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Electrodynamic tether thrusters can use the power provided by solar panels to drive a current in the tether and then the Lorentz force to push against the Earth's magnetic field, thereby achieving propulsion without the expenditure of onboard energy sources or propellant. Practical tether propulsion depends critically on being able to extract multiamp electron currents from the ionosphere with relatively short tethers (10 km or less) and reasonably low power. We describe a new anodic design that uses an uninsulated portion of the metallic tether itself to collect electrons. Because of the efficient collection of this type of anode, electrodynamic thrusters for reboost of the International Space Station and for an upper stage capable of orbit raising, lowering, and inclination changes appear to be feasible. Specifically, a 10-km-long bare tether, utilizing 10 kW of the space station power could save most of the propellant required for the station reboost over its 10-year lifetime. The propulsive small expendable deployer system experiment is planned to test the bare-tether design in space in the year 2000 by deploying a 5-km bare aluminum tether from a Delta II upper stage to achieve up to 0.5-N drag thrust, thus deorbiting the stage.

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Electrodynamic tethered systems, in which an exposed portion of the conducting tether itself collects electrons from the ionosphere, promise to attain currents of 10 A or more in low Earth orbit. For the first time, another desirable feature of such bare-tether systems is reported and analyzed in detail: Collection by a bare tether is relatively insensitive to variations in electron density that are regularly encountered on each revolution of an orbit. This self-adjusting property of bare-tether systems occurs because the electron-collecting area on the tether is not fixed, but extends along its positively biased portion, and because the current varies as collecting length to a power greater than unity. How this adjustment to density variations follows from the basic collection law of thin cylinders is shown. The effect of variations in the motionally induced tether voltage is also analyzed. Both power and thruster modes are considered. The performance of bare-tether systems to tethered systems is compared using passive spherical collectors of fixed area, taking into consideration recent experimental results. Calculations taking into account motional voltage and plasma density around a realistic orbit for bare-tether systems suitable for space station applications are also presented.

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The effects of five technological procedures and of the contents of total anthocyanins and condensed tan- nins on 19 fermentation-related aroma compounds of young red Mencia wines were studied. Multifactor ANOVA revealed that levels of those volatiles changed significantly over the length of storage in bottles and, to a lesser extent, due to other technological factors considered; total anthocyanins and condensed tannins also changed significantly as a result of the five practices assayed. Five aroma compounds pos- sessed an odour activity value >1 in all wines, and another four in some wines. Linear correlation among volatile compounds and general phenolic composition revealed that total anthocyanins were highly related to 14 different aroma compounds. Multifactor ANOVA, considering the content of total anthocy- anins as a sixth random factor, revealed that this parameter affected significantly the contents of ethyl lactate, ethyl isovalerate, 1-pentanol and ethyl octanoate. Thus, the aroma of young red Mencia wines may be affected by levels of total anthocyanins

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Performances, design criteria, and system mass of bare tethers for satellite deorbiting missions are analyzed. Orbital conditions and tether cross section define a tether length, such that 1) shorter tethers are electron collecting practically in their whole extension and 2) longer tethers collect practically the short-circuit current in a fixed segment length. Long tethers have a higher drag efficiency (defined as the drag force vs the tether mass) and are better adapted to adverse plasma densities. Dragging efficiency and mission-related costs are used to define design criteria for tether geometry. A comparative analysis with electric thrusters shows that bare tethers have much lower costs for low- and midinclination orbits and remain an attractive option up to 70 deg.

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The performance efficiency of electrodynamic bare tethers acting as thrusters in low Earth orbit, as gauged by the ratio of the system mass dedicated to thrust over mission impulse, is analyzed and compared to the performance efficiency of electrical thrusters. Tether systems are much lighter for times beyond six months in space-tug operations, where there is a dedicated solar array, and beyond one month for reboost of the International Space Station, where the solar array is already in place. Bare-tether propulsive efficiency itself, with the tether considered as part of the power plant, is higher for space tugs. Tether optimization shows that thin tapes have greater propulsive efficiency and are less sensitive to plasma density variations in orbit than cylindrical tethers. The efficiency increases with tape length if some segment next to the power supply at the top is insulated to make the tether potential bias vanish at the lower end; multitape tethers must be used to keep the efficiency high at high thrust levels. The efficiency has a maximum for tether-hardware mass equal to the fraction of power-subsystem mass going into ohmic power, though the maximum is very flat. For space tugs, effects of induced-bias changes in orbit might need to be reduced by choosing a moderately large power-subsystem to tether-hardware mass ratio or by tracking the current-voltage characteristic of the solar array.

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An electrodynamic tether can propel a spacecraft through a planetary magnetized plasma without using propellant. In the classical embodiment of an electrodynamic tether, the ambient magnetic fleld exerts a Lorentz force on the current along the tether, the ambient plasma providing circuit closure for the current A suggested propulsion scheme would hypothetically eliminate tether performance dependence on the plasma density by using a full wire loop to close the current circuit, and a superconductor to shield a loop segment from the external uniform magnetic fleld and cancel the Lorentz force on that segment. Here, we use basic electromagnetic laws to explain how such a scheme cannot produce a net force. Because there is no net current in the superconducting shield, the circulation of the magnetic field along a closed line outside the full cross section, in its plane, is just due to the current flowing in the loop segment. The presence of the superconducting shield simply moves the Lorentz force from the shielded loop segment to the shield itself and, as a result, the total magnetic force, acting on full loop plus shield, remains zero.

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An electrodynamic tether system for power generation at Jupiter is presented that allows extracting energy from Jupiter's corotating plasmasphere while leaving the system orbital energy unaltered to first order. The spacecraft is placed in a polar orbit with the tether spinning in the orbital plane so that the resulting Lorentz force, neglecting Jupiter's magnetic dipole tilt, is orthogonal to the instantaneous velocity vector and orbital radius, hence affecting orbital inclination rather than orbital energy. In addition, the electrodynamic tether subsystem, which consists of two radial tether arms deployed from the main central spacecraft, is designed in such a way as to extract maximum power while keeping the resulting Lorentz torque constantly null. The power-generation performance of the system and the effect on the orbit inclination is evaluated analytically for different orbital conditions and verified numerically. Finally, a thruster-based inclination-compensation maneuver at apoapsis is added, resulting in an efficient scheme to extract energy from the plasmasphere of the planet with minimum propellant consumption and no inclination change. A tradeoff analysis is conducted showing that, depending on tether size and orbit characteristics, the system performance can be considerably higher than conventional power-generation methods.

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Propulsion and power generation by bare electrodynamic tethers are revisited in a unified way and issues and constraints are addressed. In comparing electrodynamic tethers, which do not use propellant, with other propellantconsuming systems, mission duration is a discriminator that defines crossover points for systems with equal initial masses. Bare tethers operating in low Earth orbit can be more competitive than optimum ion thrusters in missions exceeding two-three days for orbital deboost and three weeks for boosting operations. If the tether produces useful onboard power during deboost, the crossover point reaches to about 10 days. Power generation by means of a bare electrodynamic tether in combination with chemical propulsion to maintain orbital altitude of the system is more efficient than use of the same chemicals (liquid hydrogen and liquid oxygen) in a fuel cell to produce power for missions longer than one week. Issues associated with tether temperature, bowing, deployment, and arcing are also discussed. Heating/cooling rates reach about 4 K/s for a 0.05-mm-thick tape and a fraction of Kelvin/second for the ProSEDS (0.6-mm-radius) wire; under dominant ohmic effects, temperatures areover200K (night) and 380 K (day) for the tape and 320 and 415 K for that wire. Tether applications other than propulsion and power are briefly discussed.

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The current space environment, consisting of manmade debris and micrometeoroids, poses a risk to safe operations in space, and the situation is continuously deteriorating due to in-orbit debris collisions and to new satellite launches. Bare electrodynamic tethers can provide an efficient mechanism for rapid deorbiting of satellites from low Earth orbit at end of life. Because of its particular geometry (length very much larger than cross-sectional dimensions), a tether may have a relatively high risk of being severed by the single impact of small debris. The rates of fatal impact of orbital debris on round and tape tethers of equal length and mass, evaluated with an analytical approximation to debris flux modeled by NASA’s ORDEM2000, shows much higher survival probability for tapes. A comparative numerical analysis using debris flux model ORDEM2000 and ESA’s MASTER2005 validates the analytical result and shows that, for a given time in orbit, a tape has a probability of survival of about one and a half orders of magnitude higher than a round tether of equal mass and length. Because deorbiting from a given altitude is much faster for the tape due to its larger perimeter, its probability of survival in a practical sense is quite high.

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En esta tesis se aborda el estudio del proceso de isomerización del sistema molecular LiNC/LiCN tanto aislado como en presencia de un pulso láser aplicando la teoría del estado de transición (TST). Esta teoría tiene como pilar fundamental el hecho de que el conocimiento de la dinámica en las proximidades de un punto de silla de la superficie de energía potencial permite determinar los parámetros cinéticos de la reacción objeto de estudio. Históricamente, existen dos formulaciones de la teoría del estado de transición, la versión termodinámica de Eyring (Eyr38) y la visión dinámica de Wigner (Wig38). Ésta última ha sufrido recientemente un amplio desarrollo, paralelo a los avances en sistemas dinámicos que ha dado lugar a una formulación geométrica en el espacio de fases que sirve como base al trabajo desarrollado en esta tesis. Nos hemos centrado en abordar el problema desde una visión fundamentalmente práctica, ya que la teoría del estado de transición presenta una desventaja: su elevado coste computacional y de tiempo de cálculo. Dos han sido los principales objetivos de este trabajo. El primero de ellos ha sido sentar las bases teóricas y computacionales de un algoritmo eficiente que permita obtener las magnitudes fundamentales de la TST. Así, hemos adaptado con éxito un algoritmo computacional desarrollado en el ámbito de la mecánica celeste (Jor99), obteniendo un método rápido y eficiente para la obtención de los objetos geométricos que rigen la dinámica en el espacio de fases y que ha permitido calcular magnitudes cinéticas tales como el flujo reactivo, la densidad de estados de reactivos y productos y en última instancia la constante de velocidad. Dichos cálculos han sido comparados con resultados estadísticos (presentados en (Mül07)) lo cual nos ha permitido demostrar la eficacia del método empleado. El segundo objetivo de esta tesis, ha sido la evaluación de la influencia de los parámetros de un pulso electromagnético sobre la dinámica de reacción. Para ello se ha generalizado la metodología de obtención de la forma normal del hamiltoniano cuando el sistema químico es alterado mediante una perturbación temporal periódica. En este caso el punto fijo inestable en cuya vecindad se calculan los objetos geométricos de interés para la aplicación de la TST, se transforma en una órbita periódica del mismo periodo que la perturbación. Esto ha permitido la simulación de la reactividad en presencia de un pulso láser. Conocer el efecto de esta perturbación posibilita el control de la reactividad química. Además de obtener los objetos geométricos que rigen la dinámica en una cierta vecindad de la órbita periódica y que son la clave de la TST, se ha estudiado el efecto de los parámetros del pulso sobre la reactividad en el espacio de fases global así como sobre el flujo reactivo que atraviesa la superficie divisoria que separa reactivos de productos. Así, se ha puesto de manifiesto, que la amplitud del pulso es el parámetro más influyente sobre la reactividad química, pudiendo producir la aparición de flujos reactivos a energías inferiores a las de aparición del sistema aislado y el aumento del flujo reactivo a valores constantes de energía inicial. ABSTRACT We have studied the isomerization reaction LiNC/LiCN isolated and perturbed by a laser pulse. Transition State theory (TST) is the main tool we have used. The basis of this theory is knowing the dynamics close to a fixed point of the potential energy surface. It is possible to calculate kinetic magnitudes by knowing the dynamics in a neighbourhood of the fixed point. TST was first formulated in the 30's and there were 2 points of view, one thermodynamical by Eyring (Eyr38) and another dynamical one by Wigner (Wig38). The latter one has grown lately due to the growth of the dynamical systems leading to a geometrical view of the TST. This is the basis of the work shown in this thesis. As the TST has one main handicap: the high computational cost, one of the main goals of this work is to find an efficient method. We have adapted a methodology developed in the field of celestial mechanics (Jor99). The result: an efficient, fast and accurate algorithm that allows us to obtain the geometric objects that lead the dynamics close to the fixed point. Flux across the dividing surface, density of states and reaction rate coefficient have been calculated and compared with previous statistical results, (Mül07), leading to the conclusion that the method is accurate and good enough. We have widen the methodology to include a time dependent perturbation. If the perturbation is periodic in time, the fixed point becomes a periodic orbit whose period is the same as the period of the perturbation. This way we have been able to simulate the isomerization reaction when the system has been perturbed by a laser pulse. By knowing the effect of that perturbation we will be able to control the chemical reactivity. We have also studied the effect of the parameters on the global phase space dynamics and on the flux across the dividing surface. It has been prove that amplitude is the most influent parameter on the reaction dynamics. Increasing amplitude leads to greater fluxes and to some flux at energies it would not if the systems would not have been perturbed.

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El objetivo principal de este proyecto será la obtención de una cartografía derivada empleando servicios OGC. Dado que se desconoce la funcionalidad y disponibilidad de dichos servicios se tendrá que hacer un análisis a priori de dichos servicios y a partir de este se seleccionará una zona de trabajo, objetivo y escala adecuada del mapa final. Objetivos Específicos: - Exploración y análisis de las diferentes IDEs dependientes de organizaciones oficiales. - Analizar la disponibilidad real de datos en sus correspondientes servicios de WFS, así como sus posibilidades de descarga y necesidad de registro. - Elección de una zona de trabajo, fin del mapa y escala adecuada. - Creación de una cartografía base. - Creación del mapa del Camino de Santiago a su paso por La Rioja y Navarra, relacionado con los monumentos y bodegas de la zona. - Impresión y maquetación.na de trabajo, objetivo y escala adecuada del mapa final. El Open Geospatial Consortium (OGC) fue creado en 1994 y agrupa (en febrero de 2009) a 372 organizaciones públicas y privadas. Su fin es la definición de estándares abiertos e interoperables dentro de los Sistemas de Información Geográfica y de la World Wide Web. Persigue acuerdos entre las diferentes empresas del sector que posibiliten la interoperación de sus sistemas de geoprocesamiento y facilitar el intercambio de la información geográfica en beneficio de los usuarios. Facilitar el acceso del público en general a productos cartográficos y descargas de información geográfica de gran calidad, siempre actualizados y cumpliendo requisitos de interoperabilidad. En este análisis tenemos en cuenta los siguientes servicios: - Web Map Service (WMS), o Servicios Web de Mapas - Web Feature Services (WFS), o Servicios Web de Entidades vectoriales - Web Coverage Services (WCS), o Servicios Web de Coberturas ráster.

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Flora vascular del Tejedelo de Requejo (Zamora, España)