Singular Temperatures Connected to Charge Transport Mechanism Transitions in Perylene Bisimides from Steady-State Photocurrent Measurements

Perylene bisimides (PBIs) are n-type semiconducting and photogenerating materials widely used in a variety of optoelectronic devices. Particularly interesting are PBIs that are simultaneously water-soluble and liquid-crystalline (PBI-W+LC) and, thus, attractive for the development of high-performing easily processable applications in biology and “green” organic electronics. In this work, singular temperatures connected to charge transport mechanism transitions in a PBI-W+LC derivative are determined with high accuracy by means of temperature-dependent photocurrent studies. These singular temperatures include not only the ones observed at 60 and 110 °C, corresponding to phase transition temperatures from crystalline to liquid-crystalline (LC) and from LC to the isotropic phase, respectively, as confirmed by differential scanning calorimetry (DSC), but also a transition at 45 °C, not observed by DSC. By analyzing the photocurrent dependence simultaneously on temperature and on light intensity, this transition is interpreted as a change from monomolecular to bimolecular recombination. These results might be useful for other semiconducting photogenerating materials, not necessarily PBIs or even organic semiconductors, which also show transport behavior changes at singular temperatures not connected with structural or phase transitions.

Kyoto, Japan, 1852 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Kaei kaisei shinsen Kyo ezu, Morikawa Yasuyuki gazu genko ; Haga Shunsui hozu kosei. It was published by Koto Shorin Takehara Yoshibe hanmoto in Kaei 5-nen [1852]. Scale [ca. 1:17,000]. Covers Kyoto, Japan. Map in Japanese.The image inside the map neatline is georeferenced to the surface of the earth and fit to the Tokyo Universal Transverse Mercator (UTM) Zone 53N projected coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as roads, drainage, built-up areas and selected buildings, fortifications, ground cover, and more. Relief shown pictorially.This layer is part of a selection of digitally scanned and georeferenced historic maps from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of originators, ground condition dates, scales, and map purposes.

New Orleans, Louisiana Census tracks and blocks, 1960 (Image 2 of 2) (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: New Orleans, Louisiana, by census tracts and blocks: 1960. It was published by The Census Bureau ca. 1960. Scale [ca. 1:17,500]. This layer is image 2 of 2 total images of the two sheet source map. The image inside the map neatline is georeferenced to the surface of the earth and fit to the Louisiana State Plane Coordinate System, South NAD83 (in Feet) (Fipszone 1702). All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, or other information associated with the principal map. This map shows features such as Census block and tract numbers and boundaries, roads, canals, drainage, and more. Includes inset and legend. This layer is part of a selection of digitally scanned and georeferenced historic maps from The Harvard Map Collection as part of the Imaging the Urban Environment project. Maps selected for this project represent major urban areas and cities of the world, at various time periods. These maps typically portray both natural and manmade features at a large scale. The selection represents a range of regions, originators, ground condition dates, scales, and purposes.

New Orleans, Louisiana Census tracks and blocks, 1960 (Image 1 of 2) (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: New Orleans, Louisiana, by census tracts and blocks: 1960. It was published by The Census Bureau ca. 1960. Scale [ca. 1:17,500]. This layer is image 1 of 2 total images of the two sheet source map. The image inside the map neatline is georeferenced to the surface of the earth and fit to the Louisiana State Plane Coordinate System, South NAD83 (in Feet) (Fipszone 1702). All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, or other information associated with the principal map. This map shows features such as Census block and tract numbers and boundaries, roads, canals, drainage, and more. Includes inset and legend. This layer is part of a selection of digitally scanned and georeferenced historic maps from The Harvard Map Collection as part of the Imaging the Urban Environment project. Maps selected for this project represent major urban areas and cities of the world, at various time periods. These maps typically portray both natural and manmade features at a large scale. The selection represents a range of regions, originators, ground condition dates, scales, and purposes.

Milwaukee, Wisconsin, 1882 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Map of the city of Milwaukee : engraved from original drawings & surveys, Milwaukee Lith & Eng. Co. It was published by Silas Chapman in 1882. Scale [ca. 1:17,000]. The image inside the map neatline is georeferenced to the surface of the earth and fit to the Wisconsin South State Plane NAD 1983 coordinate system (in Feet) (Fipszone 4803). All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as roads, street railways, railroads and stations, drainage, selected buildings, city ward boundaries, and more. Relief is shown by contours and hachures. Includes index. This layer is part of a selection of digitally scanned and georeferenced historic maps from The Harvard Map Collection as part of the Imaging the Urban Environment project. Maps selected for this project represent major urban areas and cities of the world, at various time periods. These maps typically portray both natural and manmade features at a large scale. The selection represents a range of regions, originators, ground condition dates, scales, and purposes.

Liverpool, England, 1854 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Map of the borough of Liverpool : with Parliamentary boundaries, ecclesiastical divisions and a part of the Cheshire coast. It was published by engraved and published by H. Hilliar in 1854. Scale [ca. 1:17,000]. Covers portions of Liverpool and Birkenhead, England. The image inside the map neatline is georeferenced to the surface of the earth and fit to the 'British National Grid' coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as roads, railroads, drainage, built-up areas and selected buildings and industries, canals, docks, wharves, city districts, ground cover, parks and more. This layer is part of a selection of digitally scanned and georeferenced historic maps from The Harvard Map Collection as part of the Imaging the Urban Environment project. Maps selected for this project represent major urban areas and cities of the world, at various time periods. These maps typically portray both natural and manmade features at a large scale. The selection represents a range of regions, originators, ground condition dates, scales, and purposes.

Vienna, Austria, 1720 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Wien die Welt berühmte Kayserls. Resid. Stadt : nach ihrem porspect u. grund riss samt anstossender Gegend und Neuen Linieun um die Vor-städte, versertigt und verlegts Matth. Seütter in Augsp. It was published by Matth. Seütter in [1720]. Scale [ca. 1:17,000]. Map in German. The image inside the map neatline is georeferenced to the surface of the earth and fit to the MGI 3-Degree Gauss Kruger coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as roads, drainage, built-up areas and selected buildings, ground cover, fortifications, and more. Includes index and view: Prospect der Kayserl. Residen-stadt Wien wie solche von Mitternacht anzusehen. This layer is part of a selection of digitally scanned and georeferenced historic maps from The Harvard Map Collection as part of the Imaging the Urban Environment project. Maps selected for this project represent major urban areas and cities of the world, at various time periods. These maps typically portray both natural and manmade features at a large scale. The selection represents a range of regions, originators, ground condition dates, scales, and purposes.

Warsaw, Poland, 1831 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Warsaw = Warszawa, drawn by W.B. Clarke, Arch. ; engraved by T.E. Nicholson. It was published by Published under the superintendence of the Society for the Diffusion of Useful Knowledge [by] Baldwin & Cradock in 1831. Scale [ca. 1:17,000] Covers Warsaw, Poland. Map in English and Polish.The image inside the map neatline is georeferenced to the surface of the earth and fit to the 'Pulkovo 1942 Adjust 1958 Poland Zone II' coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map.This map shows features such as roads, drainage, built-up areas and selected buildings, fortification, ground cover, city district boundaries, and more. Relief shown by hachures. Includes profile views of selected buildings.This layer is part of a selection of digitally scanned and georeferenced historic maps from The Harvard Map Collection as part of the Imaging the Urban Environment project. Maps selected for this project represent major urban areas and cities of the world, at various time periods. These maps typically portray both natural and manmade features at a large scale. The selection represents a range of regions, originators, ground condition dates, scales, and purposes.

Tokyo, Japan, 1907 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: The revised map of Tokyo, S. Nishinomiya. It was published by S. Nishinomiya in 1907. Scale [ca. 1:17,000]. Covers Tokyo, Japan. The image inside the map neatline is georeferenced to the surface of the earth and fit to the Tokyo UTM Zone 54N coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as roads, railroad and street railway lines and stations, drainage, built-up areas and selected buildings, city and county boundaries, parks, cemeteries, and more. Relief is shown by hachures. Includes insets: [Tokyo and environs] -- Tsukiji Foreign Settlement. This layer is part of a selection of digitally scanned and georeferenced historic maps from The Harvard Map Collection as part of the Imaging the Urban Environment project. Maps selected for this project represent major urban areas and cities of the world, at various time periods. These maps typically portray both natural and manmade features at a large scale. The selection represents a range of regions, originators, ground condition dates, scales, and purposes.

Boston, Massachusetts, 1846 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Plan of Boston comprising a part of Charlestown and Cambridge, published by George G. Smith, engraver, 1846. Scale [ca. 1:7,310]. Covers Boston proper (Shawmut Peninsula and Boston Neck) with small portions of Charlestown, Cambridge, and South Boston. The image inside the map neatline is georeferenced to the surface of the earth and fit to the Massachusetts State Plane Coordinate System, Mainland Zone (in Feet) (Fipszone 2001). All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, or other information associated with the principal map. This map shows features such as roads, railroads, wharves, drainage, churches, schools, selected public buildings, parks, cemeteries, city ward boundaries and more. Relief is shown by hachures. Includes insets: Plan of South Boston from a drawing by S.P. Fuller. Scale [ca. 1:17,600] -- Plan of East Boston from actual survey by R.H. Eddy. Scale [ca. 1:17,000]. Includes also indexes to points of interest and streets. This layer is part of a selection of digitally scanned and georeferenced historic maps of Massachusetts from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of regions, originators, ground condition dates (1755-1922), scales, and purposes. The digitized selection includes maps of: the state, Massachusetts counties, town surveys, coastal features, real property, parks, cemeteries, railroads, roads, public works projects, etc.

Boston, Massachusetts, 1851 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Plan of Boston comprising a part of Charlestown and Cambridge, published by George G. Smith, engraver, 1851. Scale [ca. 1:7,380]. Covers Boston proper (Shawmut Peninsula and Boston Neck) with small portions of Charlestown, Cambridge, and South Boston. The image inside the map neatline is georeferenced to the surface of the earth and fit to the Massachusetts State Plane Coordinate System, Mainland Zone (in Feet) (Fipszone 2001). All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, or other information associated with the principal map. This map shows features such as roads, railroads, signal stations, wharves, drainage, churches, schools, selected public buildings, parks, cemeteries, city ward boundaries and more. Relief is shown by hachures. Includes insets: Plan of South Boston from a drawing by S.P. Fuller. Scale [ca. 1:17,600] -- Plan of East Boston from actual survey by R.H. Eddy. Scale [ca. 1:17,000]. Includes also indexes to points of interest and streets. This layer is part of a selection of digitally scanned and georeferenced historic maps of Massachusetts from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of regions, originators, ground condition dates (1755-1922), scales, and purposes. The digitized selection includes maps of: the state, Massachusetts counties, town surveys, coastal features, real property, parks, cemeteries, railroads, roads, public works projects, etc.

Boston, Massachusetts, 1835 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Plan of Boston comprising a part of Charlestown and Cambridge, published by George G. Smith, engraver, 1835. Scale [ca. 1:7,310]. Covers Boston proper (Shawmut Peninsula and Boston Neck) with small portions of Charlestown, Cambridge, and South Boston. The image inside the map neatline is georeferenced to the surface of the earth and fit to the Massachusetts State Plane Coordinate System, Mainland Zone (in Feet) (Fipszone 2001). All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, or other information associated with the principal map. This map shows features such as roads, railroads, wharves, drainage, churches, schools, selected public buildings, parks, cemeteries, city ward boundaries and more. Relief is shown by hachures. Includes insets: Plan of South Boston from a drawing by S.P. Fuller. Scale [ca. 1:17,600] -- Plan of East Boston from actual survey by R.H. Eddy. Scale [ca. 1:17,000]. This layer is part of a selection of digitally scanned and georeferenced historic maps of Massachusetts from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of regions, originators, ground condition dates (1755-1922), scales, and purposes. The digitized selection includes maps of: the state, Massachusetts counties, town surveys, coastal features, real property, parks, cemeteries, railroads, roads, public works projects, etc.

Kyōto-shi, Japan, 1894 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Teikoku Kyōto shigai meisho shinzu, Kataoka Kenzō hen. It was published by Fūgetsu Shōzaemon in Meiji 27-nen [1894]. Scale [ca. 1:17,000]. Covers Kyōto-shi, Japan. Map in Japanese.The image inside the map neatline is georeferenced to the surface of the earth and fit to the Tokyo Universal Transverse Mercator (UTM) Zone 53N projected coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as drainage, streets, railroads, mountains, built-up areas and selected buildings, and more. Relief shown pictorially. Includes views of places of interest.This layer is part of a selection of digitally scanned and georeferenced historic maps from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of originators, ground condition dates, scales, and map purposes.

Africa, 1795 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: Karte von Afrika, Nach Vaugondy neu verzeichnet herausgegeben von Franz Joh. Jos. Von Reilly ; gestochen von Hier. Benedicti. It was published by Reilly'sches Landkarten und Kunstwerke Verschleiss Komptoir in 1795. Scale [ca. 1:17,500,000]. Covers Africa. Map in German.The image inside the map neatline is georeferenced to the surface of the earth and fit to the Africa Sinusoidal projected coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as drainage, cities and other human settlements, territorial boundaries, shoreline features, and more. Relief shown pictorially. Includes also notes. This layer is part of a selection of digitally scanned and georeferenced historic maps from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of originators, ground condition dates, scales, and map purposes.

Africa, 1805 (Raster Image)

This layer is a georeferenced raster image of the historic paper map entitled: A new map of Africa : from the latest authorities, by John Cary, engraver. It was published by J. Cary, Engraver and Map-Seller, 181 Strand in June 1st., 1805. Scale [ca. 1:17,500,000]. Covers also a small portion of Europe and the Middle East. The image inside the map neatline is georeferenced to the surface of the earth and fit to the Africa Sinusoidal projected coordinate system. All map collar and inset information is also available as part of the raster image, including any inset maps, profiles, statistical tables, directories, text, illustrations, index maps, legends, or other information associated with the principal map. This map shows features such as drainage, cities and other human settlements, territorial boundaries, roads, shoreline features, and more. Relief shown pictorially and with shading. Includes alsoThis layer is part of a selection of digitally scanned and georeferenced historic maps from the Harvard Map Collection. These maps typically portray both natural and manmade features. The selection represents a range of originators, ground condition dates, scales, and map purposes.