Análise da frequência anual das condições de céu em Botucatu, São Paulo

This paper presents an analysis of the frequency of the sky conditions in Botucatu. The classification of sky conditions was made based on the clearness index (K T), calculated from a database with 10 years of measured daily global solar radiation. Throughout the year in Botucatu, there is a predominance of days with clear sky condition, on average 114 days. For cloudy sky condition, the average frequency is 61 days. About the two intermediate sky conditions, the frequency of the sky partially cloudy with dominance for the diffuse is 94 days and the one with dominance for the clear is 96 days. The main influential factors on the sky conditions in Botucatu are the inputs of cold fronts and the formation of the South Atlantic Convergence Zone. They respond primarily by altering the sky condition of clear to cloudy or partially cloudy with dominance to diffuse. The aerosols resulting from burning in sugarcane fields respond by altering the sky condition from clear to partly cloudy with dominance for the clear.

Análise do escoamento de HFC-134a em tubos capilares usando o modelo de dois fluidos

This work presents a numerical model to simulate refrigerant flow through capillary tubes, commonly used as expansion devices in refrigeration systems. The capillary tube is considered straight and horizontal. The flow is taken as one-dimensional and adiabatic. Steady state and thermodynamic equilibrium conditions are assumed. The two-fluid model, involving four conservation equations and considering the hidrodynamic nonequilibrium between the liquid and vapor phases is applied to the flow region. The pressure profiles and the mass flow rates given by the model are compared with experimental data.

Análise térmica do processo de incineração de resíduos aquosos com chamas enriquecidas

The use of oxygen to enrich the combustion air can be an attractive technique to increase capacity of an incinerator originally designed to operate with air. If incinerator parameters such as operation temperature, turbulence level and residence time are fixed for a certain fuel supply rate, it is possible to increase the residue consumption rate using enriched air. This paper presents the thermal analysis for operation with enriched air of an aqueous residue experimental incinerator. The auxiliary fuel was diesel oil. The theoretical results showed that there is a considerable increase in the incineration ratio up to approximately 50 % of O 2 in the oxidiser. The tendency was confirmed experimentally. Thermal analysis was demonstrated to be an important tool to predict possible incinerator capacity increase.

Estudo comparativo experimental da injeção perineural do álcool benzílico 0,75% e do álcool etílico absoluto nos nervos palmares de eqüinos

The clinical and histopathological effects of two alcoholic neurolytics were studied in horses. Normal horses were shod with a designed shoe adaptted with 5 screws to produce solar pain. After gait and lameness score analysis, the palmar nerve of 5 horses was injected with 5 ml of 0,75% benzyl alcohol (Group A) and 5 horses were injected with 5 ml of absolute ethyl alcohol (Group B). The animals were submitted to regular lameness evaluation and solar sensibility tests during next six months. The solar sensitivity returned 5 months latter in the group injected with benzyl alcohol 0,75%, while in the group injected with absolute ethyl alcohol, the sole was still desensitized 6 months latter. The histopathological findings showed that the nerve injected with benzyl alcohol 0,75%, resulted in axonotmesis, characterized by axonal nerve degeneration, with possibilities for the nerve conduction recovery. The perineural injection of ethyl alcohol absolute, resulted in neurotmesis with difficult nerve regeneration. It was concluded that chemical neurolysis with alcohol is an option for temporary or permanent nerve blocks in horses.

Análise de processos alternativos na preparação de esqueletos para uso didático

Zoology laboratories at institutions of research and education have shown great demand for anatomical parts for practical lessons. However, although the bibliography is not necessarily scarce, analyses of the cost/benefit relations of such processes are rare, considering aspects such as preparation time, quality of the anatomical parts, and material and human resources. In addition to the common techniques already used, new low-cost products, not cited in literature and easily found in the market, were also tested. The main objective of this work was to elaborate and organize information on techniques of bone parts maceration for study collections, making comparative analyses on the cost/benefit relations of each technique. Twelve products were tested, evaluating experimental conditions such as: concentration and combination of reagents, temperature, pH and time of exposure of the parts to the reagents. The results indicated that the products recommended for the use in the maceration processes were: water, hydrogen peroxide and papaya juice (Carica papaya).

Análise histopatológica de órgãos linfóides de bovinos e camundongos intoxicados experimentalmente por Baccharis coridifolia: Caracterização imunoistoquímica de linfócitos B e T

Baccharis coridifolia is one of the most important poisonous plants to cattle in the South of Brazil. The plant provokes necrotic lesions in the lymphoid tissues and in the gastrointestinal tract of cattle. Experimental administration to mice produces most of the lesions seen in the lymphoid tissues of cattle. This study was conducted to search possible differences in the susceptibility of T and B lymphocyte subpopulations. Lymph nodes, spleen, thymus and gut-associated lymphoid tissue (GALT) of cattle and mice experimentally poisoned were evaluated. The results were evaluated based on cell populations affected or remaining in the organs. Immunostaining for B lymphocytes (anti-BLA-36) identified the germinal center of follicles of the lymph node, spleen and GALT in both species. Immunostaining for T lymphocyte (anti-CD3) identified the paracortical area of the germinal centers of the lymph nodes and GALT, the periarteriolar area of the spleen, and the whole thymus both in cattle and mice. Experimentally poisoned cattle and mice shows necrosis of the germinal center of secondary follicles of the lymph nodes, spleen and GALT, where necrotic cells were immunostained for B and less often for T lymphocyte. Necrotic cells in the paracortical region of the lymph node were less often and were immunostained. Necrotic lesions of the thymus were seen only in mice, with positively stained for T lymphocyte. The distribution of the lesions in the lymphoid tissues and the immunostaining in necrotic cells suggested that the active principles of the plant are cytotoxic to B and T cells.

Análise das dosagens e concentrações séricas da ciclosporina A em cães da raça Golden Retriever normais ou afetados pela distrofia muscular

The muscular dystrophy of Golden Retriever (GRMD) is a degenerative miopaty caused by the absence of dystrophy and it is genetically homologue of the Duchenne muscular dystrophy in humans, so, these dogs are considerably experimental models for studies on cellular therapy. Their successful depends of the adequate immunosuppression. Cyclosporin A (CsA) is indicated for that and the monitoring of the blood concentration and adverse effects are essential to viabilise the therapy. It was studied GRMD dogs, and normal dogs from the same breed, submitted for therapy with CsA, associated, on GRMD, of cell transplantation. It was evaluated blood concentration of the drug, between two or tree days using the method of FPIA. In our results we found that the CsA blood concentrations oscillated too much on six than eight of our animals. We concluded that the doses varieties individually and the correct dosage as to important as the evaluation of the blood concentration of the drug and became viable for cell therapy.

Análise de séries temporais de coordenadas estimadas com gps: Uma proposta metodológica para detecção, remoção e recuperação de efeitos sazonais

GPS active networks are more and more used in geodetic surveying and scientific experiments, as water vapor monitoring in the atmosphere and lithosphere plate movement. Among the methods of GPS positioning, Precise Point Positioning (PPP) has provided very good results. A characteristic of PPP is related to the modeling and / or estimation of the errors involved in this method. The accuracy obtained for the coordinates can reach few millimeters. Seasonal effects can affect such accuracy if they are not consistent treated during the data processing. Coordinates time series analyses have been realized using Fourier or Harmonics spectral analyses, wavelets, least squares estimation among others. An approach is presented in this paper aiming to investigate the seasonal effects included in the stations coordinates time series. Experiments were carried out using data from stations Manaus (NAUS) and Fortaleza (BRFT) which belong to the Brazilian Continuous GPS Network (RBMC). The coordinates of these stations were estimated daily using PPP and were analyzed through wavelets for identification of the periods of the seasonal effects (annual and semi-annual) in each time series. These effects were removed by means of a filtering process applied in the series via the least squares adjustment (LSQ) of a periodic function. The results showed that the combination of these two mathematical tools, wavelets and LSQ, is an interesting and efficient technique for removal of seasonal effects in time series.

Análise espacial de nutrientes e produção de alface cultivada em ambiente protegido

The objective of this work was to study spatial variability of some chemical soil attributes and lettuce production (total shoot fresh matter mass - MF; commercial shoot fresh matter mass - MFC; commercial shoot dry matter mass - MCS; and head commercial diameter - DCC) offering subsidies to the protected environment mapping in nutrients management areas in lettuce culture aiming for a higher productivity with application of fertilizers. The experiment was conducted in a protective environment (greenhouse) with lettuce irrigated by drip irrigation and sampling grid with 152 points. The special dependence analysis, determined by the variogram, was obtained with the aid of the GS+ Program. Considering the need for crop nutrients through the map obtained for element P (phosphorus) it was possible to establish two distinct areas for the application of this element in plantation fertilization. Through the lettuce yield maps obtained with MFC and DCC attributes was difficult to establish distinct areas for its management with data observed in only one crop cycle. Krigagem has proved useful for mapping the attributes studied.

Validação de método de análise quantitativa para a triancinolona a partir de complexo ternário por espectrofotometria de UV-Vis

Triamcinolone (TRI), a drug widely used in the treatment of ocular inflammatory diseases, is practically insoluble in water, which limits its use in eye drops. Cyclodextrins (CDs) have been used to increase the solubility or dissolution rate of drugs. The purpose of the present study was to validate a UV-Vis spectrophotometric method for quantitative analysis of TRI in inclusion complexes with beta-cyclodextrin (B-CD) associated with triethanolamine (TEA) (ternary complex). The proposed analytical method was validated with respect to the parameters established by the Brazilian regulatory National Agency of Sanitary Monitoring (ANVISA). The analytical measurements of absorbance were made at 242nm, at room temperature, in a 1-cm path-length cuvette. The precision and accuracy studies were performed at five concentration levels (4, 8, 12, 18 and 20μg.mL -1). The B-CD associated with TEA did not provoke any alteration in the photochemical behavior of TRI. The results for the measured analytical parameters showed the success of the method. The standard curve was linear (r2 > 0.999) in the concentration range from 2 to 24 μg.mL -1. The method achieved good precision levels in the inter-day (relative standard deviation-RSD <3.4%) and reproducibility (RSD <3.8%) tests. The accuracy was about 80% and the pH changes introduced in the robustness study did not reveal any relevant interference at any of the studied concentrations. The experimental results demonstrate a simple, rapid and affordable UV-Vis spectrophotometric method that could be applied to the quantitation of TRI in this ternary complex.

Análise de crescimento e produtividade de cultivares de arroz de terras altas dos tipos tradicional, intermediário e moderno

The growth analysis allows the characterization and understanding of the upland rice cultivars development. This study aimed at characterizing, by using the growth analysis, the physiological components and agronomic performance, as well as the differences among traditional, intermediate and modern upland rice cultivars. The experiment was conducted under upland rice conditions, favored by the use of supplementary irrigation. The experimental design was randomized blocks, with three treatments consisting of traditional (Caiapó), modern (Maravilha) and intermediate (BRS Primavera) cultivars and eight replications. The leaf area index (LAI), instantaneous growth rate (IGR), relative growth rate (RGR), net assimilation rate (NAR) and specific leaf area (SLA), as well as grain yield and yield components, were evaluated. The intermediate and traditional cultivars presented the highest total dry matter accumulation rate, while the traditional and modern ones showed the highest LAI. The intermediate cultivar presented the highest IGR, RGR, NAR and SLA levels, as well as the highest grain yield, as a consequence of the higher spikelet fertility and 1,000 grain mass.

Análise química da folha d de abacaxizeiro cv. smooth cayenne antes e após a indução floral em função de doses e parcelamentos de nitrogênio

Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

Análise das tensões de água no solo cultivado com morangueiro sob poda

Strawberry yield and quality was evaluated after drastic pruning (second cycle), under different soil water tensions, drip irrigation. The experiment was conducted on beds at a greenhouse, located at Engineering Department, Federal University of Lavras (UFLA), from April to December of 2010. An experimental design was in randomized blocks with three replicates. The treatments were composed of six different soil water tension, 15, 25, 35, 45, 55 e 70 kPa. Results obtained allowed to verify that to higher values of: total and commercial fresh weight of fruits per plant, total and commercial number fruits per plant and total and commercial yield, it is necessary to irrigate when soil water tension gets approximately to 15 kPa, at 0.15 m deep. Commercial average fruit mass and noncommercial fresh weight of fruits per plant, were not reduced under different soil water tensions applied.

Towards an insight on photodamage in hair fibre by UV-light: An experimental and theoretical study

Synopsis: Objectives: In this research, an experimental and theoretical study was conducted to design a photodegradation mechanism of the amino acid tryptophan (Trp) in hair fibres. Methods: For the experimental research, Caucasian hair fibres were exposed to several different solar radiation simulation periods. Then, Trp and its photoproducts (N-formylkynurenine and kynurenine) were assayed by excitation and emission spectroscopic analysis. Results: For the theoretical study, reactions involved in the photodegradation of Trp were evaluated by high-level quantum mechanical calculations in a density functional theory (DFT) framework which indicate a probable Trp degradation mechanism with a minimum expended energy pathway. Conclusion: The biochemistry concerning these reactions is essentially important for a biological system where the degradation of Trp occurs. © 2013 John Wiley & Sons Ltd.

UV filters in water samples: Experimental design on the SPE optimization followed by GC-MS/MS analysis

Esse estudo descreve o desenvolvimento e otimização de um método de extração em fase solida (SPE) para análise dos filtros ultravioletas (UV): benzofenona-3 (BP-3), etilhexil salicilato (ES), etilhexil metoxinamato (EHMC) e octocrileno (OC) em matrizes ambientais. Um planejamento fatorial fracionário (PFF) 25-1 foi empregado na avaliação das variáveis significativas do método de extração. As condições experimentais otimizadas da avaliação estatística foram: capacidade do cartucho de 500 mL, eluente acetato de etila, metanol como solvente de lavagem (10% em água, v/v) and volume do eluente de 3 × 2 mL e pH 3. Os parâmetros analíticos avaliados foram satisfatõrios, apresentando linearidade de 100 a 4000 ng L -1, recuperaç ões para os quatro níveis de fortificação (Limite de Quantificação do Método, 200, 1000 e 2000 ng L-1) entre 62 e 107% com desvio padrão relativo menor que 14%. Os limites de quantificação foram encontrados na faixa de ng L-1, variando entre 10 e 100 ng L-1. O método proposto foi aplicado para a determinação dos quatro filtros UV em amostras de águas naturais. This study describes the development and optimization of a solid-phase extraction (SPE) method for analysis of ultraviolet (UV) filters, benzophenone-3 (BP-3), ethylhexyl methoxycinnamate (EHMC), ethylhexyl salicylate (ES) and octocrylene (OC), in environmental matrices. A 25-1 fractional factorial design (FFD) was used to evaluate the significant variables for the extraction method. The optimized experimental conditions determined from the statistical evaluation were: breakthrough volume of 500 mL, eluent of ethyl acetate, wash solvent of methanol (10% in water, v/v), eluent volume of 3 × 2 mL and pH 3. The evaluated analytical parameters were satisfactory for the analytes and showed linearity between 100 and 4000 ng L-1, recoveries for four fortification levels (Method Quantification Limit, 200, 1000 and 2000 ng L-1) were between 62 and 107% with relative standard deviations less than 14%. Limits of quantification were in the ng L-1 range and were between 10 and 100 ng L-1. The proposed method was used to analyze four UV filters in natural water samples. ©2013 Sociedade Brasileira de Química.