Organic carbon analyses of ODP Site 160-971 in the Mediterranean Sea

Mud volcanism on the Mediterranean Ridge is caused by extrusion of overpressured sediments, with consequent formation of spectacular dome-shaped features composed of mud breccias at the seafloor. The organic material in the mud breccia of the Napoli mud volcano is a mixture of different facies, stratigraphic origin and thermal maturities. One portion is synsedimentary organic material with only minor diagenetic alterations and represents sedimenting material that was embedded into the mud volcano during its extrusion. The mud breccia also contains thermally mature organic material of mainly terrestrial provenance with algae of fresh- and brackish-water origin. Vitrinite reflectance data of this maturity generation range from 0.65 to 0.90% R(oil) and thus characterize thermally mature source rocks, a rank which is corroborated by fluorescence and molecular characteristics. The predominance of vitrinite in the maceral assemblages and the occurrence of biomarkers of terrigenous origin suggest that the major part of the mud matrix derives from a lacustrine or riverine sedimentary unit in the subsurface, possibly from the Messinian stage. A third generation of organic material includes inertinites and vitrinites of high reflectance, which represent recycled organic matter present in any marine sediment. By use of the Lopatin method for modelling the thermal maturation of hydrocarbon source rocks from the vitrinite reflectance data, we calculated that the depth of mobilization ranges from 4900 m to 7500 m, depending upon the temperature gradient used.

Oxygen and hydrogen isotope ratios of pore waters from ODP sites in the Mediterranean Sea

Pore fluids from two ODP sites at Eastern Mediterranean mud volcanoes have been analyzed for their Cl concentration and their delta18O and deltaD isotopic composition. The Cl data span a wide range of concentrations, from extremely depleted with respect to seawater (as low as 60 mM) at the crest of Milano dome (site 970) to strongly enriched (up to 5.4 M) at Napoli dome (site 971). Chloride enrichment is known to be due to dissolving Messinian evaporites, whereas the source of the low-Cl fluid is deduced from stable isotope data presented here. The isotopic composition of the endmember fluid is found to be +10? for delta18O and -32? for deltaD for low- as well as for high-Cl waters. From this signature it can be concluded that neither gas hydrates nor meteoric water play a significant role in the freshening of the pore water. Several other processes altering the delta18O/deltaD composition of pore waters are discussed and considered to be of only negligible influence. The process characterizing the isotopic composition of the fluid is found to be clay mineral dehydration (mainly smectite-illite transformation), corresponding to a depth range of 3.5-7 km and an elevated temperature of about 120-165°C. A quantitative estimate shows that this reaction is capable of producing the observed extreme Cl depletion.

A sedimentological, faunal, and isotopic record of the middle-to-late Pliocene transition at DSDP Hole 80-548

Hydraulic piston coring at DSDP Site 548, on the upper continental slope southwest of Ireland, recovered a nearly complete Pliocene section spanning 103 m of sediment. The sediments are greenish gray carbonate-rich hemipelagites containing abundant nannofossils and foraminifers. Grain-size analysis demonstrates that the texture of the section is fairly constant, with most of the variation occurring in 63- to 32-µm and < 2-µm fractions. Previous research has shown that the middle-to-late Pliocene transition in the North Atlantic was marked by the appearance of the planktonic foraminiferal species Globorotalia inflata and by the first occurrence of significant quantities of ice-rafted sediment grains in deep-sea sediments. The latter is taken to represent the first important development of Northern Hemisphere glaciation. The first appearance of G. inflata is carefully documented for Site 548 and is demonstrated to be an evolutionary datum at this site, rather than an ecologically controlled first appearance. Surface ocean conditions represented in the sediment section spanning the appearance of G. inflata were strongly cyclic, resulting in large periodic changes in the abundances of Globorotalia puncticulata and N. acostaensis. The benthic foraminiferal population was studied in detail over the middle-to-upper Pliocene transition to establish the nature and behavior of the intermediate-depth water mass in the northeastern Atlantic at the time of ice-sheet growth in the Northern Hemisphere. This water mass is presently warm and saline, having its source in the Mediterranean Sea. The benthic data show that the intermediate-depth water mass was undergoing a series of progressive changes over the interval including the first appearance of G. inflata. These changes are particularly reflected in the relative abundances of Globocassidulina subglobosa (Brady), Uvigerina, and Ehrenbergina. Also, the mean size of individuals in the G. subglobosa populations shows systematic variation, indicating changing intermediate-depth water properties. Oxygen-isotope analyses show that the intermediate-depth water mass was cold during the middle-to-late Pliocene transition. This interpretation is supported by the relative abundances of benthic foraminiferal species. Hence, the intermediate-depth northeastern Atlantic water mass of the middle to late Pliocene was considerably different from the intermediate-depth water mass of the present.

Mercury concentrations in waters of the Atlantic Ocean and Mediterranean Sea

Total mercury concentration in waters of the Atlantic Ocean and Mediterranean Sea measured in January-April 1982 varied from 0.007 to 0.192 µg/l. Particulate form was 1.6-16% of dissolved form. Inorganic mercury accounted for 16-67% of dissolved mercury. Total mercury concentration in the surface film was 0.74-1.85 µg/l, 10-40 times higher than in seawater. Concentration of particulate form in the film was from 100 to 400 times higher than in seawater.

Individual dinoflagellate cysts species of surface sediment samples from the Mediterranean Sea

To determine the relationship between the spatial dinoflagellate cyst distribution and oceanic environmental conditions, 34 surface sediments from the Eastern and Western Mediterranean Sea have been investigated for their dinoflagellate cyst content. Multivariate ordination analyses identified sea-surface temperature, chlorophyll-a , nitrate concentration, salinity, and bottom oxygen concentration as the main factors affecting dinoflagellate cyst distribution in the region. Based on the relative abundance data, two associations can be distinguished that can be linked with major oceanographic settings. (1) An offshore eastern Mediterranean regime where surface sediments are characterized by oligotrophic, warm, saline surface water, and high oxygen bottom water concentrations (Impagidinium species, Nematosphaeropsis labyrinthus, Pyxidinopsis reticulata and Operculodinium israelianum). Based on the absolute abundance, temperature is positively related to the cyst accumulation of Operculodinium israelianum. Temperature does not form a causal factor influencing the accumulation rate of the other species in this association. Impagidinium species and Nematosphaeropsis labyrinthus show a positive relationship between cyst accumulation and nitrate availability in the upper waters. (2) Species of association 2 have highest relative abundances in the Western Mediterranean Sea, Strait of Sicily/NW Ionian Sea, and/or the distal ends of the Po/Nile/Rhône River plumes. At these stations, surface waters are characterized by (relative to the other regime) higher productivity associated with lower sea-surface temperature, salinity, and lower bottom water oxygen concentrations (Selenopemphix nephroides, Echinidinium spp., Selenopemphix quanta, Quinquecuspis concreta, Brigantedinium spp. and Lingulodinium machaerophorum). Based on both the absolute and relative abundances, Selenopemphix nephroides is suggested to be a suitable indicator to trace changes in the trophic state of the upper waters. The distribution of Lingulodinium machaerophorum is related to the presence of river-influenced surface waters, notably the Nile River. We suggest that this species might form a suitable marker to trace past variations in river discharge, notably from the Nile.

Gridded bathymetry from multibeam echosounder HS-DS2 data of the cruise M52/1 (2002)

Bathymetry based on data recorded during M52-1 between 02.01.2002 and 01.02.2002 in the Black Sea. The cruise was focused on studying the distribution, structure and architecture of gas hydrate deposits in the Black Sea as well as their relationship to fluid migration pathways. While high-resolution geoacoustic investigation tools covering a whole range of frequencies and techniques render detailed images of near-surface gas hydrates and associated fluid migration pathways.