Sediment geochemical evidence for an early-middle Gilbert (early Pliocene) productivity peak in the North Pacific Red Clay Province

Current attempts to understand climatic variability during the early to middle Pliocene require paleoceanographic information from the Pacific and Indian Oceans that may serve to test and/or constrain future circulation models. Ocean Drilling Program (ODP) Sites 885/886 are located in the central subarctic North Pacific at water depths exceeding 5700 m. Recent studies of rock magnetic properties suggest that the fine-grained Fe oxide component in sediment at Sites 885/886 experienced reductive dissolution during the early-middle Gilbert. Because such an interval in the North Pacific Red Clay Province suggests a maximum in the sedimentary flux of organic carbon and/or a minimum in bottom water dissolved O2 concentrations (and hence, a peak change in North Pacific oceanographic conditions), a geochemical investigation was conducted to test the hypothesis. Quaternary sediment at Hole 886B was subjected to an oxyhydroxide removal procedure, and chemical analyses indicate that bulk sediment concentrations of Fe and the Fe/Sc ratio decrease significantly upon reductive dissolution. Downcore chemical analyses of untreated sediment at Hole 886B demonstrate that similar depletions also occur across the proposed interval of reduced sediment. Downcore chemical analyses also indicate that a pronounced increase in the Ba/Sc ratio occurs across the interval. These results are consistent with an interpretation that abyssal sediment of the North Pacific experienced a decrease in redox conditions during the early-middle Gilbert, and that this change in oxidation state was related to a peak in paleoproductivity. If the zenith of late Miocene to middle Pliocene enhanced productivity observed at other Indo-Pacific divergence regions similarly can be constrained to the early-middle Gilbert, there exists an oceanographic boundary condition in which to test future models concerning Pliocene warmth.

Clay mineralogy of ODP Site 188-1165

The Ocean Drilling Program Leg 188 Site 1165 was drilled on the Wild Drift on the Continental Rise off Prydz Bay, East Antarctica to a total depth of 999.1 meters below seafloor (mbsf). It recovered an extensive suite of terrigenous and hemipelagic sediments of early Miocene to Pleistocene age. Of special interest in this study is the sediment column between 0 and 50 mbsf, which consists of a well-preserved section of Pliocene-Pleistocene-age sediments that was sampled at 10-cm intervals. Multiproxy study of this interval could show possible intervals of expansions of the ice-sheet across the continental shelves and express the climatic evolution in Antarctica, particularly during the 'middle' Pliocene warm period (3.15 to 2.85 Ma) which may provide an indication of how the Earth responds to a rise of its surface temperature. According to the existing age model, the upper 50 mbsf stratigraphic sequence of Site 1165 reaches back to ~4.9 Ma. Throughout this interval, the clay-mineral content is characterized by fluctuations of individual clay minerals, particularly smectite and chlorite. The smectite concentration varies mainly between 0% and 30%. Illite fluctuates less between 50% and 80%, and kaolinite varies mainly between 10% and 20%. Chlorite concentrations are mainly 0% to 10%. There is also a noticeable change in magnetic susceptibility at ~34 mbsf that is clearly indicated in the composition of the clay-mineral suite. At this level, smectite decreases and illite, kaolinite and chlorite show some variability. In particular, there is a slight but persistent increase in chlorite. The results from the Plio-Pleistocene transition, with evenly fluctuating smectite and illite contents and the gradually increasing chlorite content, may indicate cooler conditions compared to the mid-Pliocene conditions. Slight increase in illite content and decrease in smectite content towards Pleistocene supports the previous assumption. The results from the mid-Pliocene with the increasing smectite content and decreasing illite content may indicate warmer and possibly interglacial conditions.