992 resultados para bonding agent


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软件过程建模是指对软件过程建立模型,并且对模型建立和模型执行提供自动化支持。软件过程建模技术为软件过程的描述、表示、执行、分析、跟踪、变更以及改进提供了方法和工具,从而为软件组织实现软件开发过程的管理和改进提供了有力的支持,对于保证软件组织的软件产品质量,提高开发效率具有重要的理论和实践价值。 软件过程的一个重要特征是极大地依赖于软件开发人员,当软件过程面临各种变化时,正是作为软件过程的主体——软件开发人员的及时反应和应对,使得软件过程能够灵活适应各种软件开发的实际和变化状况;忽视软件开发人员在软件过程中的核心作用,是目前大多软件过程建模方法不适用于软件企业实际应用的原因之一。Agent技术主要基于对人的观察,其已被认识到是软件过程建模领域的重要研究方向之一。然而,相关研究工作并没有很好地体现人在软件过程中的核心作用,其根本原因在于其所采用或关注的是单Agent技术,而非多Agent系统技术。以互联为背景的多Agent系统能够很好地刻画人类的社会性,因此,对于当前以全球性、分布式多点等为主要特点的软件过程而言,采用多Agent系统技术,关注软件过程中所涉及的实体之间的协商、协作、竞争、承诺等特性是将Agent技术应用于软件过程的研究重点。 本文提出一种适应性多边软件过程Agent协商模型AMNM-PA。AMNM-PA基于软件开发者为软件过程中的核心要素并且软件过程为这些核心要素之间的相互协同关系的观点,将软件开发建模描述为代表软件开发者的自治的软件过程Agent(简称过程Agent)之间的协商;在协商中,过程Agent能够在变化的环境下针对各种不同实际应用,以及根据对环境的感知和所拥有的知识,适应、灵活地确立彼此间的协同关系,即建立软件过程。 本文在组织上采用了从模型要素及其相互关系定义、模型要素具体描述到模型实现及验证的逻辑结构。首先,本文给出AMNM-PA的模型定义,对过程Agent的协商所涉及的协商要素及其相互之间的关系进行描述。其次,本文详细描述协商要素中的决策过程,即过程Agent在协商中进行决策所依据的协商策略选择方法及各种可选协商策略;并以决策过程为基础,提出一种多边适应性协商算法,以此给出基于AMNM-PA的适应性多边协商过程的基本算法。随后,本文详细描述了另一协商要素——协商规则,其解决了协商过程的离线和在线灵活性问题,从而为软件过程建模的灵活性提供了解决方案。最后,本文实现了基于AMNM-PA的协商系统,并在该系统的支持下进行了实验研究,验证了AMNM-PA能够在变化的环境中适应性地建立面向实际软件项目的软件过程,并且该软件过程所包含的个体利益能够得到均衡、整体利益较高;同时很好地支持了软件过程建立和执行的灵活性。

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软件开发过程的不可见是软件项目失败的主要原因之一。为了提高软件开发过程的可见性,研究人员从软件开发过程的表示、软件开发知识的管理和软件开发数据的挖掘等方面提出了相应理论、方法和工具,这些理论、方法和工具对提高软件过程的可见性提供了一定的帮助,但却都有自己的局限性,难以全面覆盖提高软件开发过程可见性的要素。 为此,我们需要进一步融合软件过程建模、知识管理和数据挖掘等领域各自的研究成果,探索一种不但支持从过程资产库提取知识,而且支持对这些知识进行描述和管理,同时还能将这些知识直接用于建立符合组织能力的软件过程模型,并可以根据该软件过程模型生成符合组织中人的能力的软件开发项目计划的完整方法,为提高软件开发过程的可见性提供全面、有力的支持,从而有效保障软件开发的质量和效率。 本文给出一种根据组织的软件过程资产库生成软件过程Agent知识的方法,该方法生成的软件过程Agent知识可被用于建立一种基于组织实体能力的软件过程模型。基于该方法,本文实现了一个软件过程Agent自动生成工具,该工具可以根据指定的软件过程资产库自动生成软件过程Agent实例及其知识。同时本文在应用实例研究中进行了实验验证,证明了该方法的有效性。 本文研究是对基于组织实体能力的软件过程建模方法的扩展和补充。该方法和基于组织实体能力的软件过程建模方法的集成,可有效支持根据组织过程资产库生成组织的软件开发知识并将这些知识进行描述,使其能够被用于建立符合组织能力的软件开发模型,并最终根据特定目标生成符合组织实际能力软件开发项目计划。

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本文从经济学和社会心理学角度出发 ,探讨了多种高级认知结构在社会活动中的作用 ,建立了多种高级认知结构的框架 ,研究了这些高级认知结构在多智能体代理系统环境中如何相互作用问题 ,并提出了三个系统模型来刻画这些相互作用。

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The structural properties for various SiCO isomers in the singlet and triplet states have been investigated using CASSCF methods with a 6-311 +G* basis set and also using three DFT and MP2 with same basis set for those systems except for the linear singlet state. The detailed bonding character is discussed, and the state-state correlations and the isomerization mechanism are also determined. Results indicate that there are four different isomers for each spin state, and for all isomers, the triplet state is more stable than the corresponding singlet state. The most stable is the linear SiCO ((3)Sigma(-)) species and may be refer-red to the ground state. At the CASSCF-MP2(full)/6-311+G* level, the state-state energy separations of the other triplet states relative to the ground state are 43.2 (cyclic), 45.2 (linear SiOC), and 75.6 kcal/mol (linear CSiO), respectively, whereas the triplet-singlet state excitation energies for each configuration are 17.3 (linear SiCO), 2.2 (cyclic SiCO), 10.2 (linear SiOC), and 18.5 kcal/mol (linear CSiO), respectively. SiCo ((3)Sigma(-)) may be classified as silene (carbonylsilene), and its COdelta- moiety possesses CO- property. The dissociation energy of the ground state is 42.5 kcal/mol at the CASSCF-MP2(full)/6-311+G* level and falls within a range of 36.5-41.5 kcal/mol at DFT level, and of 23.7-28.9 kcal/mol at the wave function-correlated level, whereas the vertical IP is 188.8 kcal/mol at the CASSCF-MP2(full)/6-311+G* level and is very close to the first IP of Si atom. Three linear isomers (SiCO, SiOC, and CSiO) have similar structural bonding character. SiOC may be referred to the iso-carbonyl Si instead of the aether compound, whereas the CSiO isomer may be considered as the combination of C (the analogue of Si) with SiO (the analogue of CO). The bonding is weak for all linear species, and the corresponding potential energy surfaces are flat, and thus these linear molecules are facile. Another important isomer is of cyclic structure, it may be considered as the combination of CO with Si by the side pi bond. This structure has the smallest triplet state-singlet state excitation energy (similar to2.2 kcal/mol); the C-O bonds are longer, and the corresponding vibrational frequencies are significantly smaller than those of the other linear species. This cyclic species is not classified as an epoxy compound. State-state correlation analysis and the isomerization pathway searches have indicated that there are no direct correlations among three linear structures for each spin state, but they may interchange by experiencing two transition states and one cyclic intermediate. The easiest pathway is to break the Si-O bond to go to the linear SiCO, but its inverse process is very difficult. The most difficult process is to break the C-O bond and to go to the linear CSiO.

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High-throughput screening is a promising new approach in analytical chemistry. Within the framework of an extended screening program (The German-Chinese Drug Screening Program), the enantioseparation of 86 drugs was investigated by capillary zone electrophoresis in the presence of the chiral solvating agent (CSA) octakis-(2,3,6-tri-O-methyl)-gamma-cyclodextrin (TM-gamma-CD). By this means, 15 drugs could be separated into enantiomeric pairs. Approximate measures for the degree of interaction (migration retardation factor, R-m) and for the degree of enantiomer recognition (migration separation factors, alpha(m)) revealed intriguing patterns that were compared with those found for native gamma-cyclodextrin (gamma-CD). Although there is a distinct influence of the analyte structure on the electrophoretic data, interpretation remains difficult. Most remarkably, permethylation of gamma-CD leads neither to a higher affinity nor to better chiral recognition, in contrast to the findings with alpha-CD.

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为了根据人力资源及项目信息进行资源调度,基于过程Agent的人力资源调度方法通过对软件过程中的人力资源建模,描述和定义了任务(目标)及联合体投标模型,并根据用户对目标的偏好生成调度计划,能够为软件企业在人力资源优化调度、项目进度安排等方面提供决策支持,进而提高软件企业的项目管理能力和资源利用效率。最后通过一个实例表明了该方法的可行性和有效性。

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为提高复杂网络环境和任务需求下器材保障的智能化水平,提出了一个数据驱动的多Agent器材保障决策支持系统DSS(decision support system),系统中的数据、模型以及Agent可分布在不同的网络节点上,高层Agent可由粒度更小的子AgentAgent部件组合而成;系统中的各类智能Agent相互协作,共同完成异构数据集成、多维数据集构造、器材保障模型挖掘、复杂规划问题求解,以及保障方案自动生成等任务,从而有效降低了系统开发的难度,提高了Agent协作的灵活性。研究结果表明,该系统架构能够显著提升器材保障决策方案的质量和效率。

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Amphiphilic supramolecular miktoarm star copolymers linked by ionic bonds with controlled molecular weight and low polydispersity have been successfully synthesized via reversible addition-fragmentation chain transfer (RAFT) polymerization using an ion-bonded macromolecular RAFT agent (macro-RAFT agent). Firstly, a new tetrafunctional initiator, dimethyl 4,6-bis(bromomethyl)-isophthalate, was synthesized and used as an initiator for atom transfer radical polymerization (ATRP) of styrene to form polystyrene (PSt) containing two ester groups at the middle of polymer chain. Then, the ester groups were converted into tertiary amino groups and the ion-bonded supramolecular macro-RAFT agent was obtained through the interaction between the tertiary amino group and 2-dodecylsulfanylthiocarbonylsulfanyl-2-methyl propionic acid (DMP). Finally, ion-bonded amphiphilic miktoarm star copolymer, (PSt)(2)-poly(N-isopropyl-acrylamide)(2), was prepared by RAFT polymerization of N-isopropylacrylamide (NIPAM) in the presence of the supramolecular macro-RAFT agent. The polymerization kinetics was investigated and the molecular weight and the architecture of the resulting star polymers were characterized by means of H-1-NMR, FTIR, and GPC techniques. (c) 2008 Wiley Periodicals, Inc.

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The influence of the concentration of a nucleating agent (NA), namely 1,3:2,4-di(3,4-dimethylbenzylidene) sorbitol (DMDBS), on the gamma phase content in a propylene/ethylene copolymer was investigated by means of Differential Scanning Calorimetry (DSC), Wide-Angle X-ray Diffraction (WAXD), Small- Angle X-ray Scatter (SAXS) and Polarized Optical Microscopy (POM).

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Selective extraction-separation of yttrium(Ill) from heavy lanthanides into 1-octyl-3-methylimidazolium hexafluorophosphate ([C(8)mim][PF6]) containing Cyanex 923 was achieved by adding a water-soluble complexing agent (EDTA) to aqueous phase. The simple and environmentally benign complexing method was proved to be an effective strategy for enhancing the selectivity of [C(n)mim] [PF6]/[Tf2N]-based extraction system without increasing the loss of [C(n)mim](+). (c) 2007 Elsevier B.V. All rights reserved.

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This paper describes the formation of fibril like aggregates from the self-assembly of block copolymer mixture (polystyrene-b-poly(4-vinylpyridine) (PS-b-P4VP) and polystyrene-b-poly(acrylic acid) (PS-b-PAA)) via interpolymer hydrogen bonding in nonselective solvent. The hydrogen bonding between P4VP and PAA in chloroform leads to the formation of complex. When all the pyridine units in P4VP were all hydrogen bonded to acrylic acid in PAA, the formed complex is insoluble, resulting in the formation of spherical micellar aggregates and nanorods.