Barium in sediments and pore waters of several ODP Leg 170 and Leg 205 sites

Barium concentrations were measured on 17 pore fluid and 13 sediment samples from Sites 1253 and 1254 drilled offshore Costa Rica during Ocean Drilling Program (ODP) Leg 205. An additional 83 pore fluid and 29 sediment samples were analyzed for Ba concentrations from Sites 1039 and 1040 drilled during ODP Leg 170 offshore Costa Rica. Sites 1039/1253 and 1040/1254 are part of a transect across the Middle America Trench offshore Nicoya Peninsula. The entire incoming sediment section is being underthrust beneath the margin, providing an ideal setting to examine Ba cycling in the shallow levels of the subduction zone. Results from these analyses indicate that a significant amount of Ba is liberated from the mineral barite (BaSO4) in the uppermost hemipelagic sediments arcward of the trench. The shallow distillation of Ba may impact the amount of sedimentary Ba reaching the deeper subduction zone.

Calcium isotopes in planktonic foraminifera - core tops and sediment trap samples

For paleoceanographic studies, it is important to understand the processes that influence the calcium (Ca) isotopic composition of foraminiferal calcite tests preserved in the sediment record. Seven species of planktonic foraminifera from coretop sediments collectively exhibited a Ca temperature dependent fractionation of 0.013 per mil per °C. This is in agreement with previously published estimates for most species of planktonic foraminifera as well as biogenic and inorganic calcite and aragonite. Four species of planktonic foraminifera collected from a sediment trap showed a considerable amount of scatter and no consistent temperature dependent fractionation. Analyzed size fractions of coretop samples show no significant relationship with d44/40Ca. However, preliminary results suggest that the symbiotic and spinose foraminifera G. sacculifer might exhibit a relationship between test size and d44/40Ca. A one-box model in which Ca isotopes are allowed to fractionate by Rayleigh distillation from a biomineralization reservoir (internal pool) was used to constrain the isotopic composition of the original biomineralization Ca reservoir, assuming around 85% of the Ca reservoir is precipitated and the fractionation factor during precipitation is 0.9985 + 0.00002(T ºC). To explain the foraminiferal Ca isotope data, this model indicates that the Ca isotopic composition of the biomineralization reservoir is offset from seawater (approximately -0.8per mil).

Ex situ sulphate reduction rates of sediment at the rim of a vesicomyd clam colony in the Japan Deep Sea Trench (dive 955)

Sediment samples were collected from the rim of a large vesicomyid clam colony in the Japan Deep Sea Trench. Immediately after sample recovery onboard, the sediment core was sub-sampled for ex situ rate measurements. Sulfate reduction were measured ex situ by the whole core injection method with three replicates. We incubated the samples at in situ temperature (1.5°C) for 48 hours with carrier-free 35SO4 (dissolved in water, 50 kBq). Sediment was fixed 20 ml ZnAc solution (20%, w/v) for AOM or SR. Turnover rates were measured as previously described (Kallmeyer et al., 2004).

Ex situ sulphate reduction rates of sediment at the rim of a vesicomyd clam colony in the Japan Deep Sea Trench (dive 957)

Sediment samples were collected from the rim of a large vesicomyid clam colony in the Japan Deep Sea Trench. Immediately after sample recovery onboard, the sediment core was sub-sampled for ex situ rate measurements. Sulfate reduction were measured ex situ by the whole core injection method with three replicates. We incubated the samples at in situ temperature (1.5°C) for 48 hours with carrier-free 35SO4 (dissolved in water, 50 kBq). Sediment was fixed 20 ml ZnAc solution (20%, w/v) for AOM or SR. Turnover rates were measured as previously described (Kallmeyer et al., 2004).

The Shrimp Export Boom and Small-Scale Fishermen in Myanmar

This paper examines the impact of the recent shrimp export boom in Myanmar on the economic state of small-scale fishermen. Results indicate that there has been an active increase in shrimp fishing stimulated by expanding export demand. With this, the income of shrimp fishermen has increased dramatically in the past 10 years. However, future prospects appear gloomy due to the possibility of over exploitation of shrimp resources.

Political limits on the world oil trade : firm-level evidence from US firms

International politics affect trade patterns, especially for firms in extractive industries. We construct the firm-level dataset for the U.S. oil-importing companies over 1986-2010 to test whether the state of international relations with the trading partners of the U.S. affect importing behavior of the U.S. firms. To measure "political distance" between the U.S. and her trading partners we use voting records for the UN General Assembly. We find that the U.S. firms, in fact, import significantly less oil from the political opponents of the U.S. Our conjecture is that the decrease in oil imports is mainly driven by large, vertically-integrated U.S. firms that engage in foreign direct investment (FDI) overseas.

Perspectiva jurídica de la gestión y conservación de los recursos pesqueros en España. La pesca-turismo como opción de futuro

El objetivo de la presente Tesis está dirigido a analizar diversas opciones de diversificación que la pesca marítima profesional puede tener, poniendo el acento en el respeto al medio ambiente. En concreto la Pesca-turismo aparece como una de las alternativas más viables tanto por su respeto al medio ambiente como por su relativamente sencilla posibilidad de implantación en España. A fin de poder desarrollar la misma se proponen los cambios legislativos necesarios para su implantación en nuestro país procediéndose, para ello, al estudio de la situación actual de la actividad pesquera en nuestro país desde un punto de vista jurídico, con una especial consideración de la gestión y conservación de los recursos pesqueros. El estudio de su posible implantación en España, comienza analizando cuáles son las diferentes administraciones que influyen en dicha actividad y en qué medida lo hacen, tanto en el ámbito nacional como en el supranacional, con una especial referencia a la Unión Europea, así como la organización de las mismas. Acto seguido se procede al examen, tanto de la normativa sobre la materia, como de la jurisprudencia y la doctrina aplicables a la actividad de pesca marítima en España para, una vez llevado a cabo dicho estudio, comenzar con el examen de los requisitos exigidos, ya sean éstos de índole material o humana, a aquéllos que quieran llevarla a cabo. A continuación, se estudia el régimen de infracciones y sanciones, entrando, por último, en el terreno más propiamente de conservación de los recursos, donde se examinan las medidas que, a tal fin, se encuentran en nuestro ordenamiento jurídico. Más adelante se analiza, siquiera sea brevemente, la pesca deportiva, que, aunque con una incidencia muy inferior, no deja de ser otra forma de actividad extractiva. La existencia de otras experiencias parecidas a la propuesta de pesca-turismo en el ámbito internacional es objeto de estudio a fin de determinar cuál es la situación en otros países donde se hayan implantado con anterioridad. Para ello se lleva a cabo un análisis de las distintas soluciones que a este mismo problema se han dado en otros países también con amplia tradición en este campo procediendo, a tal fin, a un estudio de la legislación sobre la pesca-turismo, fundamentalmente en Italia, pero también en Francia y Portugal. A la vista de cuanto antecede es posible concluir que al día de hoy no es factible la realización de las actividades de Pesca-turismo con los instrumentos jurídicos de los que se dispone en España, dado que existen puntos sustanciales en los mismos que o bien impiden o bien no permiten su desarrollo. Por tanto el planteamiento de tales actividades necesariamente conlleva una serie de modificaciones normativas. El siguiente paso y en relación con las modificaciones normativas a efectuar, se ofrece un texto alternativo al texto legal a modificar (Ley 3/2001 de Pesca Marítima del Estado) y al Real Decreto 1027/1989, mientras que se dejan efectuados los apuntes precisos de cual debería de ser el marco reglamentario que, en desarrollo de las modificaciones anteriores, posibilitasen el ejercicio de la Pesca-turismo en España. Por último se ha optado por efectuar un análisis de la opinión del sector, tendente a verificar si los datos obtenidos empíricamente quedaban asimismo reflejados en las actitudes de los destinatarios finales de tales normas, que no serían otros que los pescadores profesionales. A tal fin se ha procedido a recoger las opiniones de diversos colectivos del sector, a través tanto de las cofradías de pescadores como de las Federaciones, acerca de las actividades de pesca-turismo, buscando la representación de todas las zonas geográficas. Fruto de tal investigación se ha llegado a la conclusión de que el desarrollo de las actividades propuesta de pescaturismo cuenta con una opinión favorable dentro del sector que, con una mayoría aplastante se manifestó a favor de desarrollar la posibilidad de ejercicio de la mismas. SUMMARY The objective of this thesis is aimed to analyze various options of diversification that commercial maritime fishing can have, with an emphasis on respect for the environment. Specifically, fishing-tourism appears as one of the most viable alternatives because of its environmental friendliness as well by its relatively simple possibility of implementation in Spain In order to develop it, it is proposed the necessary changes legislative for implementation in our country proceeding to study of the current situation of fisheries in our country from a legal perspective, with special consideration of the management and conservation of fisheries resources. The study of their possible implementation in Spain, begins by analyzing which are the different administrations that influence in that activity and to what extent they do, both at the national field as well at the supranational field, with special reference to the European Union and organization of thereof. Then proceeds to an examination, both of the relevant legislation as well as of the jurisprudence and doctrine applicable to maritime fishing in Spain for, once conducted this study, to begin with the consideration of the requirements, be they human or material, to those who want to carry out. Then studies the regime of offences and penalties, entering, finally, in the field conservation of resources, where discusses measures which, to this end, are in our legal system Later analyzes, even briefly, sport fishing, which, although with a much lower incidence, it is another form of extractive activity. The existence of other similar experiences to the proposal of fishing-tourism in the international arena is object of study in order to determine which is the situation in other countries where it has been implemented previously. For that it is carried out an analysis of the different solutions that to this same problem have been given in other countries with long tradition in this field, to proceed to study about legislation on fishing-tourism, fundamentally in Italy, but also in France and Portugal In view of the above it can be concluded that today is not feasible to implement the fishing-tourism activities with the legal instruments that are available in Spain, as there are substantial points which prevent them or not allows its development. Therefore the approach to such activities necessarily entails a series of normatives changes. The next step and in relation to normatives changes to do, it is offered an alternative text to the legal text to modify (Law 3/2001 of the State Marine Fisheries) and to the Royal Decree No. 1027 / 1989, while we leave made accurate notes about which ought be the reglamentary framework that, in developing of the above modifications, can be enable exercise of fishing-tourism in Spain. Finally, it is been opted to carry out an analysis of the opinion of the sector, aimed at verifying if data obtained empirically were also reflected in the attitudes of the final recipients of such standards, who would not be other than the professional fishermen. For this purpose it has been collected the opinions of various groups of the sector, through of fishermen's associations and federations, about of the activities of tourism-fishing, looking for the representation of all geographical areas. The result of such an investigation has concluded that the development of this proposed activities fishing-tourism has a positive opinion within the sector because an overwhelming majority was in favor of developing the possibility of exercise of the same.

Biokerosene from Babassu and Camelina Oils: production and properties of their blends with fossil kerosene

Babassu and camelina oils have been transesterified with methanol by the classical homogeneous basic catalysis method with good yields. The babassu fatty acid methyl ester (FAME) has been subjected to fractional distillation at vacuum, and the low boiling point fraction has been blended with two types of fossil kerosene, a straight-run atmospheric distillation cut (hydrotreated) and a commercial Jet-A1. The camelina FAME has been blended with the fossil kerosene without previous distillation. The blends of babassu biokerosene and Jet-A1 have met some of the specifications selected for study of the ASTM D1655 standard: smoke point, density, flash point, cloud point, kinematic viscosity, oxidative stability and lower heating value. On the other hand, the blends of babassu biokerosene and atmospheric distillation cut only have met the density parameter and the oxidative stability. The blends of camelina FAME and atmospheric distillation cut have met the following specifications: density, kinematic viscosity at −20 °C, and lower heating value. With these preliminary results, it can be concluded that it would be feasible to blend babassu and camelina biokerosenes prepared in this way with commercial Jet-A1 up to 10 vol % of the former, if these blends prove to accomplish all the ASTM D1655-09 standards.

Viabilidad técnica para la explotación y separación isotópica de Li y prospectiva en el mercado de baterías de ION-7Li y de 6Li como material base de diseño en reactores de fusión nuclear

En claro alineamiento con estrategias de sostenibilidad en el uso de recursos naturales en un escenario constante de aumento de la demanda energética mundial, el desarrollo de la tecnología energética en la Historia de la Especie Humana muestra un vector de evolución permanente desde su origen en el sentido del desarrollo y uso de nuevas fuentes energéticas con la explotación de recursos naturales de manera más eficiente: soluciones energéticas con aumento de la densidad energética (exoenergía de proceso por unidad de masa de recurso natural). Así el cambio de escala en la demanda de explotación del Litio como recurso natural se viene presentando en la última década ligada al desarrollo del mercado de las baterías "ion-Litio" y los requisitos de combustible (Deuterio y Litio) en el camino de la fusión nuclear como opción energética próxima. El análisis anticipado de las demandas sinérgicas a escala de ambos mercados aparece de enorme interés prospectivo en sus aspectos técnicos: (1) tecnologías de base para la extracción mineral y de agua marina y (2) su enriquecimiento isotópico (de interés sinérgico; 7Li para baterías eficientes ion-litio; 6Li como regenerador de tritio en ciclo de combustible en fusión nuclear) a la vez que en sus aspectos económicos. Este Proyecto realiza: (1) un ejercicio de análisis prospectivo de la demanda y de mercado para el enriquecimiento 6Li/7Li para las próximas décadas, (2) se califican los desarrollos tecnológicos específicos que van a poder permitir la producción a escala conforme a la demanda; (3) se selecciona y califica una técnica [de centrifugación / termo-difusión/ destilación combinada] como opción tecnológicamente viable para la producción a escala de formas litiadas; (4) se propone un diseño conceptual de planta de producción y finalmente (5) propone un estudio de viabilidad para la demostración de proceso y construcción de dicha planta de demostración de la nueva capacidad tecnológica. ABSTRACT Clearly aligned with sustainability strategies under growing world energy demand in the use of natural resources the development of energy technology in the history of the human species shows a vector of ongoing evolution from its origin in the sense of the development and use of new energy sources with the exploitation of natural resources in a more efficient manner. The change of scale in the demand for exploitation of Lithium as a natural resource appears during the last decade as bound to the deployment of "lithium-ion" batteries market and to the Nuclear Fusion fuels (deuterium and lithium) supply scaled demands. The prospective analysis of demands to scale in both markets appears in scene with huge prospective interest in its technical aspects: (1) base technologies for mineral and water marine extraction (2) its isotopic enrichment (synergistic interests; 7Li efficient battery Li-ion; 6Li as fusion nuclear fuel breeder (tritium) as well as in its economic aspects. This Project: (1) propose a prospective analysis exercise of the synergistic supply demand for coming decades for the enrichment of 6Li and 7Li, (2) qualifies specific technological developments ongoing to respond to supply demand; (3) select and qualifies an appropriate technique [combined centrifugation/thermo-diffusion/distillation] as technologically viable option for lithiated forms scaled-production; (4) proposes a conceptual design of production plant based on the technique and finally (5) proposes a feasibility study for the process demonstration and construction of this new technological capability Demonstration Plant.

Control of integrated unit operations

As a thermal separation method, distillation is one of the most important technologies in the chemical industry. Given its importance, it is no surprise that increasing efforts have been made in reducing its energy inefficiencies. A great deal of research is focused in the design and optimization of the Divided-Wall Column. Its applications are still reduced due to distrust of its controllability. Previous references studied the decentralized control of DWC but still few papers deal about Model Predictive Control. In this work we present a decentralized control of both a DWC column along with its equivalent MPC schema.

Efficient management of available technologies. Aplication to mining operations for industry supplies

Nowadays, processing Industry Sector is going through a series of changes, including right management and reduction of environmental affections. Any productive process which looks for sustainable management is incomplete if Cycle of Life of mineral resources sustainability is not taken into account. Raw materials for manufacturing are provided by mineral resources extraction processes, such as copper, aluminum, iron, gold, silver, silicon, titanium? Those elements are necessary for Mankind development and are obtained from the Earth through mineral extractive processes. Mineral extraction processes are operations which must take care about the environmental consequences. Extraction of huge volumes of rock for their transformation into raw materials for industry must be optimized to reduce ecological cost of the final product as l was possible. Reducing the ecological balance on a global scale has no sense to design an efficient manufacturing in secondary industry (transformation), if in first steps of the supply chain (extraction) impact exceeds the savings of resources in successive phases. Mining operations size suggests that it is an environmental aggressive activity, but precisely because of its great impact must be the first element to be considered. That idea implies that a new concept born: Reduce economical and environmental cost This work aims to make a reflection on the parameters that can be modified to reduce the energy cost of the process without an increasing in operational costs and always ensuring the same production capacity. That means minimize economic and environmental cost at same time. An efficient design of mining operation which has taken into account that idea does not implies an increasing of the operating cost. To get this objective is necessary to think in global operation view to make that all departments involved have common guidelines which make you think in the optimization of global energy costs. Sometimes a single operational cost must be increased to reduce global cost. This work makes a review through different design parameters of surface mining setting some key performance indicators (KPIs) which are estimated from an efficient point of view. Those KPIs can be included by HQE Policies as global indicators. The new concept developed is that a new criteria has to be applied in company policies: improve management, improving OPERATIONAL efficiency. That means, that is better to use current resources properly (machinery, equipment,?) than to replace them with new things but not used correctly. As a conclusion, through an efficient management of current technologies in each extractive operation an important reduction of the energy can be achieved looking at downstream in the process. That implies a lower energetic cost in the whole cycle of life in manufactured product.

Quantum key distribution based on selective post-processing in passive optical networks

One of the main obstacles to the widespread adoption of quantum cryptography has been the difficulty of integration into standard optical networks, largely due to the tremendous difference in power of classical signals compared with the single quantum used for quantum key distribution. This makes the technology expensive and hard to deploy. In this letter, we show an easy and straightforward integration method of quantum cryptography into optical access networks. In particular, we analyze how a quantum key distribution system can be seamlessly integrated in a standard access network based on the passive optical and time division multiplexing paradigms. The novelty of this proposal is based on the selective post-processing that allows for the distillation of secret keys avoiding the noise produced by other network users. Importantly, the proposal does not require the modification of the quantum or classical hardware specifications neither the use of any synchronization mechanism between the network and quantum cryptography devices.

Oxygen extended sooting index of FAME blends with aviation kerosene

The use of biofuels in the aviation sector has economic and environmental benefits. Among the options for the production of renewable jet fuels, hydroprocessed esters and fatty acids (HEFA) have received predominant attention in comparison with fatty acid methyl esters (FAME), which are not approved as additives for jet fuels. However, the presence of oxygen in methyl esters tends to reduce soot emissions and therefore particulate matter emissions. This sooting tendency is quantified in this work with an oxygen-extended sooting index, based on smoke point measurements. Results have shown considerable reduction in the sooting tendency for all biokerosenes (produced by transesterification and eventually distillation) with respect to fossil kerosenes. Among the tested biokerosenes, that made from palm kernel oil was the most effective one, and nondistilled methyl esters (from camelina and linseed oils) showed lower effectiveness than distilled biokerosenes to reduce the sooting tendency. These results may constitute an additional argument for the use of FAME’s as blend components of jet fuels. Other arguments were pointed out in previous publications, but some controversy has aroused over the use of these components. Some of the criticism was based on the fact that the methods used in our previous work are not approved for jet fuels in the standard methods and concluded that the use of FAME in any amount is, thus, inappropriate. However, some of the standard methods are not updated for considering oxygenated components (like the method for obtaining the lower heating value), and others are not precise enough (like the methods for measuring the freezing point), whereas some alternative methods may provide better reproducibility for oxygenated fuels.

Blends of babassu, palm kernal and coconut mame with fossil kerosene: low carbon number methyl esters as a possible source for renewable jet fuel

Three different oils: babassu, coconut and palm kernel have been transesterified with methanol. The fatty acid methyl esters (FAME) have been subjected to vacuum fractional distillation, and the low boiling point fractions have been blended with fossil kerosene at three different proportions: 5, 10 and 20% vol.