945 resultados para Chiral organophosphate pesticides


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We argue that the minimal chiral background for the two-pion exchange nucleon-nucleon (NN) interaction has nowadays a rather firm conceptual basis, which entitles it to become a standard ingredient of any modern potential. In order to facilitate applications, we present a parametrized version of a configuration space potential derived previously. We than use it to assess the phenomenological contents of some existing NN potentials.

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We study an exactly solvable two-dimensional model which mimics the basic features of the standard model. This model combines chiral coupling with an infrared behavior which resembles low energy QCD. This is done by adding a Podolsky higher-order derivative term in the gauge field to the Lagrangian of the usual chiral Schwinger model. We adopt a finite temperature regularization procedure in order to calculate the non-trivial fermionic Jacobian and obtain the photon and fermion propagators, first at zero temperature and then at finite temperature in the imaginary and real time formalisms. Both singular and non-singular cases, corresponding to the choice of the regularization parameter, are treated. In the nonsingular case there is a tachyonic mode as usual in a higher order derivative theory, however in the singular case there is no tachyonic excitation in the spectrum.

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Conselho Nacional de Desenvolvimento Científico e Tecnológico (CNPq)

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An automated on-line solid phase extraction procedure followed by liquid chromatography with diode array detection was investigated for the determination of different classes of pesticides in water samples containing varied amount of humic substances. The different pesticides used were: carbendazin, carbofuran, atrazine, diuron, propanil, molinate, alachlor, parathion-ethyl, diazinon, trifluralin and the degradation products deisopropylatrazine and deethylatrazine. Humic substances extracted from a Brazilian sediment were used from 5 to 80 mg/l and their influence on recoveries was evaluated in neutral and acidic media. Recoveries higher than 70% were obtained for all the pesticides, from the preconcentration of 75 mi of aqueous sample fortified at 2 ng/ml using precolumns packed with PLRP-S. Good recoveries were obtained at neutral pH for most of the analytes up to 40 mg/l of humic acid. Only at 80 mg/l the recoveries were significantly affected, both at acidic and neutral pH. The method was applied to the determination of pesticides in river water spiked at 0.1 to 1 ng/ml. Detection limits obtained for water containing 10 mg/l of humic acid were between 0.05 and 0.3 ng/ml.

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A simple and efficient method for the simultaneous gas chromatographic determination of ten organochlorine pesticides (alpha-HCH, beta-HCH, gamma-HCH, p,p'-DDT, o,p'-DDT, p,p'-DDD, p,p'-DDE, aldrin, endrin, and dieldrin) and six congeners of PCBs (PCB 28, 52, 118, 138, 153, and 180) in municipal solid waste compost is described. The procedure involves a solid-phase dispersion matrix using celite as dispersant sorbent, alumina as clean up sorbent and hexane-dichloromethane (7:3, v/v) mixture as eluting solvent. An additional purification step with copper was necessary to eliminate sulphur. Analysis of the sample was performed by GC-ECD. The method was validated with fortified samples at two concentration levels (0.025 and 0.05 mg kg(-1)). Average recovery ranged from 77 to 121% with relative standard deviation between 1 and 18%. The detection limits, which ranged from 0.003 to 0.01 mg kg-1, were lower than those established by the Baden-Wurttemberg directive (0.033 mg kg(-1)).

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Fundação de Amparo à Pesquisa do Estado de São Paulo (FAPESP)

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We extend the geometric treatment done for the Majorana-Weyl fermions in two dimensions by Sanielevici and Semenoff to chiral bosons on a circle. For this case we obtain a generalized Floreanini-Jackiw Lagrangian density, and the corresponding gravitational (or Virasoro) anomalies are found as expected. © 1989 The American Physical Society.

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We seek new couplings of chiral bosons to U(1) gauge fields. Lorentz covariance of the resulting constrained lagrangian is checked with the help of a procedure based in the first-order formalism of Faddeev and Jackiw. We find Harada's constraint and another local one not previously considered. We analyze the constraint structure and part of the spectrum of this second solution and show that it is equivalent to an explicitly covariant coupling of Siegel's chiral boson to gauge fields, which preserves chirality under gauge transformations.

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A small-scale method was developed for the simultaneous determination of γ-HCH, heptachlor, aldrin, dicofol, mirex, endosulfan I, endosulfan II and endosulfan sulphate in soil. The extraction and clean-up steps were combined into one step by transferring soil samples to chromatographic columns prepacked with neutral alumina. The pesticides elution was processed with n-hexane : dichloromethane (7:3) and the concentrated eluate was analysed using gas-liquid chromatography with electron capture detection. Analyses of the in vitro fortified samples with the selected pesticides were performed at three different levels. Mean recoveries for aldrin, γ-HCH and heptachlor, at levels of 2, 10 and 20 ng/g, ranged from 71 to 87%; for dicofol, at levels of 8, 40 and 80 ng/g, ranged from 97 to 103%; for endosulfan I and II, at levels of 5, 25 and 50 ng/g, ranged from 88 to 96%; for mirex, at levels of 6, 30 and 60 ng/g, ranged from 86 to 110%; and for endosulfan sulphate, at levels of 15, 75 and 150 ng/g, ranged from 93 to 104%. The method can be used for rapid determination of these pesticides in soil. © Springer-Verlag 1996.

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We study the chiral symmetry breaking in QCD, using an effective potential for composite operators, with infrared finite gluon propagators that have been found by numerical calculation of the Schwinger-Dyson equations as well as in lattice simulations. The existence of a gluon propagator that is finite at k2 = 0 modifies substantially the transition between the phases with and without chiral symmetry.

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A time-dependent projection technique is used to treat the initial-value problem for self-interacting fermionic fields. On the basis of the general dynamics of the fields, we derive formal equations of kinetic-type for the set of one-body dynamical variables. A nonperturbative mean-field expansion can be written for these equations. We treat this expansion in lowest order, which corresponds to the Gaussian mean-field approximation, for a uniform system described by the chiral Gross-Neveu Hamiltonian. Standard stationary features of the model, such as dynamical mass generation due to chiral symmetry breaking and a phenomenon analogous to dimensional transmutation, are reobtained in this context. The mean-field time evolution of nonequilibrium initial states is discussed.

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The phenomenology of a QCD-Pomeron model based on the exchange of a pair of non-perturbative gluons, i.e. gluon fields with a finite correlation length in the vacuum, is studied in comparison with the phenomenology of QCD chiral symmetry breaking, based on non-perturbative solutions of Schwinger-Dyson equations for the quark propagator including these non-perturbative gluon effects. We show that these models are incompatible, and point out some possibles origins of this problem.

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We compute the critical coupling constant for the dynamical chiral-symmetry breaking in a model of quantum chromodynamics, solving numerically the quark self-energy using infrared finite gluon propagators found as solutions of the Schwinger-Dyson equation for the gluon, and one gluon propagator determined in numerical lattice simulations. The gluon mass scale screens the force responsible for the chiral breaking, and the transition occurs only for a larger critical coupling constant than the one obtained with the perturbative propagator. The critical coupling shows a great sensibility to the gluon mass scale variation, as well as to the functional form of the gluon propagator.

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Recently, Basseto and Griguolo1 did a perturbative quantization of what they called a generalized chiral Schwinger model. As a consequence of the kind of quantization adopted, some gauge-dependent masses raised in the model. On the other hand, we discussed the possibility of introducing a generalized Wess-Zumino term,2 where such gauge-dependent masses did appear. Here we intend to show that one can construct a non-anomalous version of a model which include that, presented by Basseto and Griguolo as a particular case, by adding to it a generalized Wess-Zumino term, as proposed in Ref. 2. So we conclude that it is possible to construct a gauge-invariant extension of the model quoted in Ref. 1, and this can be done through a Wess-Zumino term of the type proposed in Ref. 2.