Sea surface temperature calculated from UK'37 and IP25 sea-ice biomarker of sediment core SO201-2-85KL

During the past decades, remarkable changes in sea-surface temperature (SST) and sea-ice extent have been observed in the marginal seas of the subarctic Pacific. However, little is known about natural climate variability at millennial time scales far beyond instrumental observations. Geological proxy records, such as those derived from marine sediments, offer a unique opportunity to investigate millennial-scale natural climate variability of the Artic and subarctic environments during past glacial-interglacial cycles. Here we provide reconstructions of sea-ice variability inferred from IP25 (Ice Proxy with 25 carbon atoms) sea-ice biomarker and SST fluctuations based on alkenone unsaturation index (UK'37) of the subarctic Pacific realm between 138 and 70 ka. Warmest sea-surface conditions were found during the early Eemian interglacial (128 to 126 ka), exceeding modern SSTs by ~2 °C. The further North Pacific climate evolu- tion is marked by pronounced oscillations in SST and sea-ice extent on millennial time scales, which correspond remarkably well to short-term temperature oscillations known from Green- land and the North Atlantic. These results imply a common forcing, which seems to be closely coupled to dynamics of the Atlantic meridional overturning circulation. However, immediate propagation of such climate fluctuations far beyond the North Atlantic basin suggests a rapid circumpolar coupling mechanism probably acting through the atmosphere, a prerequisite to explain the apparent synchronicity of remote climatic reorganizations in the subarctic Pacific.

n-Alkanes and lignin in bottom sediments of the Norwegian Sea

Investigations of bottom sediments from the central and northern parts of the Norwegian Sea including study regions at the Storegga landslide, the Haakon Mosby mud volcano, and Knipovich Ridge were carried out. Concentration of n-alkanes in bottom sediments from these regions ranges from 0.53 to 22.1 µg/g of dry sediments that corresponds to 0.02-1.97% of Corg. Molecular composition of hydrocarbons indicates mixed allochtonous-authochtonous genesis of total organic matter (TOC) formed by hydrobiota and residuals of terrestrial plants. Terrigenous organic mater dominates in bottom sediments. Active redox, microbial and thermolytic processes of organic matter transformation take place in the sedimentary mass. Special character of chromatographic spectra of n-alkane distribution in both low and high-molecular ranges, as well as increased naphtene contents can be interpreted as a sign of oil hydrocarbon generation from maternal organic matter as a result of thermocatalytic reactions within sedimentary mass and their displacement into the upper sedimentary layers. Molecular compositions and concentrations of phenols and lignin were determined in core samples from the Norwegian Sea. Total concentration of phenols in the cores ranges from 8.1 to 101.8 (µg/g of dry sediments that corresponds to 0.15-1.15% of TOC. Lignin concentration was estimated at 21.0-459.0 µg/g of dry sediments (0.59-7.9% of ?org. Phenol compounds of p-hydroxybenzoic, vanillin, syringyl and cinnamyl families as basic components of lignin macromolecules were identified. It was found that sea currents and aerosols are the main contributors of lignin into the abyssal part of the Norwegian Sea.