Accumulation rates and grain sizes of eolian dust in sediments of the Intertropical Convergence Zone in the northeast Pacific

A 328 cm-long piston core (KODOS 02-01-02) collected from the northeast equatorial Pacific at 16°12'N, 125°59'W was investigated for eolian mass fluxes and grain sizes to test these proxies as a tool for the paleo-position of the Intertropical Convergence Zone (ITCZ). The eolian mass fluxes of the lower interval below 250 cm (15.5-7.6 Ma) are very uniform at 5 +/- 1 mg/cm**2/kyr, while those of the upper interval above 250 cm (from 7.6 Ma) are over 2 times higher than the lower interval at 12 +/- 1 mg/cm**2/kyr. The median grain size of the eolian dusts in the lower interval increases from 8.4 Phi to 8.0 Phi downward, while that of the upper interval varies in a narrow range from 8.8 Phi to 8.6 Phi. The determined values compare well in magnitude to those of central Pacific sediments for the upper interval and equatorial and southeast Pacific sediments for the lower interval. This result suggests a possibility that the study site had been under the influence of southeast trade winds at its earlier depositional period due to the northerly position of the ITCZ, and subsequently of the northeast trade winds for a later period when the upper sediments were deposited. This interpretation is consistent with a mineralogical and geochemical study published elsewhere that assigned the provenance of the study core dust to Central/South America for the lower interval and to Asia for the upper interval. This study suggests that the distinct differences in eolian mass flux and grain size observed across the ITCZ can be used to trace the paleo-latitude of the ITCZ.

Sediment grain size and carbon/carbonate at DSDO Leg 55 Holes

CaCO3 content was determined on board ship by the "Karbonat Bomb" technique (Müller and Gastner, 1971). In this simple procedure, a sample is powdered and treated with HCl in a closed cylinder. Any resulting CO2 pressure is proportional to the CaCO3 content of the sample. Application of the calibration factor to the manometer reading (x 100) yields per cent CaCO3. The error can be as low as 1 per cent for sediments high in CaCO3, and in general an accuracy of ±2 to 5 per cent can be obtained.

Grain size and diatom valves in sediment cores KS82-30 and KS82-31

Diatoms were studied quantitatively in six latest Quaternary (~70 kyr B.P. to Recent) piston cores from the westernmost Mediterranean, the Alboran Basin, and the Atlantic region immediately to the west of the Straits of Gibraltar. The Atlantic cores completely lack diatoms. In the Alboran Basin, diatoms are common from late Stage 3 (~27.5 kyr B.P.) to Termination lb (9 kyr B.P.) and in Recent core tops, but are absent in the other latest Quaternary intervals. Maximum accumulation of diatoms and highest abundance of species normally in sediments associated with increased productivity occurred during the latest Quaternary deglaciation, in the first phase of Termination I (~14.8 kyr B.P.). In the modern Alboran Basin, a region of high biological productivity occurs immediately east of the Gibraltar Straits. This high productivity results from upwelling associated with the interaction between the Atlantic inflow and the bottom topography near the Spanish coast. The upwelled nutrient-rich waters are then advected to the east and southeast by the surficial anticyclonic gyral circulation. Late Quaternary variations in diatom abundance are considered to reflect changes in this upwelling intensity with highest diatom abundances inferred to result from increased upwelling associated with an intensification of the anticyclonic gyral circulation. Highest inferred upwelling rates occurred during the first phase of latest Quaternary deglaciation. It is possible that an intensification of circulation within the Mediterranean Basin as a whole occurred from late Stage 3 to mid Termination I because widespread hiatus formation has been reported at this time in the Straits of Sicily due to an increase in the formation of intermediate waters. Diatoms were not preserved in other latest Quaternary intervals due to insufficient productivity to counterbalance their dissolution.

Grain counts and XRD mineralogy of turbidite sand and hemipelagic mud from ODP Leg 168 sites

Sequences of late Pliocene to Holocene sediment lap onto juvenile igneous crust within 20 km of the Juan de Fuca Ridge in northwestern Cascadia Basin, Pacific Ocean. The detrital modes of turbidite sands do not vary significantly within or among sites drilled during Leg 168 of the Ocean Drilling Program. Average values of total quartz, total feldspar, and unstable lithic fragments are Q = 35, F = 35, and L = 30. Average values of monocrystalline quartz, plagioclase, and K-feldspar are Qm = 46, P = 49, and K = 5, and the average detrital modes of polycrystalline quartz, volcanic-rock fragments, and sedimentary-rock plus metamorphic-rock fragments are Qp = 16, Lv = 43, and Lsm = 41. Likely source areas include the Olympic Peninsula and Vancouver Island; sediment transport was focused primarily through the Strait of Juan de Fuca, Juan de Fuca Channel, Vancouver Valley, and Nitinat Valley. Relative abundance of clay minerals (<2-µm-size fraction) fluctuate erratically with depth, stratigraphic age, and sediment type (mud vs. turbidite matrix). Mineral abundance in mud samples are 0%-35% smectite (mean = 8%), 18%-59% illite (mean = 40%), and 29%-78% chlorite + kaolinite (mean = 52%). We attribute the relatively low content of smectite to rapid mechanical weathering of polymictic source terrains, with little or no input of volcanic detritus from the Columbia River. The scatter in clay mineralogy probably was caused by converging of surface currents, turbidity currents, and near-bottom nepheloid clouds from several directions, as well as subtle changes in glacial vs. interglacial weathering products.

Grain shape of sediment from the Weddell Sea

Very fine quartz sand was examined from Paleogene and Neogene sediments of ODP Sites 693, 694, 695, 696, and 697 to determine their grain roundness using Fourier analysis and SEM surface texture characteristics. The objective of this study was to identify grain roundness and surface texture characteristics unique to East (Site 693) and West (Sites 695, 696, and 697) Antarctica and to glacial regimes. Once identified, these distinguishing features could then be used to determine changes in source area and glacial conditions in the central Weddell Sea Basin (Site 694). Three end members of very fine quartz sand are recognized in the Oligocene to Pleistocene sediments of the Weddell Sea: angular, rounded, and intermediate. End member 1 (angular) consists of extremely angular grains with numerous fracture textures. Previous investigations suggested that these sands are derived from crystalline rocks that fractured during formation or deformation and/or were exposed to weathering by ice. In this study, however, the correlation of angularity with ice activity is problematical as the most angular sands were recovered in the lower Oligocene sediments of the South Orkney Microcontinent, a period of temperate climatic conditions. End member 3 (rounded) consists of rounded grains with chemically and mechanically produced surface textures. These sands are presumed to be derived from the Beacon-type rocks in East Antarctica and the sedimentary deposits of the Northern Antarctic Peninsula. End member 2 (intermediate) grains display crystalline nodes and grain embayments. They are thought to be derived from felsic intrusives, East Antarctic quartzites, basement metamorphics of the South Orkney Microcontinent, and/or the Andean intrusive series of West Antarctica. Unfortunately, no features unique to either the East or West Antarctic sediment sources or to glacial conditions could be isolated. Therefore, the objective of determining provenance changes and sediment erosion and transport mechanisms could not be achieved using this approach.

Physical properties, grain size distribution and clay mineralogy of ODP Leg 117 sites

The fabric of sediments recovered at sites drilled on the Indus Fan, Owen Ridge, and Oman margin during Ocean Drilling Program Leg 117 was examined by scanning electron microscopy to document changes that accompany sediment burial. Two sediment types were studied: (1) biogenic sediments consisting of a variety of marly nannofossil and nannofossil oozes and chalks and (2) terrigenous sediments consisting of fine-grained turbidites deposited in association with the Indus Fan. Biogenic sediments were examined with samples from the seafloor to depths of 306 m below seafloor (mbsf) on the Owen Ridge (Site 722) and 368 mbsf on the Oman margin (Sites 723 and 728). Over these depth ranges the biogenic sediments are characterized by a random arrangement of microfossils and display little chemical diagenetic alteration. The microfossils are dispersed within a fine-grained matrix that is predominantly microcrystalline carbonate particles on the Owen Ridge and clay and organic matter on the Oman margin. Sediments with abundant siliceous microfossils display distinct, open fabrics with high porosity. Porosity reduction resulting from gravitational compaction appears to be the primary process affecting fabric change in the biogenic sediment sections. Fabric of illite-rich clayey silts and silty claystones from the Indus Fan (Site 720) and Owen Ridge (Sites 722 and 731) was examined for a composite section extending from 45 to 985 mbsf. In this section fabric of the fine-grained turbidites changes from one with small flocculated clay domains, random particle arrangement, and high porosity to a fabric with larger domains, strong preferred particle orientation roughly parallel to bedding, and lower porosity. These changes are accomplished by a growth in domain size, primarily through increasing face-to-face contacts, and by particle reorientation which is characterized by a sharp increase in alignment with bedding between 200 and 400 mbsf. Despite extensive particle reorientation, flocculated clay fabric persists in the deepest samples examined, particularly adjacent to silt grains, and the sediments lack fissility. Fabric changes over the 45-985 mbsf interval occur in response to gravitational compaction. Porosity reduction and development of preferred particle orientation in the Indus Fan and Owen Ridge sections occur at greater depths than outlined in previous fabric models for terrigenous sediments as a consequence of a greater abundance of silt and a greater abundance of illite and chlorite clays.

Grain size, mineral and chemical compositions of modern deposits fron the northern Caspian Sea and the Volga River delta

Comprehensive investigations revealed that modern deposits in the northern Caspian Sea involve terrigenous sands and aleurites with admixture of detritus and intact bivalve shells, including coquina. Generally, these deposits overlay dark grayish viscous clays. Similar geological situation occurs in the Volga River delta; however, local deposits are much poorer in biogenic constituents. Illite prevails among clay minerals. In coarse aleurite fraction (0.100-0.050 mm) heavy transparent minerals are represented mostly by epidotes, while light minerals - mostly by quartz and feldspars. Sedimentary material in the Volga River delta is far from completely differentiated into fractions due to abundant terrigenous inflows. Comparatively better grading of sediments from the northern Caspian Sea is due to additional factors such as bottom currents and storms. When passing from the Volga River delta to the northern Caspian Sea, sediments are enriched in rare earth elements (except Eu), Ca, Au, Ni, Se, Ag, As, and Sr, but depleted in Na, Rb, Cs, K, Ba, Fe, Cr, Co, Sc, Br, Zr, ??, U, and Th. Concentrations of Zn remain almost unchanged. Sedimentation rates and types of recent deposits in the northern Caspian Sea are governed mainly by abundant runoff of the Volga River.