis comprehensively supports our earlier conclusions of large-amplitude sea level variations during MIS 3 with a timing that is strongly similar to Antarctic-style climate variations.