Amorphous silicon carbonitride films modified by plasma immersion ion implantation

Amorphous silicon carbonitride (a-SiCN:H) films were deposited from hexamethyldisilazane (HMDSN) organic compounds via radio-frequency (RF) glow discharges. Afterwards the films were bombarded, from 15 to 60 min, with nitrogen ions using Plasma Immersion Ion Implantation (PIII) technique. X-ray photoelectron spectroscopy (XPS) showed that O-containing groups increased, while C-C and/or C-H groups decreased with treatment time. This result indicates chemical alterations of the polymeric films with the introduction of polar groups on the surface, which changes the surface wettability. In fact, the hydrophobic nature of a-SiCN:H films (contact angle of 100 degrees) was changed by nitrogen ion implantation and, and after aging in atmosphere air, all samples preserved the hydrophilic character (contact angle <80 degrees) independently of treatment time. The exposure of the films to oxygen plasma was performed to evaluate the etching rate, which dropped from 24% to 6% while the implantation time increased from 15 to 60 min. This data suggests that Pill increased the film structure strength, probably due to crosslinking enhancement of polymeric chains. Therefore, the treatment with nitrogen ions via Pill process was effective to modify the wettability and oxidation resistance of a-SiCN:H films. (C) 2014 Elsevier Ltd. All rights reserved.

Production and characterization of Tm3+/Yb3+ codoped pedestal-type PbO-GeO2 waveguides

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Estudo da tecnologia de acesso Wi-Fie suas aplicações em ambientes indoor e outdoor

Wireless communications is a feature that has become indispensable for many people in the whole world. Through this feature, communication process can become much more efficient, allowing people to access information much more quickly wherever they are. The constant evolution of communication technologies allows the development of new unthinkable applications and services. This new range of possibilities brings greater mobility and efficiency for final users and also helps service providers and carriers to improve the quality of services offered by them. This study presents the principles of wireless communication and the Wi-Fi technology as well as its most modern applications, covering from the basics of computer networks to the procedures of planning a wireless network, concepts of radio frequency, antennas, patterns, regulatory agencies, network equipment, protocols and network monitoring

Avaliação de projetos logísticos de RFID aplicados na indústria aeronáutica brasileira

Pós-graduação em Engenharia Mecânica - FEG

Controle de Acesso utilizando Arduino, banco de dados MySQL e LabVIEW

The search for more reliable security systems and information management of these systems is leading to a growing progress in new technologies investments that allow the implementation of equipment with a high level of reliability, but also have an agile and practical operation. This led people to turn increasingly looking for home automation systems, enterprise and industry for the automation and integration of their systems. The identification by radio frequency is very widespread today for ensuring both agility in handling records data, the reliability of their identification systems, which are increasingly advanced and less susceptible to fraud. Attached to this technology, the use of the database is always very important for the storage of information collected, the area where the MySQL platform is widely used. Using the open source Arduino platform for programming and manipulation of RFID module and LabVIEW software for the union of all these technologies and to develop a user-friendly interface, you can create a highly reliable access control and agility places a high turnover of people. This project aims to prove the advantages of using all these technologies working together, thus improving a flawed system effectively safety, cheaper and quicker

Reversão sexual de tilápias gift criadas em hapas e submetidas a diferentes taxas de alimentação em alta frequência

Pós-graduação em Zootecnia - FMVZ

Concept design for a RFID enabled student workbook

In this paper, the concept for a radio frequency identification (RFID) enabled student workbook is discussed and a prototype system developed. The workbook is a question-answer notebook in traditional paper format in which hand written solutions to student assignments are written. An embedded RFID tag in the workbook is then used for the student to store his/her solution to the attempted assignment questions at home. On entry to the classroom and once the questions have been attempted, an RFID reader in the classroom will retrieve the answers from the workbook, automatically collate the results and instantly provide a summary of these results for the individual student and the class as a whole. If problems are highlighted, the teacher can then investigate issues with individual students and review the answers provided in the workbook.

Automação do fornecimento de ração para organismos aquáticos

Coordenação de Aperfeiçoamento de Pessoal de Nível Superior (CAPES)

Sistema de monitoramento da temperatura e umidade em silos graneleiros via radiofrequencia

The use of Information and Communication Technology has grown in most agricultural activities. As a consequence, it has changed the way of thinking and acting of the farmer who wants to establish a more and more competitive market. However, the high costs of acquisition and maintenance of those technologies may be a factor which can inhibit its spread and acceptance, mainly to a large number of small grain Brazilian farmers. In this context, there is a need for innovative solutions that are proper for this universe of farmers. Starting from this premise, this paper presents the development of a low cost prototype to the monitoring process of temperature and humidity values of grains stored in silos, using communication based on wireless technology by radio frequency. Therefore, the economic implications of cost/benefit ratio of innovative application of wireless transmission in the process of thermometry of grains were analysed. The prototype was made of two electronic units, one of acquisition and another one of data reception, as well as computational software, which offered the farmer more precise information for the control of aeration. By means of stability, integrity and reliability tests of data transmission via radio, using low cost electronic components, the development system can be considered as potentially viable. It presented the difference regarding the wireless communication via radio in the process of grains thermometry, providing mobility, reducing cabling costs and maintenance, and also offering an easy system expansion; it was also appropriate to temperature and humidity monitoring in grain silos; and revealed operational viability, besides the low cost development when compared to similar products available in the Brazilian market.

Contribuições para a melhoria da gestão de resíduos de eletroeletrônicos no Brasil, no contexto da sustentabilidade ambiental

Pós-graduação em Engenharia de Produção - FEG

Módulo para identificação de objetos e transmissão de dados sem fio

Pós-graduação em Engenharia Elétrica - FEIS

Enhancement of optical absorption by modulation of the oxygen flow of TiO2 films deposited by reactive sputtering

Oxygen-deficient TiO2 films with enhanced visible and near-infrared optical absorption have been deposited by reactive sputtering using a planar diode radio frequency magnetron configuration. It is observed that the increase in the absorption coefficient is more effective when the O-2 gas supply is periodically interrupted rather than by a decrease of the partial O-2 gas pressure in the deposition plasma. The optical absorption coefficient at 1.5 eV increases from about 1 x 10(2) cm(-1) to more than 4 x 10(3) cm(-1) as a result of the gas flow discontinuity. A red-shift of similar to 0.24 eV in the optical absorption edge is also observed. High resolution transmission electron microscopy with composition analysis shows that the films present a dense columnar morphology, with estimated mean column width of 40nm. Moreover, the interruptions of the O-2 gas flow do not produce detectable variations in the film composition along its growing direction. X-ray diffraction and micro-Raman experiments indicate the presence of the TiO2 anatase, rutile, and brookite phases. The anatase phase is dominant, with a slight increment of the rutile and brookite phases in films deposited under discontinued O-2 gas flow. The increase of optical absorption in the visible and near-infrared regions has been attributed to a high density of defects in the TiO2 films, which is consistent with density functional theory calculations that place oxygen-related vacancy states in the upper third of the optical bandgap. The electronic structure calculation results, along with the adopted deposition method and experimental data, have been used to propose a mechanism to explain the formation of the observed oxygen-related defects in TiO2 thin films. The observed increase in sub-bandgap absorption and the modeling of the corresponding changes in the electronic structure are potentially useful concerning the optimization of efficiency of the photocatalytic activity and the magnetic doping of TiO2 films. (C) 2012 American Institute of Physics. [http://dx.doi.org/10.1063/1.4724334]

Increased coherence among striatal regions in the theta range during attentive wakefulness

The striatum, the largest component of the basal ganglia, is usually subdivided into associative, motor and limbic components. However, the electrophysiological interactions between these three subsystems during behavior remain largely unknown. We hypothesized that the striatum might be particularly active during exploratory behavior, which is presumably associated with increased attention. We investigated the modulation of local field potentials (LFPs) in the striatum during attentive wakefulness in freely moving rats. To this end, we implanted microelectrodes into different parts of the striatum of Wistar rats, as well as into the motor, associative and limbic cortices. We then used electromyograms to identify motor activity and analyzed the instantaneous frequency, power spectra and partial directed coherence during exploratory behavior. We observed fine modulation in the theta frequency range of striatal LFPs in 92.5 ± 2.5% of all epochs of exploratory behavior. Concomitantly, the theta power spectrum increased in all striatal channels (P < 0.001), and coherence analysis revealed strong connectivity (coefficients >0.7) between the primary motor cortex and the rostral part of the caudatoputamen nucleus, as well as among all striatal channels (P < 0.001). Conclusively, we observed a pattern of strong theta band activation in the entire striatum during attentive wakefulness, as well as a strong coherence between the motor cortex and the entire striatum. We suggest that this activation reflects the integration of motor, cognitive and limbic systems during attentive wakefulness.

Classical bifurcation in a quadrupolar NMR system

The Josephson junction model is applied to the experimental implementation of classical bifurcation in a quadrupolar nuclear magnetic resonance system. There are two regimes, one linear and one nonlinear, which are implemented by the radio-frequency and the quadrupolar terms of the Hamiltonian of a spin system, respectively. These terms provide an explanation of the symmetry breaking due to bifurcation. Bifurcation depends on the coexistence of both regimes at the same time in different proportions. The experiment is performed on a lyotropic liquid crystal sample of an ordered ensemble of 133Cs nuclei with spin I = 7/2 at room temperature. Our experimental results confirm that bifurcation happens independently of the spin value and of the physical system. With this experimental spin scenario, we confirm that a quadrupolar nuclei system could be described analogously to a symmetric two-mode Bose-Einstein condensate.

Reduced-order modelling, circuit-level design and SOI fabrication of microelectromechanical resonators

This thesis deals with two important research aspects concerning radio frequency (RF) microresonators and switches. First, a new approach for compact modeling and simulation of these devices is presented. Then, a combined process flow for their simultaneous fabrication on a SOI substrate is proposed. Compact models for microresonators and switches are extracted by applying mathematical model order reduction (MOR) to the devices finite element (FE) description in ANSYS c° . The behaviour of these devices includes forms of nonlinearities. However, an approximation in the creation of the FE model is introduced, which enables the use of linear model order reduction. Microresonators are modeled with the introduction of transducer elements, which allow for direct coupling of the electrical and mechanical domain. The coupled system element matrices are linearized around an operating point and reduced. The resulting macromodel is valid for small signal analysis around the bias point, such as harmonic pre-stressed analysis. This is extremely useful for characterizing the frequency response of resonators. Compact modelling of switches preserves the nonlinearity of the device behaviour. Nonlinear reduced order models are obtained by reducing the number of nonlinearities in the system and handling them as input to the system. In this way, the system can be reduced using linear MOR techniques and nonlinearities are introduced directly in the reduced order model. The reduction of the number of system nonlinearities implies the approximation of all distributed forces in the model with lumped forces. Both for microresonators and switches, a procedure for matrices extraction has been developed so that reduced order models include the effects of electrical and mechanical pre-stress. The extraction process is fast and can be done automatically from ANSYS binary files. The method has been applied for the simulation of several devices both at devices and circuit level. Simulation results have been compared with full model simulations, and, when available, experimental data. Reduced order models have proven to conserve the accuracy of finite element method and to give a good description of the overall device behaviour, despite the introduced approximations. In addition, simulation is very fast, both at device and circuit level. A combined process-flow for the integrated fabrication of microresonators and switches has been defined. For this purpose, two processes that are optimized for the independent fabrication of these devices are merged. The major advantage of this process is the possibility to create on-chip circuit blocks that include both microresonators and switches. An application is, for example, aswitched filter bank for wireless transceiver. The process for microresonators fabrication is characterized by the use of silicon on insulator (SOI) wafers and on a deep reactive ion etching (DRIE) step for the creation of the vibrating structures in single-crystal silicon and the use of a sacrificial oxide layer for the definition of resonator to electrode distance. The fabrication of switches is characterized by the use of two different conductive layers for the definition of the actuation electrodes and by the use of a photoresist as a sacrificial layer for the creation of the suspended structure. Both processes have a gold electroplating step, for the creation of the resonators electrodes, transmission lines and suspended structures. The combined process flow is designed such that it conserves the basic properties of the original processes. Neither the performance of the resonators nor the performance of the switches results affected by the simultaneous fabrication. Moreover, common fabrication steps are shared, which allows for cheaper and faster fabrication.