中国区划工作的回顾与展望

在回顾国内外区划工作基础上,总结了我国区划工作各个发展阶段的特点,简单概述了我国区划工作中的方法论,讨论了区划工作中存在的若干问题。20世纪后半叶起,我国的区划研究进入系统研究和全面发展期。这期间我国区划工作的主要特点可归纳为:(1)众多区划方案的提出都有其深刻的历史背景,既是科学的总结,又与我国当时经济发展的水平和需求相关;(2)区划工作多是静态的,不能及时反映变化了的自然和人文要素;(3)现有区划工作未能将自然区划和经济区划很好地结合起来;(4)区划工作大多集中在陆地系统,对海洋系统的关注不够;(5)

SARS控制与预警地理信息系统的研制与应用

针对中国当前非典型肺炎(SARS)疫情防治工作的迫切需求,作者基于其在地理信息科研领域具有大型国产GIS软件平台(SuperMAP)及其在辅助决策空间信息模型工具等方面的科研优势,紧急研制了“国家SARS疫情控制与预警信息系统”。该系统由5个子系统构成,是一个将空间定位、空间信息管理、空间信息分析技术和通信技术进行有机的整合,形成了前后端一体的SARS疫情实时传输、处理、分析和分布完整的信息系统。在SARS疫情的信息采集、管理、分析及其防治与监控措施的发布等方面发挥了重要的作用。

Microstructure and mechanical properties of Mg-4.5Zn-xNd (x=0, 1 and 2, wt%) alloys

Microstructure and mechanical properties of Mg-4.5Zn-xNd (x = 0, 1 and 2, wt%) alloys heat-treated at 603 K for 2 It have been investigated. T-phase (an Mg-Zn-Nd ternary phase) was observed in the Nd containing alloys. The optimal mechanical properties were obtained in the Mg-4.5Zn-1Nd alloy, and the ultimate tensile strength and yield strength were 228 and 79 MPa, respectively. Through comparing with the Mg-4.5Zn alloy, the increments of ultimate tensile strength and yield strength were 51 and 17 MPa.

Molecular dynamics study on the phase diagrams of linear and branched chain molecules

The particle transfer molecular dynamics is used to study the phase equilibria of linear and branched chain molecules. The scaling of the critical temperature versus chain length is obtained and the critical densities are found to decrease with increasing chain length, which are in agreement with the results of experiment and theory. The phase diagrams of the linear and the branched chain molecules nearly overlap with each other. Moreover, the radial distribution functions of linear and branched chain molecules in gas phase are very similar, but in the liquid phase, they are different for different kinds of chains.

Preparation and characterization of cationic corn starch with a high degree of substitution in dioxane-THF-water media

Cationic corn starch derivatives with a high degree of substitution are prepared in alkaline solution or in mixed media of organic solvent and water with different levels of the cationic reagent, 2,3-epoxypropyltrimethylammonium chloride. The starch cationization yield is investigated, and the results indicate that the degree of substitution (DS) of the samples depends on the reaction conditions and reaction media. The maximum DS values are up to 1.37 in 1,4-dioxane alkali ne-aqueous solution. Meanwhile, the structures of the cationic starch derivatives are characterized by elemental analyses, FTIR spectroscopy, X-ray diffraction, and C-13 NMR spectroscopy, as well as by SEM techniques.

Architectures of Strontium Hydroxyapatite Microspheres: Solvothermal Synthesis and Luminescence Properties

Strontium hydroxyapatite (Sr-5(PO4)(3)OH, SrHAp) microspheres with 3D architectures have been successfully prepared through a efficient and facile solvothermal process. The experimental results indicate that the SrHAP microspheres are composed of a large amount of nanosheets, which are assembled in a radial form from the center to the surface of the microspheres. The as-obtained SrHAp samples show an intense and bright blue emission from 350 to 570 nm centered at 427 nm (CIE coordinates: x = 0.153, y = 0.081; lifetime: 9.2 ns; quantum efficiency: 31%) under long-wavelength UV light excitation (344 nm). This blue emission might result from the CO2 center dot- radical impurities in the crystal lattice. Furthermore, the surfactants CTAB and trisodium citrate have an obvious impact on the morphologies and the luminescence properties of the products, respectively.

Preparation of SrAl2O4:Eu2+, Dy3+ fibers by electrospinning combined with sol-gel process

One-dimensional SrAl2O4:Eu2+, Dy3+ fibers were fabricated by a simple electrospinning combined with sol-gel process. X-ray diffraction, Fourier transform infrared spectroscopy, scanning electron microscopy, transmission electron microscopy and photoluminescence were used to characterize the fibers. The results show that the phase structure of SrAl2O4:Eu2+, Dy3+ belongs to a monoclinic one, the composite fibers and fibers calcined at high temperature remain the original one-dimensional texture, and the SrAl2O4:Eu2+, Dy3+ was a green emission. (C) 2010 Elsevier Inc. All rights reserved.

Theoretical investigation of 5D-metal monocarbide

Bond distances, vibrational frequencies, electron affinities, ionization potentials and dissociation energies of the title molecules in neutral, positively and negatively charged ions were studied by use of density functional method. The calculated results were compared with previous theoretical and experimental studies. Ground states for each molecule were assigned. It was found that for some molecules, low-lying state, in which the energy is much close to the ground state, was obtained. In this case, further studies both experimentally and theoretically are necessary in order to find the true global minimum.

CPE-g-HEA/TDI热塑性弹性体的制备和性能研究

采用氯化原位接枝法合成主链为氯化聚乙烯(CPE)、支链为丙烯酸-2-羟基乙酯（HEA）的官能化接枝聚合 物(CPE-g-HEA),制备CPE-g-HEA/2,4-二异氰酸甲苯酯（TDI）热塑性弹性体,并对其性能进行研究。结果表明, CPE-g-HEA/TDI热塑性弹性体的物理性能较好;与溶液法产物相比,共混法CPE-g-HEA/TDI热塑性弹性体的强度 较大、相对分子质量较小、相对分子质量分布较宽,热行为基本无变化;共混法CPE-g-HEA/TDI热塑性弹性体的反 应温度应控制在60～70℃,共混次数(即打三角包次数) 为150次时拉伸强度较高、80次时拉断伸长率较高,HEA/TDI摩尔比为1/0.5时拉伸强度较高。

Negative differential resistance and memory effect in diodes based on 1,4-dibenzyl C60 and zinc phthalocyanine doped polystyrene hybrid material

Negative differential resistance (NDR) and memory effect were observed in diodes based on 1,4-dibenzyl C60 (DBC) and zinc phthalocyanine doped polystyrene hybrid material. Certain negative starting sweeping voltages led to a reproducible NDR, making the hybrid material a promising candidate in memory devices. It was found that the introduction of DBC enhanced the ON/OFF current ratio and significantly improved the memory stability. The ON/OFF current ratio was up to 2 orders of magnitude. The write-read-erase-reread cycles were more than 10(6), and the retention time reached 10 000 s without current degradation.

EPDM增韧PET的研究

在引发剂过氧化二异丙苯(DCP)的作用下,通过添加少量界面增容剂苯乙烯(St)提高接枝率,使甲基丙烯酸缩水甘油酯(GMA)与(乙烯/丙烯/二烯)共聚物(EPDM)反应,得到接枝物EPDM-g-GMA,将EPDM-g-GMA与PET共混,以提高共混体系的冲击强度。探讨了不同含量的EPDM-g-GMA对共混体系力学性能的影响。结果表明,随着EPDM-g-GMA含量的增加,共混体系的缺口冲击强度显著提高,当其含量为50％时,材料的缺口冲击强度为344.9J/m,约为纯PET的12倍;拉伸强度、弯曲强度和弯曲弹性模量出现一定程度的下降;EPDM-g-GMA含量为20％～30％时,材料的综合力学性能较好。

以亚磷酸二乙酯为第三组分的铁系催化体系催化异戊二烯聚合

以乙酰丙酮铁 (简称Fe) /三异丁基铝 (简称Al) /亚磷酸二烷基酯 (简称DP)为催化体系 ,对异戊二烯进行聚合 ,考察了不同DP(烷基为甲基、乙基、正丁基或异辛基 )、催化剂组成及反应条件对聚合的影响。结果表明 ,以亚磷酸二乙酯 (DEP)为第三组分的催化体系 ,在己烷中于相对较高温度 (5 0℃ )下的催化活性最高。催化剂最佳配比为Al/Fe(摩尔比 ) 1 5 ,DEP/Fe(摩尔比 ) 2 0。所得聚异戊二烯橡胶的 3 ,4-结构(含 1 ,2 -结构 )摩尔分数约为 60 % ,微观结构基本不受反应条件的影响。