渤海湾盆地前第三系构造演化与煤成气成藏研究

The disequilibrium between supply and demand the east part of North China accelerated natural gas exploration in Bohai bay basin. Exploration practice showed that coal-derived gas is important resource. In searching of big to middle scaled coal derived gas field, and realize successive gas supply, the paper carried out integrated study on structural evolution of Pre-Tertiary and evaluation of reservoir forming condition of coal-derived gas. Study work of the paper was based on the following condition: available achievement in this field at present, good understanding of multiphase of tectonic movement. Study work was focused on geological evolution, source rock evaluation and dissection key factors controlling reservoir forming. Based on analysis of seismic data, drilling data, tectonic style of Pre-Tertiary was subdivided, with different tectonic style representing different tectonic process. By means of state of the art, such as analysis of balanced cross section, and erosion restoration, the paper reestablished tectonic history and analyzed basin property during different tectonic phase. Dynamic mechanism for tectonic movement and influence of tectonic evolution on tectonic style were discussed. Study made it clear that tectonic movement is intensive since Mesozoic including 2 phase of compressional movement (at the end of Indo-China movement, and Yanshan movement), 2 phase of extensional movement (middle Yanshan movement, and Himalayan movement), 2 phase of strike slip movement, as well as 2 phase of reversal movement (early Yanshan movement, and early Himalayan movement). As a result, three tectonic provinces with different remnant of strata and different tectonic style took shape. Based on afore mentioned study, the paper pointed out that evolution of Bohai bay basin experienced the following steps: basin of rift valley type (Pt2+3)-craton basin at passive continental margin (∈1－2)-craton basin at active continental margin (∈3- O)-convergent craton basin (C-T1+2)-intracontinental basin (J＋K). Superposition of basins in different stage was discussed. Aimed at tectonic feature of multiple phases, the paper put forward concept model of superposition of tectonic unit, and analyzed its significance on reservoir forming. On basis of the difference among 3 tectonic movements in Mesozoic and Cenozoic, superposition of tectonic unit was classified into the following 3 categories and 6 types: continuous subsidence type (I), subsidence in Mesozoic and uplift for erosion in Cenozoic (II1), repeated subsidence and uplift in Mesozoic and subsidence in Cenozoic (II2), repeated subsidence and uplift in Mesozoic and uplift for erosion in Cenozoic (II3), uplift for erosion in Mesozoic and subsidence in Cenozoic (II4), and continuous uplift (III). Take the organic facies analysis as link, the paper established relationship between sedimentary environment and organic facies, as well as organic facies and organic matter abundance. Combined information of sedimentary environment and logging data, the paper estimated distribution of organic matter abundance. Combined with simulation of secondary hydrocarbon generation, dynamic mechanism of hydrocarbon generation, and thermal history, the paper made static and dynamic evaluation of effective source rock, i.e. Taiyuan formation and Shanxi formation. It is also pointed out that superposition of tectonic unit of type II2, type II4, and type I were the most favorable hydrocarbon generation units. Based on dissection of typical primary coal-derived gas reservoir, including reservoir forming condition and reservoir forming process, the paper pointed out key factors controlling reservoir forming for Carboniferous and Permian System: a. remnant thickness and source rock property were precondition; b. secondary hydrocarbon generation during Himalayan period was key factor; c. tectonic evolution history controlling thermal evolution of source rock was main factor that determine reservoir forming; d. inherited positive structural unit was favorable accumulation direction; e. fault activity and regional caprock determined hydrocarbon accumulation horizon. In the end, the paper established reservoir forming model for different superposition of tectonic units, and pointed out promising exploration belts with 11 of the first class, 5 of the second class and 6 of the third class.

均衡重力异常计算与综合解释——以黄海地区为例

Petroleum and Natural Gas is an important strategic resources. The reserves of Petroleum and Natural Gas can’t meet the need of our country, which also blocks the development of economy and threatens the safety of national. Therefore, it makes a great sense to bring “the second round of oil & gas exploration” into effect and study the exploration of oil and gas of Pre-Cenozoic residual basins in China. The integrated geophysical exploration is the main way to research the Pre-Cenozoic residual basins. Gravity exploration is one of the most important exploration methods, which has played an important role in oil and gas prospecting, such as compartmentalizing geotectonic elements, delineating the distribution range of sedimentary basins, searching oil and gas structure, abstracting oil and gas information, and so on, from its naissance. The isostatic gravity anomalies is significant for exploration, which can help us research deep crustal structure, the equilibrium state of earth, the geologic structure of shallow crust, the basement shape of sedimentary basins and the genetic evolution of sedimentary basins. In the paper, we stress the implication and physical meanings systemically, and discuss the calculation theory. On the basis of previous work, we test different isostatic compensation models and parameters to find out their influences to the result of isostatic gravity anomalies. In addition, we improve the method of isostatic gravity anomalies calculation and give a system of isostatic gravity anomalies calculation which is proved has satisfying effect. From the research above, we find that the results of Platt model and Airy model are consistent, which have similar form and almost the same value. However, by contrast, the Airy model is proved has better adaptability than Platt model. The two main parameters——crust thickness and density difference of crust and mantle, both have influence to the isostatic gravity anomalies, but the latter have more. Finally, we adopt the regional field extending edge method to make the result more of actual geologic condition. On the methods above, we calculate the isostatic gravity anomalies field in Yellow Sea area from the Bouguer gravity anomalies and the water depth and altitude data. And then the isostatic gravity anomalies character is analyzed and the integrated geological-geophysical interpretation is made on the basis of summarizing the previous research result systemically and analyzing other geophysical data and geological information. From the research, we find that the Yellow Sea area belongs to continental type crust equilibrium regions, where the isostatic gravity anomalies field is placid and has less fluctuation values, which implies that the area is in equilibrium state to different extends.

生物－热催化过渡带沉积成岩演化及其成烃作用研究

The biothermocatalytic transitional zone gas is a new type of natural gas genetic theory, and also an clean, effective and high quality energy with shallow burial depth, wide distribution and few investment. Meanwhile, this puts biothermocatalytic transitional zone gas in important position to the energy resource and it is a challenging front study project. This paper introduces the concept, the present situation of study and developmental trend about biothermocatalytic transitional zone gas in detail. Then by using heat simulating of source rocks and catalysis mechanism analysis in the laboratory and studying structural evolution, sedimentation, diagenesis and the conditions of accumulation formation and so on, this paper also discusses catalytic mechanism and evolutionary model of the biothermocatalytic transitional zone gas formation, and establishes the methods of appraisal parameter and resources prediction about the biothermocatalytic transitional zone gas. At last, it shows that geochemical characteristics and differentiated mark of the biothermocatalytic transitional zone gas, and perfect natural gas genetic theory, and points out the conditions of accumulation formation, distribution characteristics and potential distribution region on the biothermocatalytic transitional zone gas m China. The paper mainly focuses on the formation mechanism and the resources potential about the biothermocatalytic transitional zone gas. Based on filed work, it is attached importance to a combination of macroscopic and microcosmic analysis, and the firsthand data are obtained to build up framework and model of the study by applying geologic theory. Based on sedimentary structure, it is expounded that structural actions have an effect on filling space and developmental cource of sediments and evolution of source rocks. Carried out sedimentary environment, sequence stratigraphy, sedimentary system and diagenesis and so on, it is concluded that diagenesis influences developmental evolution of source rocks, and basic geologic conditions of the biothermocatalytic transitional zone gas. Applying experiment simulating and catalytic simulating as well as chemical analysis, catalytic mechanism of clay minerals is discussed. Combined diagenecic dynamics with isotope fractionation dynamics, it is established that basis and method of resource appraisal about the biothermocatalytic transitional zone gas. All these results effectively assess and predict oil&gas resources about the biothermocatalytic transitional zone gas-bearing typical basin in China. I read more than 170 volumes on the biothermocatalytic transitional zone gas and complete the dissertation' summary with some 2.4 ten thousand words, draw up study contents in some detail and set up feasible experimental method and technologic course. 160 pieces of samples are obtained in oilfield such as Liaohe, Shengli, Dagang and Subei and so on, some 86 natural gas samples and more than 30 crude oil samples. Core profiles about 12 wells were observed and some 300 geologic photos were taken. Six papers were published in the center academic journal at home and abroad. Collected samples were analysised more than 1000 times, at last I complete this dissertation with more than 8 ten thousand words, and with 40 figures and 4 plates. According to these studies, it is concluded the following results and understandings. 1. The study indicates structural evolution and action of sedimentary basin influence and control the formation and accumulation the biothermocatalytic transitional zone gas. Then, the structural action can not only control accommodation space of sediments and the origin, migration and accumulation of hydrocarbon matters, but also can supply the origin of energy for hygrocarbon matters foramtion. 2. Sedimentary environments of the biothermocatalytic transitional zone gas are lake, river and swamp delta- alluvial fan sedimentary systems, having a warm, hot and humid climate. Fluctuation of lake level is from low to high., frequency, and piling rate of sedimentary center is high, which reflect a stable depression and rapidly filling sedimentary course, then resulting in source rocks with organic matter. 3. The paper perfects the natural gas genetic theory which is compound and continuous. It expounds the biothermocatalytic transitional zone gas is a special gas formation stage in continuous evolutionary sequence of organic matter, whose exogenic force is temperture and catalysis of clay minerals, at the same time, having decarbxylation, deamination and so on. 4. The methodology is established which is a combination of SEM, TEM and Engery spectrum analysis to identify microstructure of crystal morphology about clay minerals. Using differential thermal-chromatographic analysis, it can understand that hydrocarbon formation potential of different typies kerogens and catalytic method of all kinds of mineral matrix, and improve the surface acidity technology of clay minerals measured by the pyridine analytic method. 5. The experiments confirm catalysis of clay minerals to organic matter hygrocarbon formation. At low temperature (<300 ℃), there is mainly catalysis of montmorillonite, which can improve 2-3 times about produced gas of organic matters and the pyrolyzed temperature decreased 50 ℃; while at the high temperature, there is mainly catalysis of illite which can improve more than 2 times about produced gas of organic matters. 6. It is established the function relationship between organic matter (reactant) concentration and temperature, pressure, time, water and so on, that is C=f (D, t). Using Rali isotope fractionation effect to get methane isotope fractionation formula. According to the relationship between isotope fractionation of diagenesis and depth, and combined with sedimentary rate of the region, it is estimated that relict gas of the biothermocatalytic transitional zone gas in the representative basin. 7. It is revealed that hydrocarbon formation mechanism of the biothermocatalytic transitional zone gas is mainly from montmorillonite to mixed minerals during diagenesis. In interlayer, a lot of Al~(3+) substitute for Si~(4+), resulting in a imbalance between surface charge and interlayer charge of clay minerals and the occurrence of the Lewis and Bronsted acid sites, which promote to form the carbon cation. The cation can form alkene or small carbon cation. 8. It is addressed the comprehensive identification mark of the biothermo - catalytic transitional zone gas. In the temproal-spatial' distribution, its source rocks is mainly Palaeogene, secondly Cretaceous and Jurassic of Mesozoic, Triassic, having mudy rocks and coal-rich, their organic carbon being 0.2% and 0.4% respectively. The vitrinite reflection factor in source rocks Ro is 0.3-0.65%, a few up to 0.2%. The burial depth is 1000-3000m, being characterized by emerge of itself, reservoir of itself, shallow burial depth. In the transitional zone, from shallow to deep, contents of montmorillonites are progressively reduced while contents of illites increasing. Under SEM, it is observed that montmorillonites change into illite.s, firstly being mixed illite/ montmorillonite with burr-like, then itlite with silk-like. Carbon isotope of methane in the biothermocatatytic transitional zone gas , namely δ~(13)C_1-45‰- -60 ‰. 9. From the evolutionary sequence of time, distribution of the biothermocatalytic transitional zone gas is mainly oil&gas bearing basin in the Mesozoic-Neozoic Era. From the distribution region, it is mainly eastern stuctural active region and three large depressions in Bohaiwang basin. But most of them are located in evolutionary stage of the transitional zone, having the better relationship between produced, reservoir and seal layers, which is favorable about forming the biothermocatalytic transitional zone gas reservoir, and finding large gas (oil) field.

中国大中型气田天然气成藏物理化学模拟研究

Natural gas pays more important role in the society as clean fuel. Natural gas exploration has been enhanced in recent years in many countries. It also has prospective future in our country through "85" and "95" national research. Many big size gas fields have been discovered in different formations in different basins such as lower and upper Paleozoic in Erdos basin, Tertiary system in Kuche depression in Tarim basin, Triassic system in east of Sichuan basin. Because gas bearing basins had been experienced multiple tectogenesis. The characteristics of natural gases usually in one gas field are that they have multiple source rocks and are multiple maturities and formed in different ages. There has most difficult to research on the gas-rock correlation and mechanism of gas formation. Develop advanced techniques and methods and apply them to solve above problems is necessary. The research is focused on the critical techniques of geochemistry and physical simulation of gas-rock correlation and gas formation. The lists in the following are conclusions through research and lots of experiments. I 8 advanced techniques have been developed or improved about gas-rock correlation and gas migration, accumulation and formation. A series of geochemistry techniques has been developed about analyzing inclusion enclave. They are analyzing gas and liquid composition and biomarker and on-line individual carbon isotope composition in inclusion enclave. These techniques combing the inclusion homogeneous temperature can be applied to study on gas-rock correlation directly and gas migration, filling and formation ages. Technique of on-line determination individual gas carbon isotope composition in kerogen and bitumen thermal pyrolysis is developed. It is applied to determine the source of natural is kerogen thermal degradation or oil pyrolysis. Method of on-line determination individual gas carbon isotope composition in rock thermal simulation has being improved. Based on the "95"former research, on-line determination individual gas carbon isotope composition in different type of maceral and rocks thermal pyrolys is has been determined. The conclusion is that carbon isotope composition of benzene and toluene in homogenous texture kerogen thermal degradation is almost same at different maturity. By comparison, that in mixture type kerogen thermal pyrolysis jumps from step to step with the changes of maturity. This conclusion is a good proof of gas-rock dynamic correlation. 3. Biomarker of rock can be determined directly through research. It solves the problems such as long period preparing sample, light composition losing and sample contamination etc. It can be applied to research the character of source rock and mechanism of source rock expulsion and the path of hydrocarbon migration etc. 4. The process of hydrocarbon dynamic generation in source rock can be seen at every stage applying locating observation and thermal simulation of ESEM. The mechanism of hydrocarbon generation and expulsion in source rock is discussed according to the experiments. This technique is advanced in the world. 5. A sample injection system whose character is higher vacuum, lower leaks and lower blank has been built up to analyze inert gas. He,Ar,Kr and Xe can be determined continuously on one instrument and one injection. This is advanced in domestic. 7. Quality and quantity analysis of benzene ring compounds and phenolic compounds and determination of organic acid and aqueous gas analysis are applied to research the relationship between compounds in formation water and gas formation. This is another new idea to study the gas-rock correlation and gas formation. 8. Inclusion analysis data can be used to calculate the Paleo-fluid density, Paleo-geothermal gradient and Paleo-geopressure gradient and then to calculate the Paleo-fluid potential. It's also a new method to research the direction of hydrocarbon migration and accumulation. 9. Equipment of natural gas formation simulation is produced during the research to probe how the physical properties of rock affect the gas migration and accumulation and what efficiency of gas migrate and factors of gas formation and the models of different type of migration are. II study is focused on that if the source rocks of lower Paleozoic generated hydrocarbon and what the source rocks of weathered formation gas pool and the mechanism of gas formation are though many advanced techniques application. There are four conclusions. 1.The maturity of Majiagou formation source rocks is higher in south than that in north. There also have parts of the higher maturity in middle and east. Anomalous thermal pays important role in big size field formation in middle of basin. 2. The amount of gas generation in high-over maturity source rocks in lower Paleozoic is lager than that of most absorption of source rocks. Lower Paleozoic source rocks are effective source rocks. Universal bitumen exists in Ordovician source rocks to prove that Ordovician source rocks had generated hydrocarbon. Bitumen has some attribution to the middle gas pool formation. 3. Comprehensive gas-rock correlation says that natural gases of north, west, south of middle gas field of basin mainly come from lower Paleozoic source rocks. The attribution ratio of lower Paleozoic source rocks is 60%-70%. Natural gases of other areas mainly come from upper Paleozoic. The attribution ratio of upper Paleozoic source rocks is 70%. 4. Paleozoic gases migration phase of Erdos basin are also interesting. The relative abundance of gasoline aromatic is quite low especially toluene that of which is divided by that of methyl-cyclohexane is less than 0.2 in upper Paleozoic gas pool. The migration phase of upper Paleozoic gas may be aqueous phase. By comparison, the relative abundance of gasoline aromatic is higher in lower Paleozoic gas. The distribution character of gasoline gas is similar with that in source rock thermal simulation. The migration phase of it may be free phase. IH Comprehensive gas-rock correlation is also processed in Kuche depression Tarim basin. The mechanism of gas formation is probed and the gas formation model has been built up. Four conclusions list below. 1. Gases in Kuche depression come from Triassic-Jurassic coal-measure source rocks. They are high-over maturity. Comparatively, the highest maturity area is Kelasu, next is Dabei area, Yinan area. 2. Kerogen thermal degradation is main reason of the dry gas in Kuche depression. Small part of dry gas comes from oil pyrolysis. VI 3.The K12 natural gas lays out some of hydro-gas character. Oil dissolved in the gas. Hydro-gas is also a factor making the gas drier and carbon isotope composition heavier. 4. The mechanism and genesis of KL2 gas pool list as below. Overpressure has being existed in Triassic-Jurassic source rocks since Keche period. Natural gases were expulsed by episode style from overpressure source rocks. Hetero-face was main migration style of gas, oil and water at that time. The fluids transferred the pressure of source rocks when they migrated and then separated when they got in reservoir. After that, natural gas migrated up and accumulated and formed with the techno-genesis. Tectonic extrusion made the natural gas overpressure continuously. When the pressure was up to the critical pressure, the C6-C7 composition in natural gas changed. The results were that relative abundance of alkane and aromatic decreased while cycloalkane and isoparaffin increased. There was lots of natural gas filling during every tectonic. The main factors of overpressure of natural gas were tectonic extrusion and fluid transferring pressure of source rocks. Well preservation was also important in the KL2 gas pool formation. The reserves of gas can satisfy the need of pipeline where is from west to east. IV A good idea of natural gas migration and accumulation modeling whose apparent character is real core and formation condition is suggested to model the physical process of gas formation. Following is the modeling results. 1. Modeling results prove that the gas accumulation rule under cap layer and gas fraction on migration path. 2. Natural gas migration as free phase is difficult in dense rock. 3. Natural gases accumulated easily in good physical properties reservoirs where are under the plugging layer. Under the condition of that permeability of rock is more than 1 * 10~(-3)μm~(-1), the more better the physical properties and the more bigger pore of rock, the more easier the gas accumulation in there. On the contrary, natural gas canonly migrate further to accumulate in good physical properties of rock. 4. Natural gas migrate up is different from that down. Under the same situation, the amount of gas migration up is lager than that of gas migration down and the distance of migration up is 3 times as that of migration down. 5. After gas leaks from dense confining layer, the ability of its dynamic plug-back decreased apparently. Gas lost from these arils easily. These confining layer can confine again only after geology condition changes. 6. Water-wetted and capillary-blocking rocks can't block water but gases generally. The result is that water can migrate continuously through blocking rocks but the gases stay under the blocking rocks then form in there. The experiments have proved the formation model of deep basin gas.

南海天然气水合物地热学研究

Through generalizing the thermal field characteristics in gas hydrates distribution area in the world, the favorable thermal conditions for gas hydrates in the South China Sea are analyzed firstly. On the basis of above analysis, focused on the gas hydrates stability zone (GHSZ), the dissertation initiated the gas hydrates studies with geothermal methods in the South China Sea which will provide useful information for gas hydrates resource exploration and evaluation in the future. On the basis of study on hydrates phase equilibrium and the GHSZ affecting factors, the potential planar distribution of gas hydrates is determined by studying the temperature and pressure conditions in the sea bottom with different water depth, and the thickness of GHSZ is attained by solving the hydrates phase boundary curve equation and geothermal gradient curve equation. The result shows that, if the chemical composition of hydrocarbons contains methane only and the salt content of water is 3.5%, hydrates can form and keep stable at sea bottom at water depth not less than 550m, and the thickness of GHSZ is more than 200m in Xisha Through, Southeastern area of Dongsha Islands, Southwestern basin of Taiwan Island, northern area of Nansha Trough. The GHSZ is thicker with heat flow, geothermal gradient, and thermal conductivity decreasing, and with water depth increasing. Geothermal field simulating also attains the base of GHSZ in Xisha through, which is less than the depth of BSR. Although the present T-P conditions is not the most favorable for gas hydrates through 6Ma history, gas hydrates are still profitable in Xisha Through, Southeastern area of Dongsha Islands, Southwestern basin of Taiwan Island, Luzon Trough and northern area of Nansha Trough by systemic study on the sedimentary and structural characteristics, the conditions of T-P and natural gas source, considering geochemical and geophysical indications found in the South China Sea.

鄂尔多斯盆地东部古生界沉积体系与储层研究

Ordos basin with profuse coal, petroleum, natural gas and others mineral resources create the comprehensiveness notice of earthling, and became one of studying hotspots for China and foreign countries geology, petroleum and natural gas geology's workman. Late years, having found commercial value of large middle type gas pools in the upper Palaeozoic group, which have exhibited a very good foreground for gas exploring and exploitation. Through the new gas exploring headway and the exploring course, the east of the basin should regard Ordovician weathering crust in the upper Palaeozoic group, tide flat and barrier-lagoon, deltaic deposit system in the lower Palaeozoic group as the major exploration and research emphasis. Furthermore, it has been found that much gas showed wells, which has gain quantitative industry gas flow wells, especially the new assessment invigorative harvest, and bode that the east of the Ordos basin possess major exploring potential. In regional tectonic, the research region mainly lay in the Yishan incline, and the east part involved the west part of Jinxi warping belt. In tectonic and sedimentary evolution, it had inherited the characteristic of whole basin. From Latepaleozoic to triassic epoch, it developed gradational the transition of sedimentary that changed from sea to land, and from river to lake.

鄂尔多斯盆地苏里格气田储层次生孔隙性质与分布预测

Permian reservoir in Sulige area of Ordos Basin, on which this paper focused, belongs to fluvial-delta lithofacies. The majority formations in this area are complicated channel sand deposit with serious inhomogeneity which makes natural gas exploration be very tough in this area. This inhomogeneity can be found everywhere both in large horizontal area and vertical profile of inner and interbedded formations.This paper studied the inhomogeneity characteristic of Permian formation in sulige area of Ordos Basin according to the logging data.Correlating with core data, a criterion to distinguish different type of reservoirs by using logging data is determined after the study of logging response is done considering the diverse conditions of deposit environments, lithology and reservoir space. The characteristic relationships between the various type formations and logging responses fully and systemically are established.It investigated reservoir parameter calculation methods amply. Combining the conventional and special logging data, basing on the feature of low porosity -permeability formation of sulige area, a set of methods to calculate reservoir parameters was formed including primary porosity, secondary porosity, fracture porosity, permeability and water saturation under the conditions of both low porosity-permeability and inhomogenous reservoirs. One thing should be pay close attention is the parameter M for calculating saturation. It is found that the M in low porosity -permeability formation decreases as the porosity decrease, which is opposite to the law that M increases as the porosity decrease in the formation with intermediate to high porosity and permeability. This view has innovated the traditional theory and offered theory basis for the logging interpretation of low porosity - permeability reservoir. Meanwhile it also improved the Arqi formula theoretically and enhanced the logging interpretation accuracy and rescued a number of formations which has been thought to be hopeless according to the old theory.By using advantage logging interpretation procedure, a territorial synthetic geology evaluation to the inhomogeneous reservoir was completed basing on the single well interpretation. All the reservoir evaluation parameters including sand formation thickness, primary porosity, secondary porosity were calculated and evaluated. The rules of changing and development for sand formation thickness, sand physical properties and secondary porous were found at different formations of upper part of the Member 8 of Shihezi, lower part of the Member 8 of Shihezi, the Member 1 of shanxi and the Member 2 of shanxi individually. Evaluation and Correlation of these five formations were also completed and one conclusion was arrived: upper part of the Member 8 of Shihezi formation has the best performance followed by the lower part of the Member 8 of Shihezi, the Member 1 of shanxi and the Member 2 of shanxi formation.After studied the relationship between reservoir deposition characteristic and the natural gas richness, it is regarded that reservoir inhomogeneity is the key issue of the impaction on the natural gas. Natural gas in Sulige gas field was mainly accumulated in sands of channel bar, distributary channel and debouchure bar. Especially, the quartz sand with rich of secondary porous space has obvious better physical properties than other reservoir and usually can forms the concentration of natural gas.

济阳坳陷高青—平南断裂带天然气地球化学及与火成岩的关系

济阳坳陷位于渤海湾盆地东南部，是中国东部重要的含油气坳陷之一，同时也是重要的天然气气藏富集区。坳陷中部高青－平南断裂从孔店组沉积时开始发育，至明化镇末期断裂停止活动。岩浆活动导致断裂带两侧天然气的分布较为复杂：既有纯烃类气藏，也有纯非烃类气藏，还有混合气藏。已有的工作主要是着重气藏形成的地质条件、成藏模式以及盆地演化过程中的构造-热事件中的岩浆活动对CO2气藏形成的总体影响。对烃类气藏成因研究不足，仅简单的归于油型气；同时天然气藏与火山活动之间的关系研究不够，本论文在天然气、火山岩地球化学基础上，探讨天然气的来源，综合分析了火山活动对天然气形成的影响。论文获得的主要认识如下： 1. 根据花沟地区天然气碳及稀有气体地球化学特征结合该地区火山岩流体包裹体组分，认为高青、花沟地区烃类气藏应该是有机与无机成因相结合的混合气体，其有机来源主要是来自油型气；无机来源主要是地幔脱气以及发生氧化还原反应生成的无机成因气；而平南、平方王地区烃类气主要为油型气。 2. CO2气藏主要是无机幔源成因。据CO2体积百分含量、CO2碳同位素（δ13CCO2）表明CO2是无机成因，氦同位素R/Ra、40Ar/ 36Ar表明区内CO2成因与无机幔源成因密切相关。不同地区幔源包裹体中的CO2含量不同，研究表明后期火山岩浆更富CO2。高青地区CO2气以幔源岩浆脱气成因为主；平方王和平南地区为幔源岩浆脱气和壳源岩石化学混合成因。 3. 稀有气体同位素组成说明该地区He、Ar为壳幔混合成因。40Ar/36Ar值317~3178之间，氦同位素R/Ra在1.44~5.96之间；在3He/4He-40Ar/36Ar以及3He/4He-4He/20Ne图中均处于壳源与幔源混合成因区域。 4. 岩浆活动对天然气成藏效应体现在对天然气形成与成藏的影响。 5. 高青－平南断裂带幔源流体活动方式和活动强度存在时间和空间上的差异是造成高青－平南断裂带天然气分布不同最主要的原因。CO2气藏更容易在两个断裂的交汇处形成，说明了断裂为天然气的运移提供通道。

Methanol to olefin conversion catalysts

The past year has seen remarkable advances both in methanol to olefin process development and in understanding the catalysts and reactions invoked. The methanol to olefin process is now on the way to being commercialized locally with economic advantages in comparison with other natural gas utilization technologies and conventional naphtha cracking processes. Using a specially designed procedure, a catalyst for the selective synthesis of ethylene from methanol has been reliably reproduced. The relationships between catalyst properties and reaction performances are clearer than ever before.